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This paper deals with the composition and chemical processes occurring in the neutral atmosphere of Venus. Since the last synthesis, observers as well as modellers have emphasised the spatial and temporal variability of minor species, going beyond a static and uniform picture that may have prevailed in the past. The outline of this paper acknowledges this situation and follows closely the different dimensions along which variability in composition can be observed: vertical, latitudinal, longitudinal, temporal. The strong differences between the atmosphere below and above the cloud layers also dictate the structure of this paper. Observational constraints, obtained from both Earth and Venus Express , as well as 1D, 2D and 3D models results obtained since 1997 are also extensively referred and commented by the authors. An non-exhaustive list of topics included follows: modelled and observed latitudinal and vertical profiles of CO and OCS below the clouds of Venus; vertical profiles of CO and SO 2 above the clouds as observed by solar occultation and modelled; temporal and spatial variability of sulphur oxides above the clouds. As a conclusion, open questions and topics of interest for further studies are discussed.

The current state and surface conditions of the Earth and its twin planet Venus are drastically different. Whether these differences are directly inherited from the earliest stages of planetary evolution, when the interior was molten, or arose later during the long-term evolution is still unclear. Yet, it is clear that water, its abundance, state, and distribution between the different planetary reservoirs, which are intimately related to the solidification and outgassing of the early magma ocean, are key components regarding past and present-day habitability, planetary evolution, and the different pathways leading to various surface conditions. In this chapter we start by reviewing the outcomes of the accretion sequence, with particular emphasis on the sources and timing of water delivery in light of available constraints, and the initial thermal state of Venus at the end of the main accretion. Then, we detail the processes at play during the early thermo-chemical evolution of molten terrestrial planets, and how they can affect the abundance and distribution of water within the different planetary reservoirs. Namely, we focus on the magma ocean cooling, solidification, and concurrent formation of the outgassed atmosphere. Accounting for the possible range of parameters for early Venus and based on the mechanisms and feedbacks described, we provide an overview of the likely evolutionary pathways leading to diverse surface conditions, from a temperate to a hellish early Venus. The implications of the resulting surface conditions and habitability are discussed in the context of the subsequent long-term interior and atmospheric evolution. Future research directions and observations are proposed to constrain the different scenarios in order to reconcile Venus’ early evolution with its current state, while deciphering which path it followed.

The abundance of SO dimers (SO) 2 in the upper atmosphere of Venus and their implications for the enigmatic ultraviolet absorption has been investigated in several studies over the past few years. However, the photochemistry of sulfur species in the upper atmosphere of Venus is still not well understood and the identity of the missing ultraviolet absorber(s) remains unknown. Here we update an existing photochemical model of Venus’ upper atmosphere by including the photochemistry of SO dimers. Although the spectral absorption profile of SO dimers fits the unknown absorber, their abundance is found to be too low for them to contribute significantly to the absorption. It is more likely that their photolysis and/or reaction products could contribute more substantively. Reactions of SO dimers are found to be important sources of S 2 O, and possibly higher order S n O species and polysulfur, S n . All of these species absorb in the critical ultraviolet region and are expected to be found in both the aerosol and gas phase. indicating that in-situ high resolution aerosol mass spectrometry might be a useful technique for identifying the ultraviolet absorber on Venus. Photochemistry of sulfur species in the upper Venus atmosphere is not well understood and the identity of ultraviolet (UV) absorber(s) remain unknown. Here, the authors show that sulfur monoxide dimer chemistry is a possible source of polysulfur, which could be responsible for the UV absorption.

