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result(s) for
"Molle, Pascal"
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French vertical flow constructed wetlands: A need of a better understanding of the role of the deposit layer
by
Milieux aquatiques, écologie et pollutions (UR MALY) ; Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)
,
Molle, Pascal
in
Applied sciences
,
Artificial wetlands
,
Biological activity
2014
French vertical flow constructed wetlands, treating directly raw wastewater, have become the main systems implemented for communities under 2,000 population equivalent in France. Like in sludge drying reed beds, an organic deposit layer is formed over time at the top surface of the filter. This deposit layer is a key factor in the performance of the system as it impacts hydraulic, gas transfers, filtration efficiency and water retention time. The paper discusses the role of this deposit layer on the hydraulic and biological behaviour of the system. It presents results from different studies to highlight the positive role of the layer but, as well, the difficulties in modelling this organic layer. As hydraulic, oxygen transfers, and biological activity are interlinked and impacted by the deposit layer, it seems essential to focus on its role (and its quantification) to find new developments of vertical flow constructed wetlands fed with raw wastewater.
Journal Article
Wetland systems for water pollution control
by
Chazarenc, Florent
,
Déchets Eaux Environnement Pollutions (DEEP) ; Institut National des Sciences Appliquées de Lyon (INSA Lyon) ; Université de Lyon-Institut National des Sciences Appliquées (INSA)-Université de Lyon-Institut National des Sciences Appliquées (INSA)
,
Molle, Pascal
in
Environmental Engineering
,
Environmental Sciences
,
Water Pollution - prevention & control
2024
Journal Article
Long-term investigations on ammonium removal with zeolite in compact vertical flow treatment wetlands under field conditions
by
Chazarenc, Florent
,
Molle, Pascal
,
Réduire, valoriser, réutiliser les ressources des eaux résiduaires (UR REVERSAAL) ; Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)
in
Ammonium
,
Ammonium Compounds
,
Ammonium nitrogen
2022
The scope of this study was to investigate if using zeolite as a reactive material in a vertical-flow wetland under field conditions improves ammonium removal from domestic wastewater in the long term. The experimental setup consisted of two pilot-scale first stage French vertical flow treatment wetlands (2.3 m2 surface area each), which were implemented under field scale conditions inside a wastewater treatment plant in the central region of France (L'Encloitre, 37360). The filters were operated during 27 months. A compact pilot containing Leca® as a main filtration layer (Ø 1–5 mm) was compared to a similar one filled with natural zeolite (Ø 2–5 mm). The pilots were fed according to regular feeding/resting periods (3½/7 days) and the nominal loading rate was of 300 g COD m−2 d−1 and 33 g·N·m−2·d−1 during operation. In both pilots, results showed a removal efficiency of more than 90 and 85% for TSS and COD, respectively. They also showed an increased NH4-N removal of 9% on average (total removal efficiency of 84%) with the use of zeolite compared to Leca®. The ion exchange capacity of zeolite seemed not to be affected after 27 months of experiments; however, the material was compacted and more friable after operation.
Journal Article
Phosphorus retention by granulated apatite: assessing maximum retention capacity, kinetics and retention processes
2021
Abstract Natural apatites have previously shown a great capacity for phosphate retention from wastewater. However, its fine particle size distribution may lead to a premature clogging of the filter. Accordingly, a granulated apatite product was developed and manufactured in order to control the particle size distribution of the media. Experiments were conducted on laboratory columns to assess their phosphorus retention capacity, to identify the processes involved in phosphorus retention and to evaluate their kinetic rates. The results showed phosphorus retention capacities of 10.5 and 12.4 g PO4-P·kg−1 and kinetic rate coefficients in the range of 0.63 and 0.23 h−1 involving lower values than those found for natural apatites in previous studies. Scanning Electron Microscopy images showed that apatite particles in the granules were embedded in the binder and were not readily accessible to act as seeds for calcium phosphate precipitation. The retention processes differ depending on the supersaturation of the solution with respect to calcium phosphate phases: at low calcium concentrations (69.8 ± 3.9 mg·L−1), hydroxyapatite precipitates fill up the porosity of the binder up to a depth of 100–300 μm from the granule surface; at higher calcium concentrations (112.7 ± 7.4 mg·L−1) precipitation occurs at the granule surface, forming successive layers of hydroxyapatite and carbonated calcium phosphates.
