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The Sentinel-3A satellite was launched on 16 February 2016 with the Ocean and Land Colour Instrument (OLCI-A) on-board for the study of ocean color. The accuracy of ocean color parameters depends on the atmospheric correction algorithm (AC). This processing consists of removing the contribution of the atmosphere from the total measured signal by the remote sensor at the top of the atmosphere. Five ACs: the baseline AC, the Case 2 regional coast color neural network AC, its alternative version, the Polymer AC, and the standard NASA AC, are inter-compared over two bio-optical contrasted French coastal waters. The retrieved water-leaving reflectances are compared with in situ ocean color radiometric measurements collected using an ASD FielSpec4 spectrometer. Statistical and spectral analysis were performed to assess the best-performing AC through individual (relative error (RE) at 412 nm ranging between 23.43 and 57.31%; root mean squared error (RMSE) at 412 nm ranging between 0.0077 and 0.0188) and common (RE(412 nm) = 24.15–50.07%; RMSE(412 nm) = 0.0081–0.0132) match-ups. The results suggest that the most efficient schemes are the alternative version of the Case 2 regional coast color neural network AC with RE(412 nm) = 33.52% and RMSE(412 nm) = 0.0101 for the individual and Polymer with RE(412 nm) = 24.15% and RMSE(412 nm) = 0.0081 for the common ACs match-ups. Sensitivity studies were performed to assess the limitations of the AC, and the errors of retrievals showed no trends when compared to the turbidity and CDOM.

Chlorophyll-a concentration (Chl-a) is a crucial parameter for monitoring the water quality in coastal waters. The principal aim of this study is to evaluate the performance of existing Chl-a band ratio inversion models for estimating Chl-a from Sentinel2-MSI and Sentinel3-OLCI observation. This was performed using an extensive in situ Rrs-Chl-a dataset covering contrasted coastal waters (N = 1244, Chl-a (0.03–555.99) µg/L), which has been clustered into five optical water types (OWTs). Our results show that the blue/green inversion models are suitable to derive Chl-a over clear to medium turbid waters (OWTs 1, 2, and 3) while red/NIR models are adapted to retrieve Chl-a in turbid/high-Chl-a environments. As they exhibited the optimal performance considering these two groups of OWTs, MuBR (multiple band ratio) and NDCI (Normalized Difference Chlorophyll-a Index)-based models were merged using the probability values of the defined OWTs as the blending coefficients. Such a combination provides a reliable Chl-a prediction over the vast majority of the global coastal turbid waters (94%), as evidenced by a good performance on the validation dataset (e.g., MAPD = 21.64%). However, our study further illustrated that none of the evaluated algorithms yield satisfying Chl-a estimates in ultra-turbid waters, which are mainly associated with turbid river plumes (OWT 5). This finding highlights the limitation of multispectral ocean color observation in such optically extreme environments and also implies the interest to better explore hyperspectral Rrs information to predict Chl-a.

The development of algorithms for remote sensing of water quality (RSWQ) requires a large amount of in situ data to account for the bio-geo-optical diversity of inland and coastal waters. The GLObal Reflectance community dataset for Imaging and optical sensing of Aquatic environments (GLORIA) includes 7,572 curated hyperspectral remote sensing reflectance measurements at 1 nm intervals within the 350 to 900 nm wavelength range. In addition, at least one co-located water quality measurement of chlorophyll a, total suspended solids, absorption by dissolved substances, and Secchi depth, is provided. The data were contributed by researchers affiliated with 59 institutions worldwide and come from 450 different water bodies, making GLORIA the de-facto state of knowledge of in situ coastal and inland aquatic optical diversity. Each measurement is documented with comprehensive methodological details, allowing users to evaluate fitness-for-purpose, and providing a reference for practitioners planning similar measurements. We provide open and free access to this dataset with the goal of enabling scientific and technological advancement towards operational regional and global RSWQ monitoring.

Sentinel-2/MSI and Landsat-8/OLI sensors enable the mapping of ocean color-related bio-optical parameters of surface coastal and inland waters. While many algorithms have been developed to estimate the Chlorophyll-a concentration, Chl-a, and the suspended particulate matter, SPM, from OLI and MSI data, the absorption by colored dissolved organic matter, acdom, a key parameter to monitor the concentration of dissolved organic matter, has received less attention. Herein we present an inverse model (hereafter referred to as AquaCDOM) for estimating acdom at the wavelength 412 nm (acdom (412)), within the surface layer of coastal waters, from measurements of ocean remote sensing reflectance, Rrs (λ), for these two high spatial resolution (around 20 m) sensors. Combined with a water class-based approach, several empirical algorithms were tested on a mixed dataset of synthetic and in situ data collected from global coastal waters. The selection of the final algorithms was performed with an independent validation dataset, using in situ, synthetic, and satellite Rrs (λ) measurements, but also by testing their respective sensitivity to typical noise introduced by atmospheric correction algorithms. It was found that the proposed algorithms could estimate acdom (412) with a median absolute percentage difference of ~30% and a median bias of 0.002 m−1 from the in situ and synthetic datasets. While similar performances have been shown with two other algorithms based on different methodological developments, we have shown that AquaCDOM is much less sensitive to atmospheric correction uncertainties, mainly due to the use of band ratios in its formulation. After the application of the top-of-atmosphere gains and of the same atmospheric correction algorithm, excellent agreement has been found between the OLI- and MSI-derived acdom (412) values for various coastal areas, enabling the application of these algorithms for time series analysis. An example application of our algorithms for the time series analysis of acdom (412) is provided for a coastal transect in the south of Vietnam.

