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On multimillion-year time scales, Earth has experienced warm ice-free and cold glacial climates, but it is unknown whether transitions between these background climate states were the result of changes in carbon dioxide sources or sinks. Low-latitude arc-continent collisions are hypothesized to drive cooling by exhuming and eroding mafic and ultramafic rocks in the warm, wet tropics, thereby increasing Earth’s potential to sequester carbon through chemical weathering. To better constrain global weatherability through time, the paleogeographic position of all major Phanerozoic arc-continent collisions was reconstructed and compared to the latitudinal distribution of ice sheets. This analysis reveals a strong correlation between the extent of glaciation and arc-continent collisions in the tropics. Earth’s climate state is set primarily by global weatherability, which changes with the latitudinal distribution of arc-continent collisions.

We present a framework for interpreting the carbon isotopic composition of sedimentary rocks, which in turn requires a fundamental reinterpretation of the carbon cycle and redox budgets over Earth's history. We propose that authigenic carbonate, produced in sediment pore fluids during early diagenesis, has played a major role in the carbon cycle in the past. This sink constitutes a minor component of the carbon isotope mass balance under the modern, high levels of atmospheric oxygen but was much larger in times of low atmospheric O 2 or widespread marine anoxia. Waxing and waning of a global authigenic carbonate sink helps to explain extreme carbon isotope variations in the Proterozoic, Paleozoic, and Triassic.

Iron-based proxies are used to track the redox chemistry of ancient oceans, but do not reveal the sharp oxygenation event in the late Proterozoic eon that is expected from previous evaluations of proxy records. A long-term record of ocean oxidation Measurements of iron speciation in ancient rocks are used in the reconstruction of the redox chemistry of ancient oceans. However, such iron proxy data reflect the local environment and it is difficult to draw conclusions relevant to past environmental conditions on a global scale. This study presents a comprehensive statistical analyses of more than 4,000 iron speciation measurements from shales and mudstones spanning a period between 2,300 and 360 million years ago that provides a global picture of past oceanic redox conditions. The analyses suggest that the oxidation state of the deep ocean remained anoxic and ferruginous throughout the Proterozoic with no statistically significant change in oxygen content through the Ediacaran and Cambrian periods, constraining the magnitude of the end-Proterozoic increase in oxygen levels. Sedimentary rocks deposited across the Proterozoic–Phanerozoic transition record extreme climate fluctuations, a potential rise in atmospheric oxygen or re-organization of the seafloor redox landscape, and the initial diversification of animals 1 , 2 . It is widely assumed that the inferred redox change facilitated the observed trends in biodiversity. Establishing this palaeoenvironmental context, however, requires that changes in marine redox structure be tracked by means of geochemical proxies and translated into estimates of atmospheric oxygen. Iron-based proxies are among the most effective tools for tracking the redox chemistry of ancient oceans 3 , 4 . These proxies are inherently local, but have global implications when analysed collectively and statistically. Here we analyse about 4,700 iron-speciation measurements from shales 2,300 to 360 million years old. Our statistical analyses suggest that subsurface water masses in mid-Proterozoic oceans were predominantly anoxic and ferruginous (depleted in dissolved oxygen and iron-bearing), but with a tendency towards euxinia (sulfide-bearing) that is not observed in the Neoproterozoic era. Analyses further indicate that early animals did not experience appreciable benthic sulfide stress. Finally, unlike proxies based on redox-sensitive trace-metal abundances 1 , 5 , 6 , iron geochemical data do not show a statistically significant change in oxygen content through the Ediacaran and Cambrian periods, sharply constraining the magnitude of the end-Proterozoic oxygen increase. Indeed, this re-analysis of trace-metal data is consistent with oxygenation continuing well into the Palaeozoic era. Therefore, if changing redox conditions facilitated animal diversification, it did so through a limited rise in oxygen past critical functional and ecological thresholds, as is seen in modern oxygen minimum zone benthic animal communities 7 , 8 , 9 .

After nearly a billion years with no evidence for glaciation, ice advanced to equatorial latitudes at least twice between 717 and 635 Mya. Although the initiation mechanism of these Neoproterozoic Snowball Earth events has remained a mystery, the broad synchronicity of rifting of the supercontinent Rodinia, the emplacement of large igneous provinces at low latitude, and the onset of the Sturtian glaciation has suggested a tectonic forcing. We present unique Re-Os geochronology and high-resolution Os and Sr isotope profiles bracketing Sturtian-age glacial deposits of the Rapitan Group in northwest Canada. Coupled with existing U-Pb dates, the postglacial Re-Os date of 662.4 ± 3.9 Mya represents direct geochronological constraints for both the onset and demise of a Cryogenian glaciation from the same continental margin and suggests a 55-My duration of the Sturtian glacial epoch. The Os and Sr isotope data allow us to assess the relative weathering input of old radiogenic crust and more juvenile, mantle-derived substrate. The preglacial isotopic signals are consistent with an enhanced contribution of juvenile material to the oceans and glacial initiation through enhanced global weatherability. In contrast, postglacial strata feature radiogenic Os and Sr isotope compositions indicative of extensive glacial scouring of the continents and intense silicate weathering in a post–Snowball Earth hothouse.

