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Following the increase in stringency of the European regulation limits for laboratory and real world automotive emissions, one of the main transport related aspects to improve the air quality is the mass scale in-use vehicle testing. Solid particle number (SPN) emissions have been drastically reduced with the use of diesel and gasoline particulate filters which, however, may get damaged or even been tampered. The feasibility of on-board monitoring and remote sensing as well as of the current periodical technical inspection (PTI) for detecting malfunctioning or tampered particulate filters is under discussion. A promising methodology for detecting high emitters is SPN testing at low idling during PTI. Several European countries plan to introduce this method for diesel vehicles and the European Commission (EC) will provide some guidelines. For this scope an experimental campaign was organized by the Joint Research Centre (JRC) of the EC with the participation of different instrument manufacturers. Idle SPN concentrations of vehicles without or with a malfunctioning particulate filter were measured. The presence of particles under the current cut-off size of 23 nm as well as of volatile particles during idling are presented. Moreover, the extreme case of a well performing vehicle tested after a filter regeneration is studied. In most of the cases the different sensors used were in good agreement, the high sub-23 nm particles existence being the most challenging case due to the differences in the sensors’ efficiency below the cut-off size.

Vehicle emissions are a significant source of air pollution in cities. Particulate matter (PM) is a pollutant with adverse health effects. Regulations worldwide determine the PM exhaust emissions of vehicles by gravimetric quantification of the mass deposited on a filter over a test cycle. The introduction of particulate filters as vehicle exhaust gas aftertreatment devices led to low PM emissions. A particle number methodology (counting solid particles > 23 nm), complementary to the PM mass measurement, was developed by the PMP (Particle Measurement Programme) group of the GRPE (Working Party on Pollution and Energy) of the UNECE (United Nations Economic Commission for Europe) during the first decade of the 21st century. The methodology was then introduced in the EU (European Union) regulations for light-duty (2011), heavy-duty (2013), and non-road mobile machinery (2019). In parallel, during the last 15 years, UN (United Nations) regulations and GTRs (Global Technical Regulations) including this methodology were also developed. To address the on-road emissions, the EU introduced RDE (real-driving emissions) testing with PEMS (portable emissions measurement systems) in 2017. Other countries (e.g., China, India) have also started adopting the number methodology. The PMP group recently improved the current laboratory and on-board methodologies and also extended them to a lower particle size (counting solid particles > 10 nm). Due to the rapid evolution of the vehicle exhaust particle number regulations and the lack of a summary in the literature, this paper gives an overview of current and near future regulations. Emphasis is given on the technical specifications and the changes that have taken place over the years.

Thousands of particle number (PN) counters have been introduced to the European market, following the implementation of PN tests during the periodic technical inspection (PTI) of diesel vehicles equipped with particulate filters. Expanding the PN-PTI test to gasoline vehicles may face several challenges due to the different exhaust aerosol characteristics. In this study, two PN-PTI instruments, type-examined for diesel vehicles, measured fifteen petrol passenger cars with different test protocols: low and high idling, with or without additional load, and sharp accelerations. The instruments, one based on diffusion charging and the other on condensation particle counting, demonstrated good linearity compared to the reference instrumentation with R-squared values of 0.93 and 0.92, respectively. However, in a considerable number of tests, they registered higher particle concentrations due to the presence of high concentrations below their theoretical 23 nm cut-off size. The evaluation of the different test protocols showed that gasoline direct injection engine vehicles without particulate filters (GPFs) generally emitted an order of magnitude or higher PN compared to those with GPFs. However, high variations in concentration levels were observed for each vehicle. Port-fuel injection vehicles without GPFs mostly emitted PN concentrations near the lower detection limit of the PN-PTI instruments.

Vehicle emission regulations in Europe and many Asian countries include a particle number limit. The number concentration is measured, typically, with condensation particle counters (CPCs). For research purposes, the size distributions provide useful information. Scanning mobility particle sizers (SMPSs) accurately provide the size distribution but are not suitable for transient aerosol. Engine (fast) exhaust particle sizers (EEPSs) cover this gap, but with less accuracy. Fast size distribution instruments are commonly used in the research and development of engines. In the last few years, instrument algorithms have been improved, but studies assessing the improvements are limited, in particular in their lower size range, around 10–20 nm, and for soot-like aerosol. In this paper, we compared the three instruments using salt, silver, diffusion flame soot (CAST), and spark discharge graphite particles. Moreover, vehicle exhaust number concentration measurements with EEPSs over a seven-year period were presented. In terms of particle concentration, EEPS overestimated, on average, 25% compared to CPC, in agreement with previous studies. Its accuracy for mean particle size determination was better than 5 nm compared to SMPS. The agreement between the instruments was satisfactory but the uncertainty increased at low concentrations and larger particle sizes, showing that there is still room for further improvements. Experimental challenges, such as low concentration levels of modern vehicles, losses in the diluters, use of photometric mode by the CPCs, and the material impact, are also discussed.