The present study evaluates the influence of industrialization on suspended particulate matter (SPM) dynamics along the northern coast of Rio de Janeiro, focusing specifically on the Açu Port Industrial Complex (APIC). A 20-year MODIS-Aqua (1 km) dataset (2002–2022) was processed using the OC-SMART atmospheric correction. For SPM estimation, a retrieval approach for coastal turbid waters that integrates two optimized bio-optical algorithms based on Optical Water Types (OWTs) was developed. The validity of this approach was substantiated through the utilization of the GLORIA in situ dataset and satellite matchups, which demonstrated its robust performance across a range of turbidity conditions. Its main innovation lies in the OWT-based fusion of two optimized SPM models, enabling robust retrievals across diverse coastal optical conditions. Statistical analyses based on Census X11 decomposition and the Seasonal Mann–Kendall test revealed strong spatial and temporal variability, with SPM concentrations increasing by up to 60% near the APIC during the study period, coinciding with dredging, port expansion, and sediment disposal. These findings indicate a pronounced anthropogenic signal, while spatial and temporal correlation analyses demonstrated that sediment dispersion is consistently directed northward, primarily controlled by currents and wind forcing. The results indicate that industrial activities augment the supply of sediments, while natural hydrodynamic processes govern their dispersion and transport, emphasizing the impact of human pressures and physical drivers on coastal sediments.

Remote sensing of suspended particulate matter, SPM, from space has long been used to assess its spatio-temporal variability in various coastal areas. The associated algorithms were generally site specific or developed over a relatively narrow range of concentration, which make them inappropriate for global applications (or at least over broad SPM range). In the frame of the GlobCoast project, a large in situ data set of SPM and remote sensing reflectance, Rrs(λ), has been built gathering together measurements from various coastal areas around Europe, French Guiana, North Canada, Vietnam, and China. This data set covers various contrasting coastal environments diversely affected by different biogeochemical and physical processes such as sediment resuspension, phytoplankton bloom events, and rivers discharges (Amazon, Mekong, Yellow river, MacKenzie, etc.). The SPM concentration spans about four orders of magnitude, from 0.15 to 2626 g·m−3. Different empirical and semi-analytical approaches developed to assess SPM from Rrs(λ) were tested over this in situ data set. As none of them provides satisfactory results over the whole SPM range, a generic semi-analytical approach has been developed. This algorithm is based on two standard semi-analytical equations calibrated for low-to-medium and highly turbid waters, respectively. A mixing law has also been developed for intermediate environments. Sources of uncertainties in SPM retrieval such as the bio-optical variability, atmospheric correction errors, and spectral bandwidth have been evaluated. The coefficients involved in these different algorithms have been calculated for ocean color (SeaWiFS, MODIS-A/T, MERIS/OLCI, VIIRS) and high spatial resolution (LandSat8-OLI, and Sentinel2-MSI) sensors. The performance of the proposed algorithm varies only slightly from one sensor to another demonstrating the great potential applicability of the proposed approach over global and contrasting coastal waters.

Oceanic N 2 fixation by diazotrophic microorganisms is the primary external source of new nitrogen to the surface ocean sustaining net production of organic matter. Studying long-term trends in biomass within N 2 fixation hotspots is crucial for understanding and predicting the response of N 2 fixation to global climate change. Here we developed a bio-optical model based on the spectral phytoplankton absorption coefficient derived from satellite ocean color observations to estimate a proxy for particulate organic nitrogen in the western tropical South Pacific. We demonstrate the existence of a seasonal new biomass production annually over the past 20 years, likely driven by recurrent N 2 fixation. Importantly, our results also reveal a gradual decline in biomass within this N 2 fixation hotspot over the last two decades. This decline indicates that seasonal nitrogen inputs via N 2 fixation are decreasing. This trend inevitably could lead to a decline in the efficiency of the biological carbon pump, with potential implications for global biogeochemical cycles and climate regulation. Using satellite ocean-color data, this study reveals a 20-year decline in plankton biomass in a major nitrogen-fixation hotspot, suggesting reduced nitrogen inputs and potential implications for global biogeochemical cycles and climate regulation.