Steep topography, a tropical climate, and mafic lithologies contribute to efficient chemical weathering and carbon sequestration in the Southeast Asian islands. Ongoing arc–continent collision between the Sunda-Banda arc system and Australia has increased the area of subaerially exposed land in the region since the mid-Miocene. Concurrently, Earth’s climate has cooled since the Miocene Climatic Optimum, leading to growth of the Antarctic ice sheet and the onset of Northern Hemisphere glaciation. We seek to evaluate the hypothesis that the emergence of the Southeast Asian islands played a significant role in driving this cooling trend through increasing global weatherability. To do so, we have compiled paleoshoreline data and incorporated them into GEOCLIM, which couples a global climate model to a silicate weathering model with spatially resolved lithology. We find that without the increase in area of the Southeast Asian islands over the Neogene, atmospheric pCO₂ would have been significantly higher than preindustrial values, remaining above the levels necessary for initiating Northern Hemisphere ice sheets.

The oxygen isotope composition (δ18O) of marine sedimentary rocks has increased by 10 to 15 per mil since Archean time. Interpretation of this trend is hindered by the dual control of temperature and fluid δ18O on the rocks’ isotopic composition. A new δ18O record in marine iron oxides covering the past ∼2000 million years shows a similar secular rise. Iron oxide precipitation experiments reveal a weakly temperature-dependent iron oxide–water oxygen isotope fractionation, suggesting that increasing seawater δ18O over time was the primary cause of the long-term rise in δ18O values of marine precipitates. The 18O enrichment may have been driven by an increase in terrestrial sediment cover, a change in the proportion of high- and low-temperature crustal alteration, or a combination of these and other factors.

Changes in the geological sulfur cycle are inferred from the sulfur isotopic composition of marine barite. The structure of the 34S/32S record from the Mesozoic to present, which includes ∼50- and 100-Ma stepwise increases, has been interpreted as the result of microbial isotope effects or abrupt changes to tectonics and associated pyrite burial. Untangling the physical processes that govern the marine sulfur cycle and associated isotopic change is critical to understanding how climate, atmospheric oxygenation, and marine ecology have coevolved over geologic time. Here we demonstrate that the sulfur outgassing associated with emplacement of large igneous provinces can produce the apparent stepwise jumps in the isotopic record when coupled to long-term changes in burial efficiency. The record of large igneous provinces map onto the required outgassing events in our model, with the two largest steps in the sulfur isotope record coinciding with the emplacement of large igneous provinces into volatile-rich sedimentary basins. This solution provides a quantitative picture of the last 120 My of change in the ocean’s largest oxidant reservoir.

The Neoproterozoic was an era of great environmental and biological change, but a paucity of direct and precise age constraints on strata from this time has prevented the complete integration of these records. We present four high-precision U-Pb ages for Neoproterozoic rocks in northwestern Canada that constrain large perturbations in the carbon cycle, a major diversification and depletion in the microfossil record, and the onset of the Sturtian glaciation. A volcanic tuff interbedded with Sturtian glacial deposits, dated at 716.5 million years ago, is synchronous with the age of the Franklin large igneous province and paleomagnetic poles that pin Laurentia to an equatorial position. Ice was therefore grounded below sea level at very low paleolatitudes, which implies that the Sturtian glaciation was global in extent.

The triple oxygen isotope composition of sulphate minerals has been used to constrain the evolution of Earth’s surface environment (e.g., pO 2 , pCO 2 and gross primary productivity) throughout the Proterozoic Eon. This approach presumes the incorporation of atmospheric O 2 atoms into riverine sulphate via the oxidative weathering of pyrite. However, this is not borne out in recent geological or modern sulphate records, where an atmospheric signal is imperceptible and where terrestrial pyrite weathering occurs predominantly in bedrock fractures that are physically more removed from atmospheric O 2 . To better define the transition from a Proterozoic to a modern-like weathering regime, here we present new measurements from twelve marine evaporite basins spanning the Phanerozoic. These data display a step-like transition in the triple oxygen isotope composition of evaporite sulphate during the mid-Paleozoic (420 to 387.7 million years ago). We propose that the evolution of early root systems deepened the locus of pyrite oxidation and reduced the incorporation of O 2 into sulphate. Further, the early Devonian proliferation of land plants increased terrestrial organic carbon burial, releasing free oxygen that fueled increased redox recycling of soil-bound iron and resulted in the final rise in pO 2 to modern-like levels. Ancient sulfate mineral compositions reflect an increase in Earth’s oxidation state ~400 million years ago, likely including an increase in atmospheric oxygen levels and shift in mineral weathering pathways.

New constraints on the tectonic evolution of the Neo-Tethys Ocean indicate that at ∼90–70 Ma and at ∼50–40 Ma, vast quantities of mafic and ultramafic rocks were emplaced at low latitude onto continental crust within the tropical humid belt. These emplacement events correspond temporally with, and are potential agents for, the global climatic cooling events that terminated the Cretaceous Thermal Maximum and the Early Eocene Climatic Optimum. We model the temporal effects of CO₂ drawdown from the atmosphere due to chemical weathering of these obducted ophiolites, and of CO₂ addition to the atmosphere from arc volcanism in the Neo-Tethys, between 100 and 40 Ma. Modeled variations in net CO₂-drawdown rates are in excellent agreement with contemporaneous variation of ocean bottom water temperatures over this time interval, indicating that ophiolite emplacement may have played a major role in changing global climate. We demonstrate that both the lithology of the obducted rocks (mafic/ultramafic) and a tropical humid climate with high precipitation rate are needed to produce significant consumption of CO₂. Based on these results, we suggest that the low-latitude closure of ocean basins along east–west trending plate boundaries may also have initiated other long-term global cooling events, such as Middle to Late Ordovician cooling and glaciation associated with the closure of the Iapetus Ocean.