In Europe and Asia, vehicle emissions regulations include a number limit for particles larger than 23 nm, which might be reduced to 10 nm in the future. A particle number system (LABS) consists of a volatile particle remover (VPR) and a particle number counter (PNC). However, it is not simple to derive the combined penetration (efficiency), because the parts are calibrated separately at different sizes and with different materials. On the other hand, portable emissions measurement systems (PEMS) for real-driving emissions (RDE) testing or counters for periodical technical inspection (PTI) of vehicle exhaust are calibrated as complete units with soot-like aerosol. The aim of this study is to estimate the efficiency of a LABS using different materials (soot, graphite, salt, silver, emery oil), typically used for the calibration of LABS, PEMS or PTI counters. The results show that appropriate selection of the calibration material is important in order to have representative of the reality efficiencies. The impact is very high for 23 nm systems, but less critical for 10 nm systems. The estimation of a mean size based on the ratio of 23 nm and 10 nm measurements and the correction of the losses in the sub-23 nm region are also discussed.

Road transport is a relevant source of greenhouse gas emissions. In order to meet the European decarbonisation targets, the share of electrified vehicles, including battery electric vehicles and plug-in hybrid electric vehicles (PHEVs), is rapidly growing, becoming the second most popular powertrain in the European market. PHEVs are of interest since they are expected to deliver a reduction in gaseous pollutants such as NOx as well as in greenhouse gases such as CO2. Herein, we explored both categories of emissions for three PHEVs with gasoline direct-injection engines, meeting the latest European emission standards (Euro 6d and Euro 6d-TEMP). They were studied in laboratory and on the road, in different modalities and temperatures. All tested vehicles met the Euro 6 emission limits in the Worldwide Harmonised Light-Duty Vehicles Test Procedure (WLTP) and the real driving emissions (RDE) test procedure. Still, when their internal combustion engine ignited even for a few km, their emissions were comparable to, and in some cases higher than, the average emissions reported for a fleet of eight conventional Euro 6d-TEMP gasoline direct-injection vehicles. The tested PHEVs presented similar trends to those of conventional vehicles, such as the increase in all pollutants considered at low ambient temperature or the high CO emissions during acceleration events, concomitantly with NH3. Moreover, depending on the boundary conditions, emissions were higher for the vehicles with a battery fully charged with respect to tests performed with the depleted battery. Furthermore, the use of an operating mode that allowed charging the vehicles’ high voltage battery using the internal combustion engine had a very strong impact on the vehicles’ CO2 emissions, offsetting the benefits in terms of greenhouse gas reduction demonstrated in other conditions. The results indicate that for the sample tested, the expected reduction in pollutants emission due to the presence of a hybrid gasoline-electric traction seemed in some cases limited, also showing high variability. CO2 emissions were also affected by the initial state of charge of the vehicles’ high voltage battery as well as from the user-selectable operating mode, also in this case with high variability.

Road transport significantly contributes to air pollution in cities. Emission regulations have led to significantly reduced emissions in modern vehicles. Particle emissions are controlled by a particulate matter (PM) mass and a solid particle number (SPN) limit. There are concerns that the SPN limit does not effectively control all relevant particulate species and there are instances of semi-volatile particle emissions that are order of magnitudes higher than the SPN emission levels. This overview discusses whether a new metric (total particles, i.e., solids and volatiles) should be introduced for the effective regulation of vehicle emissions. Initially, it summarizes recent findings on the contribution of road transport to particle number concentration levels in cities. Then, both solid and total particle emission levels from modern vehicles are presented and the adverse health effects of solid and volatile particles are briefly discussed. Finally, the open issues regarding an appropriate methodology (sampling and instrumentation) in order to achieve representative and reproducible results are summarized. The main finding of this overview is that, even though total particle sampling and quantification is feasible, details for its realization in a regulatory context are lacking. It is important to define the methodology details (sampling and dilution, measurement instrumentation, relevant sizes, etc.) and conduct inter-laboratory exercises to determine the reproducibility of a proposed method. It is also necessary to monitor the vehicle emissions according to the new method to understand current and possible future levels. With better understanding of the instances of formation of nucleation mode particles it will be possible to identify its culprits (e.g., fuel, lubricant, combustion, or aftertreatment operation). Then the appropriate solutions can be enforced and the right decisions can be taken on the need for new regulatory initiatives, for example the addition of total particles in the tailpipe, decrease of specific organic precursors, better control of inorganic precursors (e.g., NH3, SOx), or revision of fuel and lubricant specifications.