Coastal zones are highly dynamical systems triggered by a variety natural and anthropogenic forcing factors, that include sea level rise, extreme events, local oceanic and atmospheric processes, ground subsidence, etc. However so far, they remain poorly monitored on a global scale. To better understand changes affecting world coastal zones and to provide crucial information to decision-makers involved in adaptation to and mitigation of environmental risks, coastal observations of various types need to be collected and analyzed. In this white paper, we first discuss the main forcing agents acting on coastal regions (e.g., sea level, winds, waves and currents, river runoff, sediment supply and transport, vertical land motions, land use) and the induced coastal response (e.g., shoreline position, estuaries morphology, land topography at the land-sea interface and coastal bathymetry). We identify a number of space-based observational needs that have to be addressed in the near future to understand coastal zone evolution. Among these, improved monitoring of coastal sea level by satellite altimetry techniques is recognized as high priority. Classical altimeter data in the coastal zone are adversely affected by land contamination with degraded range and geophysical corrections. However, recent progress in coastal altimetry data processing and multi-sensor data synergy, offers new perspective to measure sea level change very close to the coast. This issue is discussed in much detail in this paper, including the development of a global coastal sea-level and sea state climate record with mission consistent coastal processing and products dedicated to coastal regimes. Finally, we present a new promising technology based on the use of Signals of Opportunity (SoOps), i.e., communication satellite transmissions that are reutilized as illumination sources in a bistatic radar configuration, for measuring coastal sea level. Since SoOp technology requires only receiver technology to be placed in orbit, small satellite platforms could be used, enabling a constellation to achieve high spatio-temporal resolutions of sea level in coastal zones.

Passive ocean color images have provided a sustained synoptic view of the distribution of ocean optical properties and color and biogeochemical parameters for the past 20-plus years. These images have revolutionized our view of the ocean. Remote sensing of ocean color has relied on measurements of the radiance emerging at the top of the atmosphere, thus neglecting the polarization and the vertical components. Ocean color remote sensing utilizes the intensity and spectral variation of visible light scattered upward from beneath the ocean surface to derive concentrations of biogeochemical constituents and inherent optical properties within the ocean surface layer. However, these measurements have some limitations. Specifically, the measured property is a weighted-integrated value over a relatively shallow depth, it provides no information during the night and retrievals are compromised by clouds, absorbing aerosols, and low Sun zenithal angles. In addition, ocean color data provide limited information on the morphology and size distribution of marine particles. Major advances in our understanding of global ocean ecosystems will require measurements from new technologies, specifically lidar and polarimetry. These new techniques have been widely used for atmospheric applications but have not had as much as interest from the ocean color community. This is due to many factors including limited access to in-situ instruments and/or space-borne sensors and lack of attention in university courses and ocean science summer schools curricula. However, lidar and polarimetry technology will complement standard ocean color products by providing depth-resolved values of attenuation and scattering parameters and additional information about particle morphology and chemical composition. This review aims at presenting the basics of these techniques, examples of applications and at advocating for the development of in-situ and space-borne sensors. Recommendations are provided on actions that would foster the embrace of lidar and polarimetry as powerful remote sensing tools by the ocean science community.

The variability of the backscattering to scattering ratio of marine particles, $\"b\"_{{\\rm{bp}}}$: $\"b\"_{\\rm{p}}$, is examined from in situ measurements performed during the spring and early summer of 2004 in the eastern English Channel and southern North Sea. This area is characterized by a quasi-permanent background of mineral matter from direct inputs, or resuspension effects, and by relatively intense spring phytoplankton blooms (mainly diatoms and the prymnesiophyte \"Phaeocystis globosa\"). The $\"b\"_{{\\rm{bp}}}$: $\"b\"_{\\rm{p}}$ surface values range between 0.0024 and 0.0417, with a mean value of 0.0138 ± 0.0083. In order to interpret such a great variability, simultaneous water samples were collected for the biogeochemical characterization of the bulk suspended particle population. We show that the $\"b\"_{{\\rm{bp}}}$: $\"b\"_{\\rm{p}}$ variability is related to the composition of the particulate assemblage expressed by Chi \"a\", the POC : SPM and POC : Ch1 \"a\" ratios, where Chi \"a\", POC, and SPM are the concentrations of chlorophyll \"a\", particulate organic carbon, and suspended particulate matter, respectively. Low $\"b\"_{{\\rm{bp}}}$: $\"b\"_{\\rm{p}}$ values are observed for a particle population dominated by low refractive index material such as phytoplankton, whereas high $\"b\"_{{\\rm{bp}}}$: $\"b\"_{\\rm{p}}$ values are generally observed in presence of relatively high concentration of inorganic particles. The amount of organic material (both living and nonliving, including phytoplankton) relative to phytoplankton has a strong (and sometimes the greatest) effect on the backscattering-to-scattering ratio. Assuming that phytoplankton and detritus have similar refractive index, this pattern is interpreted as resulting from changes in the particle size distribution as well as by aggregation of mineral and nonliving organic detrital material.