Journal Article
Seeded phosphorus retention in fixed-bed laboratory columns by the use of apatites
by
Delgado-González, Laura
,
Molle, Pascal
,
Troesch, Stéphane
in
amorphous calcium phosphate
,
Environmental Sciences
,
phosphate recovery
2022
Phosphorus retention in small- and medium-sized wastewater treatment plants is crucial to preventing the eutrophication of downstream catchments. One popular solution in combination with treatment wetlands is the use of reactive filters for phosphorus retention; however, identifying a suitable substrate is not an easy task in this process. Apatites have already proven to be an effective alternative for phosphorus retention, yet more in-depth research is needed. This article uses two natural apatite materials, NA1 and NA2, introduced in four fixed-bed laboratory columns to assess their phosphorus retention capacity. Various inflow conditions are set for the NA1 substrate to evaluate the impact of calcium and biomass development on performance. The substrates show high phosphorus retention (>16.8 g PO 4 -P/kg for NA1 and >17.5 g PO 4 -P/kg for NA2) as well as high kinetic rate coefficients (1.45 and 1.70 h −1 for NA1 and NA2, respectively), with performances above 80% for both substrates. The maximum phosphorus retention capacity is not attained at the end of the experiments, despite their long duration (230 days) and the short hydraulic residence times applied (∼2 h), thus suggesting a long-term removal capacity. The NA1 column fed with a calcium-deficient synthetic solution displays just slightly reduced kinetic rates, most likely due to calcite and dolomite dissolution from the media. The column fed with treated wastewater does not reveal any significant reduction in hydraulic conductivity due to biomass development. No loss of permeability due to chemical clogging was observed in the other columns. Scanning electron microscopy indicates that phosphorus retention occurs by the precipitation of amorphous calcium phosphate for both natural apatites, thereby clearly demonstrating the implementation of seeding mechanisms. Such a retention process is sustainable, which suggests it may proceed over even higher retention capacities.
Journal Article
Septage unit treatment by sludge treatment reed beds for easy management and reuse: performance and design considerations
by
Bourdoncle, Pascal
,
Molle, Pascal
,
Troesch, Stéphane
in
Agricultural Irrigation
,
Agricultural management
,
Analytical chemistry
2018
Sustainable treatment and management of fecal sludge in rural areas require adapted solutions. Rustic and simple operating processes such as sludge treatment reed beds (STRB) have been increasingly considered for this purpose. The biggest full scale (2,600 m2 of STRB) septage treatment unit in France had been built in Nègrepelisse with the final objectives of reusing treated sludge and leachates for agriculture spreading and tree irrigation, respectively. The aim of this investigation was to validate the treatment chain of this installation. The obtained field data showed firstly that the overall removal efficiencies of STRB were satisfactory and stable. Removal rates higher than 98% for chemical oxygen demand and suspended solids and a 95% for Kjeldahl nitrogen represented so far a beneficial septage treatment by STRB. The highlighted necessity of a suitable complementary leachate treatment (before tree irrigation) justified the presence of the second stage of vertical flow constructed wetland. The sludge deposit drying and mineralization efficiencies were on the right track. According to hydrotextural diagram analysis, surface deposit was however found to have high deformability probably due to the youth of the installation. An in-depth understanding of STRB system needs continuous long-term studies.
Journal Article
Treatment performances of French constructed wetlands: Results from a database collected over the last 30 years
by
Molle, Pascal
,
Troesch, S
,
Morvannou, A
in
Advection
,
Artificial wetlands
,
Biological Oxygen Demand Analysis
2015
Approximately 3,500 constructed wetlands (CWs) provide raw wastewater treatment in France for small communities (<5,000 people equivalent). Built during the past 30 years, most consist of two vertical flow constructed wetlands (VFCWs) in series (stages). Many configurations exist, with systems associated with horizontal flow filters or waste stabilization ponds, vertical flow with recirculation, partially saturated systems, etc. A database analyzed 10 years earlier on the classical French system summarized the global performances data. This paper provides a similar analysis of performance data from 415 full-scale two-stage VFCWs from an improved database expanded by monitoring data available from Irstea and the French technical department. Trends presented in the first study are confirmed, exhibiting high chemical oxygen demand (COD), total suspended solids (TSS) and total Kjeldahl nitrogen (TKN) removal rates (87%, 93% and 84%, respectively). Typical concentrations at the second-stage outlet are 74 mgCOD L−1, 17 mgTSS L−1 and 11 mgTKN L−1. Pollutant removal performances are summarized in relation to the loads applied at the first treatment stage. While COD and TSS removal rates remain stable over the range of applied loads, the spreading of TKN removal rates increases as applied loads increase.
