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A drop in the ocean Earth's bulk composition is similar to that of a group of oxygen-poor meteorites called enstatite chondrites, thought to have formed in the early solar nebula. This leads to the suggestion that proto-Earth was dry, and that volatiles including water were delivered by asteroid and comet impacts. The deuterium-to-hydrogen (D/H) ratios measured in six Oort cloud comets are much higher than on Earth, however, apparently ruling out a dominant role for such bodies. Now the Herschel Space Telescope has been used to determine the D/H ratio in the Kuiper belt comet 103P/Hartley 2. The ratio is Earth-like, suggesting that this population of comets may have contributed to Earth's ocean waters. For decades, the source of Earth's volatiles, especially water with a deuterium-to-hydrogen ratio (D/H) of (1.558 ± 0.001) × 10 −4 , has been a subject of debate. The similarity of Earth’s bulk composition to that of meteorites known as enstatite chondrites 1 suggests a dry proto-Earth 2 with subsequent delivery of volatiles 3 by local accretion 4 or impacts of asteroids or comets 5 , 6 . Previous measurements in six comets from the Oort cloud yielded a mean D/H ratio of (2.96 ± 0.25) × 10 −4 . The D/H value in carbonaceous chondrites, (1.4 ± 0.1) × 10 −4 , together with dynamical simulations, led to models in which asteroids were the main source of Earth's water 7 , with ≤10 per cent being delivered by comets. Here we report that the D/H ratio in the Jupiter-family comet 103P/Hartley 2, which originated in the Kuiper belt, is (1.61 ± 0.24) × 10 −4 . This result substantially expands the reservoir of Earth ocean-like water to include some comets, and is consistent with the emerging picture of a complex dynamical evolution of the early Solar System 8 , 9 .

Icy bodies may have delivered the oceans to the early Earth, yet little is known about water in the ice-dominated regions of extrasolar planet-forming disks. The Heterodyne Instrument for the Far-Infrared on board the Herschel Space Observatory has detected emission lines from both spin isomers of cold water vapor from the disk around the young star TW Hydrae. This water vapor likely originates from ice-coated solids near the disk surface, hinting at a water ice reservoir equivalent to several thousand Earth oceans in mass. The water's ortho-to-para ratio falls well below that of solar system comets, suggesting that comets contain heterogeneous ice mixtures collected across the entire solar nebula during the early stages of planetary birth.

A fundamental question in cometary science is whether the different dynamical classes of comets have different chemical compositions, which would reflect different initial conditions. From the ground or Earth orbit, radio and infrared spectroscopic observations of a now significant sample of comets indeed reveal deep differences in the relative abundances of cometary ices. However, no obvious correlation with dynamical classes is found. Further results come, or are expected, from space exploration. Such investigations, by nature limited to a small number of objects, are unfortunately focussed on short-period comets (mainly Jupiter-family). But these in situ studies provide “ground truth” for remote sensing. We discuss the chemical differences in comets from our database of spectroscopic radio observations, which has been recently enriched by several Jupiter-family and Halley-type comets.

We present a comparative study on molecular abundances in comets basedon millimetre/submillimetre observations made with the IRAM 30-m,JCMT, CSO and SEST telescopes. This study concerns a sample of 24comets (6 Jupiter-family, 3 Halley-family, 15 long-period) observedfrom 1986 to 2001 and 8 molecular species (HCN, HNC, CH3CN,CH3OH, H2CO, CO, CS, H2S). HCN was detected in all comets,while at least 2 molecules were detected in 19 comets.From the sub-sample of comets for which contemporary H2O productionrates are available, we infer that the HCN abundance relative to water variesfrom 0.08% to 0.25%. With respect to other species, HCN is the moleculewhich exhibits the lowest abundance variation from comet to comet. Therefore,production rates relative to that of HCN can be used for a comparative study ofmolecular abundances in the 19 comets. It is found that: CH3OH/HCN varies from ≤ 9 to 64; CO/HCN varies from ≤ 24 to 180; H2CO/HCN varies between 1.6 and 10; and H2S/HCN varies between 1.5 and 7.6.This study does not show any clear correlation between the relative abundancesand the dynamical origins of the comets, or their dust-to-gas ratios.

The bright comet Hale–Bopp provided the first opportunity to follow the outgassing rates of a number of molecular species over a large range of heliocentric distances. We present the results of our observing campaign at radio wavelengths which began in August 1995 and ended in January 2002. The observations were carried out with the telescopes of Nançay, IRAM, JCMT, CSO and, since September 1997, SEST. The lines of nine molecules (OH, CO, HCN, CH3OH, H2CO, H2S, CS, CH3CN and HNC) were monitored. CS, H2S, H2CO, CH3CN were detected up to rh= 3–4 AU from the Sun, while HCN and CH3OH were detected up to 6 AU. CO, which is the main driver of cometary activity at heliocentric distances larger than 3–4 AU, was last detected in August 2001, at rh= 14 AU.The gas production rates obtained from this programme contain important information on the nature of cometary ices, their thermal properties and sublimation mechanisms.Line shapes allow to measure gas expansion velocities, which, at large heliocentric distances, might be directly connected to the temperature of the nucleus surface. Inferred expansion velocity of the gas varied as rh-0.4 within 7 AU from the Sun, but remained close to 0.4 km s-1 further away. The CO spectra obtained at large rhare strongly blueshifted and indicative of an important day-to-night asymmetry in outgassing and expansion velocity. The kinetic temperature of the coma, estimated from the relative intensities of the CH3OH and CO lines, increased with decreasing rh, from about 10 K at 7 AU to 110 K around perihelion.

