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We present new thermometers and barometers based on clinopyroxene–liquid equilibria specific to alkaline differentiated magmas. The new models were calibrated through the regression analyses of experimental datasets obtained by merging phase equilibria experiments from the literature with new experiments performed by using trachytic and phonolitic starting compositions. The regression strategy was twofold: (1) we have tested previous thermometric and barometric equations and recalibrated these models using the new datasets; (2) we have calibrated a new thermometer and a new barometer including only regression parameters that closely describe the compositional variability of the datasets. The new models yield more precise estimates than previous thermometers and barometers when used to predict temperatures and pressures of alkaline differentiated magmas. We have tested the reliability of the new equations by using clinopyroxene–liquid pairs from trachytes and phonolites erupted during major explosive eruptions at the Phlegrean Fields and Mt. Vesuvius (central Italy). The test yielded crystallization conditions comparable to those determined by means of melt and fluid inclusion analyses and phase equilibria studies; this validates the use of the proposed models for precise estimates of crystallization temperatures and pressures in differentiated alkaline magmas. Because these magmas feed some of the most voluminous, explosive, and threatening volcanic eruptions in the world, a better understanding of the environmental conditions of their reservoirs is mandatory and this is now possible with the new models provided here.

We present the variation in trace element partition coefficients measured at the interface between rapidly cooled clinopyroxene crystals and co-existing melts. Results indicate that, as the cooling rate is increased, clinopyroxene crystals are progressively depleted in Si, Ca and Mg counterbalanced by enrichments in Al (mainly tetrahedral Al iv ), Na and Ti. Partition coefficients (Ds) for rare earth elements (REE), high field strength elements (HFSE) and transition elements (TE) increase with increasing cooling rate, in response to clinopyroxene compositional variations. The entry of REE into the M2 site is facilitated by a coupled substitution where either Na substitutes for Ca on the M2 site or Al iv substitutes for Si in the tetrahedral site. The latter substitution reflects an increased ease of locally balancing the excess charge at M2 as the number of surrounding Al iv atoms increases. Due to the lower concentration of Ca in rapidly cooled clinopyroxenes, divalent large ion lithophile elements (LILE) on M2 decrease at the expense of monovalent cations. Conversely, higher concentrations of HFSE and TE on the M1 site are facilitated as the average charge on this site increases with the replacement of divalent-charged cations by Al vi . Although crystallization kinetics modify clinopyroxene composition, deviations from equilibrium partitioning are insufficient to change the tendency of a trace element to be compatible or incompatible. Consequently, there are regular relationships between ionic radius, valence of the trace element and D. At both equilibrium and cooling rate conditions, Ds for isovalent cations define parabola-like curves when plotted against ionic radius, consistent with the lattice strain model, demonstrating that the partitioning of trace elements is driven by charge balance mechanisms; cation substitution reactions can be treated in terms of the energetics of the various charge-imbalanced configurations.

Open‐conduit conditions characterize several of the most hazardous and active volcanic systems of basaltic composition worldwide, persistently refilled by magmatic inputs. Eruptive products with similar bulk compositions, chemically buffered by continual mafic inputs, nevertheless exhibit heterogeneous glass compositions in response to variable magma mixing, crystallization, and differentiation processes within different parts of the plumbing system. Here, we document how multivariate statistics and magma differentiation modeling based on a large data set of glass compositions can be combined to constrain magma differentiation and plumbing system dynamics. Major and trace elements of matrix glasses erupted at Stromboli volcano (Italy) over the last 20 years provide a benchmark against which to test our integrated petrological approach. Principal component analysis, K‐means cluster analysis, and kernel density estimation reveal that trace elements define a multivariate space whose eigenvectors are more readily interpretable in terms of petrological processes than major elements, leading to improved clustering solutions. Comparison between open‐ and closed‐system differentiation models outlines that steady state magma compositions at constantly replenished and erupting magmatic systems approximate simple fractional crystallization trends, due to short magma residence times. Open‐system magma evolution is associated with magma storage crystallinities that are lower than those associated with closed‐system scenarios. Accordingly, open‐system dynamics determine the efficient crystal‐melt separation toward the top of the reservoir, where eruptible melts continuously supply the ordinary activity. Conversely, a mush‐like environment constitutes the bottom of the reservoir, where poorly evolved magmas result from mixing events between mush residual melts and primitive magmas injected from deeper crustal levels. Plain Language Summary Volcanoes characterized by continuous eruptive activity are typified by constant replenishment of new magma, rising from deeper regions of the crust. The volcanic glass (supercooled silicate melt), represents the residual liquid of magma crystallization, and is found as the intracrystalline matrix of eruptive products. The study of its chemical composition may provide insight into the processes occurring at depths beneath the volcanic vent, where magma compositional changes result from crystallization and mixing with new magma rising from depth. We combine statistical analyses and analytical equations based on the chemical composition of the matrix glasses from Stromboli volcano, in order to constrain the processes which produce their chemical variations, identifying different environments where magmas are stored at depth. Our results also show that when magma is stored for a short period of time, the chemical changes to which the magma is subjected in a constantly replenished system are similar to those occurring in a system which is closed to new inputs of magma. Key Points The combination of multivariate statistics with geochemical modeling provides new constraints on magma differentiation processes Multivariate statistics based on trace elements allow better retrieval of petrological information than those based on major elements Magma differentiation in open systems approximates that occurring in closed systems when magma residence timescales are short