The Venusian atmosphere hosts a 10 km deep convective layer that has been studied by various spacecrafts. However, the impact of the strong vertical mixing on the chemistry of this region is still unknown. This study presents the first realistic coupling between resolved small‐scale turbulence and a chemical network. The resulting vertical mixing is different for each species: those with longer chemical timescales will tend to be well‐mixed. Vertical eddy diffusion due to resolved convection motions was estimated, ranging from 102 to 104 m2/s for the 48–55 km convective layer, several orders of magnitude above the typically used value. In the 48–55 km convective layer, the impact of the small‐scale turbulence on the cloud layer boundaries was between 200 m and 1 km. The impact of turbulence on cloud chemistry is consistent with Venus Express/Visible and Infrared Thermal Imaging Spectrometer observations. The observability at the cloud‐top of small‐scale turbulence by VenSpec‐U spectrometer would be challenging. Plain Language Summary Venus hosts a global sulfuric acid cloud layer between 45 and 70 km. A convective layer is present between roughly 50 and 60 km, with its variability in latitude and local time assessed by observation, with a thicker layer at high latitude and at night. One question that remains unclear is how this turbulence mixes momentum, heat, and chemical species. Especially, the impact of the strong vertical mixing on the chemistry of this region is still unknown. To investigate this topic, we use a convection‐resolving model coupled for the first time with a realistic chemical network. The resulting vertical mixing is different for each species: those with longer chemical timescales will tend to be well‐mixed. 1D and global circulation models use the so‐called vertical eddy diffusion approach to represent turbulent motion, quantified in our model and underestimated in chemistry models. The small‐scale turbulence in the cloud layer causes a variation in the altitude of the top and bottom boundaries of the cloud. Our model shows that the impact of turbulence on cloud chemistry corresponds well to what has been observed by satellites. In the future, the EnVision mission will be able to observe chemical species at the small turbulence scales. Key Points Estimation for the first time of the spatial and temporal variability of chemical species due to vertical mixing Quantification of the vertical eddy diffusion coefficient, order of magnitude above typical used values Cloud‐top altitudes change by 0.2–1 km due to vertical convective mixing and gravity waves

This work reviews possible signatures and potential detectability of present-day volcanically emitted material in the atmosphere of Venus. We first discuss the expected composition of volcanic gases at present time, addressing how this is related to mantle composition and atmospheric pressure. Sulfur dioxide, often used as a marker of volcanic activity in Earth’s atmosphere, has been observed since late 1970s to exhibit variability at the Venus’ cloud tops at time scales from hours to decades; however, this variability may be associated with solely atmospheric processes. Water vapor is identified as a particularly valuable tracer for volcanic plumes because it can be mapped from orbit at three different tropospheric altitude ranges, and because of its apparent low background variability. We note that volcanic gas plumes could be either enhanced or depleted in water vapor compared to the background atmosphere, depending on magmatic volatile composition. Non-gaseous components of volcanic plumes, such as ash grains and/or cloud aerosol particles, are another investigation target of orbital and in situ measurements. We discuss expectations of in situ and remote measurements of volcanic plumes in the atmosphere with particular focus on the upcoming DAVINCI, EnVision and VERITAS missions, as well as possible future missions.

Even though a thick atmosphere stands between Venus's cloud top and its surface, recent observations now establish the impact of Venus's topography on its upper atmospheric dynamics. Understanding how this is possible will lead to substantial progress in atmospheric computer models.

Earth has had oceans for nearly four billion years 1 and Mars had lakes and rivers 3.5–3.8 billion years ago 2 . However, it is still unknown whether water has ever condensed on the surface of Venus 3 , 4 because the planet—now completely dry 5 —has undergone global resurfacing events that obscure most of its history 6 , 7 . The conditions required for water to have initially condensed on the surface of Solar System terrestrial planets are highly uncertain, as they have so far only been studied with one-dimensional numerical climate models 3 that cannot account for the effects of atmospheric circulation and clouds, which are key climate stabilizers. Here we show using three-dimensional global climate model simulations of early Venus and Earth that water clouds—which preferentially form on the nightside, owing to the strong subsolar water vapour absorption—have a strong net warming effect that inhibits surface water condensation even at modest insolations (down to 325 watts per square metre, that is, 0.95 times the Earth solar constant). This shows that water never condensed and that, consequently, oceans never formed on the surface of Venus. Furthermore, this shows that the formation of Earth’s oceans required much lower insolation than today, which was made possible by the faint young Sun. This also implies the existence of another stability state for present-day Earth: the ‘steam Earth’, with all the water from the oceans evaporated into the atmosphere. Global climate model simulations of early Venus and Earth show that differences in the cloud regimes prevented ocean formation on Venus but not on Earth.