Formaldehyde (HCHO), a carcinogenic carbonyl compound and precursor of tropospheric ozone, can be found in vehicle exhaust. Even though the continuous monitoring of HCHO has been recommended, the real-world emissions from the road transport sector are not commonly available. The main reason for this knowledge gap has been the difficulty to measure HCHO in real-time and during real-world testing. This, for instance, increases the uncertainty of the O3 simulated by air quality models. The present study investigates real-time HCHO measurements comparing three Fourier Transform InfraRed spectrometers (FTIRs) and one Quantum Cascade Laser InfraRed spectrometer (QCL-IR) directly sampling from the exhaust of one gasoline passenger car, one Diesel commercial vehicle and one Diesel heavy-duty vehicle, all meeting recent European emission standards (Euro 6/VI). Non-negligible emissions of HCHO were measured from the Diesel light-duty vehicle, with emissions increasing as temperature decreased. Relatively low emissions were measured for the gasoline car and the Diesel heavy-duty vehicle. The results showed a good correlation between the different instruments under all the conditions tested (in most cases R2 > 0.9). Moreover, it was shown that HCHO can be accurately measured during on-road and real-world-like tests using instruments based on FTIR and QCL-IR technologies.

The European Union (EU) has introduced since the early 1990s a series of progressively more stringent emission regulations to control air pollution from the transport sector, commonly known as Euro standards. Following this path, more recently, with the European Green Deal, the European Commission has indicated the intention to review the current air pollutant emissions standards. This study investigates the emission performance of an advanced demonstrator vehicle developed to meet the increasingly more stringent air pollution limits required. Emissions of currently regulated and unregulated components including NH3, N2O, and SPN10 (solid particle number), were studied in a very wide range of real-world operative conditions. The performance of two new generation portable instruments for the onboard measurement of N2O and NH3 were also evaluated in comparison with reference laboratory equipment. Similarly, the measurement accuracy of onboard NOx sensors was also compared to laboratory reference. The vehicle presented low emissions of NOx and NH3 and relatively low emissions of N2O, also compared to data currently available in the literature, in a broad range of operative conditions, which however resulted in a large variability in emissions.

On-road real-driving emissions (RDE) tests with portable emissions measurement systems (PEMS) are part of the vehicle emissions regulations in the European Union (EU). For a given vehicle, the final emission results depend on the influence of the ambient conditions and the trip characteristics (including the driver’s behaviour) on the vehicle performance and the instrument measurement uncertainty. However, there are not many studies that have examined the emissions variability of a single vehicle following different routes. In this study, a 1.2 L gasoline direct injection (GDI) Euro 5b passenger car without a particulate filter and a PEMS was circulated in seven European laboratories. At their premises, the laboratories performed two to five repetitions of on-road trips compliant with the EU RDE regulation. The ambient temperature ranged between 7 °C and 23 °C. The average emission levels of the vehicle were 135 g/km for CO2, 77 mg/km for CO, 55 mg/km for NOx, and 9.2 × 1011 #/km for particle number. The coefficient of variance in the emissions following the same route was 2.9% for CO2, 23.8% for CO, 23.0% for NOx, and 5.8% for particle number. The coefficient of variance in the emissions following different routes in Europe was 6.9% for CO2, 9.1% for CO, 0.0% for NOx, and 9.1% for particle number. The previous values include the specific vehicle emissions variability under the narrow test conditions of this study, but only partly the PEMS measurement uncertainty because the same instrument was used in all the trips. The results of this study can be used by laboratories conducting RDE tests to assess their uncertainty budget when testing or comparing vehicles of similar technology.