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A collection of polished stone axes from a late Neolithic site and an Early Bronze Age hill fort in South Tyrol (Italy) have been analysed through a multi-analytical approach, mainly based on non-destructive techniques (i.e. Raman spectroscopy, X-ray fluorescence and prompt gamma activation analysis) to identify the raw materials used in the same area during different periods and compare them with those in use in the surrounding territories. The analytical results suggest raw material exploitation strategies based on local or close sedimentary, metamorphic and magmatic rocks. Most of the artefacts are made from antigoritic serpentinite, whose origin is probably from Hohe Tauern (Austria) or related secondary deposits. These data confirm the importance of such raw material for the production of polished stone axes during recent prehistory and integrate the present knowledge about the distribution of antigoritic artefacts in north-eastern Italy and neighbouring countries.

Hybrid solar cells based on 1,2 methanofullerene (C61) capped CdSe and poly (3-hexylthiophene) (P3HT) were been investigated through a range of techniques. High resolution transmission electron microscopy (HRTEM) was used to characterize size, morphology and crystal structure of as-grown and C61-capped CdSe quantum dots. Cross sectional lamellar specimens were prepared from full photovoltaic devices using a focused ion beam milling approach. The sections were analysed by high angle annular dark field imaging in scanning TEM mode to determine the morphology of the device, in particular the intermixing of P3HT and capped quantum dots.

Hybrid solar cells based on 1,2 methanofullerene (C sub(61)) capped CdSe and poly (3-hexylthiophene) (P3HT) were been investigated through a range of techniques. High resolution transmission electron microscopy (HRTEM) was used to characterize size, morphology and crystal structure of as-grown and C sub(61)-capped CdSe quantum dots. Cross sectional lamellar specimens were prepared from full photovoltaic devices using a focused ion beam milling approach. The sections were analysed by high angle annular dark field imaging in scanning TEM mode to determine the morphology of the device, in particular the intermixing of P3HT and capped quantmn dots.

We calculate the historical payback time (PBT) and internal rate of return (IRR) for domestic photovoltaic systems installed at different times between 2003 and 2014, in three different Italian locations (North, center, South, thus representing different levels of energy yield). We show that over time, even though rather different regimes of governmental incentivization and end-user energy prices existed, such economic parameters have hardly been affected. Remarkably, this is true even for the case of systems installed in 2014 - i.e. where no incentivization of any kind is considered, but grid parity has been attained. In this case the PBT is 10.6, 9.3, 8.5 years for the locations in the North, center, and South, respectively; the IRR is 9.1%, 10.4%, 11.3%, respectively. These observations are in marked contrast with the common understanding that the dramatic reduction of installations in Italy after 2011 is due to a reduction of the economic convenience for the end-user, suggesting that the economic factor only plays a marginal role in current PV market dynamics.

We analysed the major, minor and trace elements chemistry of forty-two Cr-spinels from four Siberian kimberlites. They showed a wide range in Mg# (Mg/(Mg + Fe2+); 0.42–0.78) and Cr# (Cr/(Cr + Al); 0.32–0.92) and a common trend of increasing Cr# with decreasing Mg#. The major element classification schemes suggested that there were spinels deriving from a peridotitic source (Xen) and spinels crystallised from kimberlitic melts (Chr). Laser-Ablation Inductively Coupled Plasma Mass Spectrometry on both groups showed that the trace elements with the highest abundance were Mn (985–3390 ppm), Ni (531–3162 ppm), V (694–2510 ppm) and Zn (475–2230 ppm). Testing the effectiveness of trace elements in determining the source for Cr-spinels, we found out that Cr-spinels crystallised directly from a kimberlitic melt usually showed higher Mn, Ni, Sc and V concentrations with respect to those of peridotitic origin. In addition, using the available partitioning models, we found that the correlations between major elements and Ni, Co, Sc and Ga in the Xen group could be explained by subsolidus equilibration between spinel, olivine and clinopyroxene at 800–1000 °C, thus supporting a peridotitic source for this group. Finally, we calculated the composition of the possible melts in equilibrium with the Cr-spinels of the Chr group, using a selected set of partition coefficients. Calculated abundances of Cu, Ga and Zr were comparable to those of the kimberlite, while V was never close to the kimberlite composition. This simulation highlighted the need for new data on the trace elements partition coefficients between kimberlitic melts and Cr-spinel.