Journal Article
Performance assessment of a vertical flow constructed wetland treating unsettled combined sewer overflow
by
Gourdon, R.
,
Molle, P.
,
Pálfy, T. G.
in
Ammonium nitrogen
,
Aromatic compounds
,
Aromatic hydrocarbons
2017
The performance of a vertical flow constructed wetland for combined sewer overflow treatment (CSO CW) has been evaluated. The full-scale site has been monitored for 3 years for major pollutants and for two load events for a range of micropollutants (metals, metalloids and polycyclic aromatic hydrocarbons (PAHs)). Performance were predominantly high (97% for total suspended solids (TSS), 80% for chemical oxygen demand (COD), 72% for NH4-N), even if several loads were extremely voluminous, pushing the filter to its limits. Two different filter materials (a 4:1 mixture of sand and zeolite and natural pozzolana) showed similar treatment performance. Furthermore, environmental factors were correlated with COD removal efficiency. The greatest influencers of COD removal efficiency were the inlet dissolved COD concentrations and the duration and potential evapotranspiration during inter-event periods. Furthermore, sludge was analysed for quality and a sludge depth map was created. The map, and calculating the changes in sludge volume, helped to understand solid accumulation dynamics.
Journal Article
Constructed wetlands and solar-driven disinfection technologies for sustainable wastewater treatment and reclamation in rural India: SWINGS project
by
Ameršek, I
,
Arias Isaza, Carlos Alberto de Jesús
,
Otter, P
in
Agricultural economics
,
Agricultural production
,
Ammonium nitrogen
2017
The largest wastewater treatment plant consists of a high-rate anaerobic system, followed by vertical and horizontal subsurface flow constructed wetlands (HFCW) with a treatment area of nearly 1900 sq m and a final step consisting of solar-driven anodic oxidation and ultraviolet disinfection units allowing direct reuse of the treated water. and even act as a revenue generator. The effluent of the HFCW is collected in a 1.8 m deep well, from where about 10% of the final effluent is pumped and disinfected using the two solar-powered units. The implementation of the systems under the umbrella of the SWINGS project will provide opportunity to tes advanced CW configurations operating to meet local needs.
Journal Article
Performance and reliability comparison of French vertical flow treatment wetlands with other decentralized wastewater treatment technologies in tropical climates
by
Oucacha, Chafatayne
,
Molle, Pascal
,
Lacombe, Gérald
in
Brazil
,
Chemical oxygen demand
,
Earth Sciences
2020
When implementing a sanitation system, the selection of treatment process can be difficult. Beyond removal efficiency and effluent concentrations, reliability should be taken into account. This study compares reliability of French vertical flow treatment wetlands (F-VFTW) with the four main decentralized wastewater treatment technologies in small communities in the French Overseas Territories (FOT). Analysis of 963 regulatory self-monitoring sampling campaigns performed on 213 wastewater treatment plants show that operational disruptions due to sludge loss and loss of nitrification are often reported for activated sludge technology; rotating biological contactors often suffer from weak settlement; facultative pond removal is limited by algae; and F-VFTW fulfills all the French regulatory objectives at a frequency of 90 to 95%. In addition, the data from this study are compared to a similar database from Brazil using a statistical approach (coefficient of reliability). Amongst the eight decentralized wastewater treatment technologies evaluated, F-VFTW appears to be the most appropriate for achieving the discharge standard with a reliability close to 95%. Its reliability to face both environmental (rainfall) and social (maintenance capacities) constraints is a key parameter.
Journal Article