Nightside observations of the 1.18‐μm atmospheric window by the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) aboard the Venus Express spacecraft were analyzed to measure and map the water vapor abundance in the lower atmosphere. Thermal emission in this window originates partly from the surface and partly from the first scale height (0–15 km) of the atmosphere. Constraints on the CO2 continuum absorption, which is the dominant source of gaseous opacity in the window, were obtained from the variation of the 1.185‐μm intensity with surface elevation. An absorption coefficient of 1 ± 0.4 × 10−9 cm−1 amagat−2 best fits the observed variation. We retrieved a water vapor mole fraction of 44 ± 9 ppm from various selections of VIRTIS spectra in the southern hemisphere, in agreement with previous analyses of the nightside emission. This value is somewhat larger than that previously determined at higher altitudes from the 2.3‐ and 1.74‐μm nightside windows, but the error bars still allow a constant with height H2O mole fraction from the surface up to 40 km. Using the intensity ratio in the two wings of the 1.18‐μm window as a proxy, we searched for horizontal variations of the H2O abundance in various VIRTIS observational sequences. We derived stringent upper limits for any possible latitudinal variations on the night side: ±1.5% in the range 60°S–25°N and ±3% for the broader range 80°S–25°N. The lack of detectable latitudinal variations is consistent with a constant with height water profile in the lower atmosphere and probably precludes any strong concentration gradient near the surface.

In order to understand the early history of telluric interiors and atmospheres during the ocean magma stage, a coupled interior‐atmosphere‐escape model is being developed. This paper describes the atmospheric part and its first preliminary results. A unidimensional, radiative‐convective, H2O‐CO2 atmosphere is modeled following a vertical T(z) profile similar to Kasting (1988) and Abe and Matsui (1988). Opacities in the thermal IR are then computed using a k‐correlated code (KSPECTRUM), tabulated continuum opacities for H2O‐H2O and CO2‐CO2 absorption, and water or sulphuric acid clouds in the moist convective zone (whenever present). The first results show the existence of two regimes depending on the relative value of the surface temperature Ts compared to a threshold temperature Tc depending on the total gaseous inventory. For Ts < Tc, efficient blanketing results in a cool upper atmosphere, a cloud cover, and a long lifetime for the underneath magma ocean with a net thermal IR flux between 200 and 280 Wm−2. For Ts > Tc, the blanketing is not efficient enough to prevent large radiative heat loss to space through a hot, cloudless atmosphere. Our current calculations may underestimate the thermal flux in the case of hot surfaces with little gaseous content in the atmosphere. Key Points Atmospheric blanketing above magma oceans rules their cooling time Blanketing efficiency depends on surface temperature and atmospheric content This simple model is perfectly suited for integration into coupled models

A pulse of sulphur dioxide in Venus’s upper atmosphere was observed by the Pioneer Venus spacecraft in the 1970s and 1980s and attributed to volcanism. Recent sulphur dioxide measurements from Venus Express indicate decadal-scale fluctuations in sulphur dioxide above Venus’s cloud tops in an atmosphere that is more dynamic than expected. Sulphur dioxide is a million times more abundant in the atmosphere of Venus than that of Earth, possibly as a result of volcanism on Venus within the past billion years 1 , 2 . A tenfold decrease in sulphur dioxide column density above Venus’s clouds measured by the Pioneer Venus spacecraft during the 1970s and 1980s has been interpreted as decline following an episode of volcanogenic upwelling from the lower atmosphere 3 , 4 . Here we report that the sulphur dioxide column density above Venus’s clouds decreased by an order of magnitude between 2007 and 2012 using ultraviolet spectrometer data from the SPICAV instrument onboard the Venus Express spacecraft. This decline is similar to observations during the 1980s. We also report strong latitudinal and temporal variability in sulphur dioxide column density that is consistent with supply fluctuations from the lower atmosphere. We suggest that episodic sulphur dioxide injections to the cloud tops may be caused either by periods of increased buoyancy of volcanic plumes, or, in the absence of active volcanism, by long-period oscillations of the general atmospheric circulation. The 30-year observational record from Pioneer Venus and Venus Express confirms that episodic injections of sulphur dioxide above the clouds recur on decadal timescales, suggesting a more variable atmosphere than expected.