With a 3.5 m diameter telescope passively cooled to approximately 80 K, and a science payload comprising two direct detection cameras/medium resolution imaging spectrometers (PACS and SPIRE) and a very high spectral resolution heterodyne spectrometer (HIFI), the Herschel Space Observatory is providing extraordinary observational opportunities in the 55-670 μm spectral range. HIFI has opened for the first time to high-resolution spectroscopy the submillimetre band that includes the fundamental rotational transitions of interstellar hydrides, the basic building blocks of astrochemistry. We discuss a recent HIFI discovery of metastable rotational transitions of the hydronium ion (protonated water, H3O+), with rotational level energies up to 1200 K above the ground state, in absorption towards Sagittarius B2(N) in the Galactic centre. Hydronium is an important molecular ion in the oxygen chemical network. Earlier HIFI observations have indicated a general deficiency of H3O+ in the diffuse gas in the Galactic disc. The presence of hot H3O+ towards Sagittarius B2(N) thus appears to be related to the unique physical conditions in the central molecular zone, manifested, for example, by the widespread presence of abundant H. One intriguing theory for the high rotational temperature characterizing the population of the H3O+ metastable levels may be formation pumping in molecular gas irradiated by X-rays emitted by the Galactic centre black hole. Alternatively, the pervasive presence of enhanced turbulence in the central molecular zone may give rise to shocks in the lower-density medium that is exposed to energetic radiation.

The gas activity of comet C/1999 S4 (LINEAR) was monitored at radio wavelengths during its disruption. A runaway fragmentation of the nucleus may have begun around 18 July 2000 and proceeded until 23 July. The mass in small icy debris (≤30-centimeter radius) was comparable to the mass in the large fragments seen in optical images. The mass budget after breakup suggests a small nucleus (∼100- to 300-meter radius) that had been losing debris for weeks. The HNC,$H_2CO,\\>H_2S$, and CS abundances relative to H2Omeasured during breakup are consistent with those obtained in other comets. However, a deficiency in CH3OHand CO is observed.

For decades, the source of Earth's volatiles, especially water with a deuterium-to-hydrogen ratio (D/H) of (1.558 ± 0.001) x [10.sup.-4], has been a subject of debate. The similarity of Earth's bulk composition to that of meteorites known as enstatite chondrites (1) suggests a dry proto-Earth (2) with subsequent delivery of volatiles (3) by local accretion (4) or impacts of asteroids or comets (5,6). Previous measurements in six comets from the Oort cloud yielded a mean D/H ratio of (2.96 ± 0.25) x [10.sup.-4]. The D/H value in carbonaceous chondrites, (1.4 ± 0.1) x [10.sup.-4], together with dynamical simulations, led to models in which asteroids were the main source of Earth's water (7), with ≤ 10 per cent being delivered by comets. Here we report that the D/H ratio in the Jupiter-family comet 103P/Hartley 2, which originated in the Kuiper belt, is (1.61 ± 0.24) x [10.sup.-4]. This result substantially expands the reservoir of Earth ocean-like water to include some comets, and is consistent with the emerging picture of a complex dynamical evolution of the early Solar System (8,9).

Volatile compounds in comets are the most pristine materials surviving from the time of formation of the Solar System, and thus potentially provide information about conditions that prevailed in the primitive solar nebula. Moreover, comets may have supplied a substantial fraction of the volatiles on the terrestrial planets, perhaps including organic compounds that played a role in the origin of life on Earth. Here we report the detection of hydrogen isocyanide (HNC) in comet Hyakutake. The abundance of HNC relative to hydrogen cyanide (HCN) is very similar to that observed in quiescent interstellar molecular clouds, and quite different from the equilibrium ratio expected in the outermost solar nebula, where comets are thought to form. Such a departure from equilibrium has long been considered a hallmark of gas-phase chemical processing in the interstellar medium, suggesting that interstellar gases have been incorporated into the comet's nucleus, perhaps as ices frozen onto interstellar grains. If this interpretation is correct, our results should provide constraints on the temperature of the solar nebula, and the subsequent chemical processes that occurred in the region where comets formed.

The mass distribution of dense cores is a potential key to understand the process of star formation. Applying dendrogram analysis to the CARMA-NRO Orion C\\(^{18}\\)O (\\(J\\)=1--0) data, we identify 2342 dense cores, about 22 \\% of which have virial ratios smaller than 2, and can be classified as gravitationally bound cores. The derived core mass function (CMF) for bound starless cores which are not associate with protostars has a slope similar to Salpeter's initial mass function (IMF) for the mass range above 1 \\(M_\\odot\\), with a peak at \\(\\sim\\) 0.1 \\(M_\\odot\\). We divide the cloud into four parts based on the declination, OMC-1/2/3, OMC-4/5, L1641N/V380 Ori, and L1641C, and derive the CMFs in these regions. We find that starless cores with masses greater than 10 \\(M_\\odot\\) exist only in OMC-1/2/3, whereas the CMFs in OMC-4/5, L1641N, and L1641C are truncated at around 5--10 \\(M_\\odot\\). From the number ratio of bound starless cores and Class II objects in each subregion, the lifetime of bound starless cores is estimated to be 5--30 free-fall times, consistent with previous studies for other regions. In addition, we discuss core growth by mass accretion from the surrounding cloud material to explain the coincidence of peak masses between IMFs and CMFs. The mass accretion rate required for doubling the core mass within a core lifetime is larger than that of Bondi-Hoyle accretion by a factor of order 2. This implies that more dynamical accretion processes are required to grow cores.