Radon anomalies are commonly observed prior to dynamic failure in the crust and are interpreted as cracking of the medium, thus attracting considerable attention in understanding the precursory phenomena of earthquakes and volcanic activity. In this study we have compared the starting radon emissions from low porosity crystalline lava (phonolite) samples with those from damaged and failed samples. The damaged sample was loaded up to just beyond the end of the linear elastic phase, as evidenced by the output of AE energy, the increase in total porosity and a decrease in P‐wave and S‐wave velocity relative to the intact sample. Whereas, the failed sample showed deformation behaviour characteristically brittle with increasing values of AE output and porosity as the sample approached macroscopic failure. Radon measurements have evidenced that dilatational microcracking of deformed sample produced no significant variation in radon emanation with respect to the intact sample. In contrast, after macroscopic failure, radon emanation drastically increased. Therefore, major finding from this study is that, in the case of low porosity and relatively high strength crystalline lavas, the development of a macroscopic fracture provides new large exhaling surface resulting in a substantial increase in radon emission rate. Key Points Radon emission from rocks increases by means of macroscopic fractures Radon emission does no change in deformed low‐porosity crystalline lavas Radon emission is governed by the different rock types

Radon and thoron emissions from lithophysae‐rich tuff under increasing deformation are measured to determine how mechanical damage affects gas emission levels in tuffs. Mechanical properties of rocks under stresses should be carefully considered to properly interpret data from geochemical field monitoring. Two samples are uniaxially loaded up to failure, while two others are unloaded at the end of the elastic phase, in order to achieve the highest compaction of existing pores. Changes in the porosity of deformed samples are evidenced by helium pycnometer and microscopy analyses. Radon and thoron exhalation rates are measured on groups of two samples by alpha spectrometer technique. Results show that tuff samples are characterised by a dual porosity consisting of a macroporosity, given by isolated large pores with sizes from mm‐ up to cm‐scale and a microporosity ranging between microns to hundreds of microns. At the end of the elastic phase pervasive pore collapse is observed, due to the closure of the cm‐scale macropores. This is mirrored by a significant decrease of radon and thoron release. After failure, a further reduction of porosity in the rock adjacent to the fault planes is observed due to extensive closure of both macropores and micropores. At this stage radon and thoron emissions increase. The formation of new exhaling surfaces is the main carrier of the bulk increase of radon and thoron exhalations, strongly prevailing over the densification carried out from the compaction mechanisms. In terms of volcanic hazard, negative anomalies in radon emissions should be considered as indicators of forthcoming ruptures. Key words: radon and thoron exhalation, tuff deformation, seismic precursor.

We document for the first time the role played by natural solidification paths on the partitioning of rare earth elements (REE) between clinopyroxene and melt. To do this, we investigated the compositional variation of clinopyroxenes formed under increasing cooling rate conditions from core to rim of a dike at Mt. Etna volcano. As the rate of cooling increases, clinopyroxenes are progressively depleted in Si + Ca + Mg counter-balanced by enrichments in Al + Na + Ti. Consequently, the concentration of REE in clinopyroxene increases due to an increased ease of locally balancing the excess charge at the M2 site as the number of surrounding tetrahedral aluminium atoms increases. Since Al iv in clinopyroxene is a charge-balancing cation for REE, the partition coefficients (D REE ) measured at the dike chilled margin are distinctly higher than those from the dike interior. We conclude that, in naturally solidifying magmas, kinetically controlled cation substitution reactions can be treated in terms of the energetics of the various charge-imbalanced configurations. This finding is corroborated by the near-parabolic dependence of D REE on cation radius due to charge-balance mechanisms described by the lattice strain model.

We present results from phase equilibria experiments conducted on the most primitive pahoehoe “cicirara” trachybasaltic lava flow ever erupted at Mt. Etna Volcano. This lava is characterized by a pahoehoe morphology in spite of its high content of phenocrysts and microphenocrysts (>40 vol%) with the occurrence of centimetre-sized plagioclases (locally named cicirara for their chick-pea-like appearance). Our experiments have been performed at 400 MPa, 1100–1150 °C and using H 2 O and CO 2 concentrations corresponding to the water-undersaturated crystallization conditions of Etnean magmas. Results show that olivine does not crystallize from the melt, whereas titanomagnetite is the liquidus phase followed by clinopyroxene or plagioclase as a function of melt–water concentration. This mineralogical feature contrasts with the petrography of pahoehoe cicirara lavas suggesting early crystallization of olivine and late formation of titanomagnetite after plagioclase and/or in close association with clinopyroxene. The lack of olivine produces MgO-rich melt compositions that do not correspond to the evolutionary behaviour of cicirara magmas. Moreover, in a restricted thermal path of 50 °C and over the effect of decreasing water concentrations, we observe abundant plagioclase and clinopyroxene crystallization leading to trace element enrichments unlikely for natural products. At the same time, the equilibrium compositions of our mineral phases are rather different from those of natural cicirara phenocrysts and microphenocrysts. The comparison between our water-undersaturated data and those from previous degassing experiments conducted on a similar Etnean trachybasaltic composition demonstrates that pahoehoe cicirara lavas originate from crystal-poor, volatile-rich magmas undergoing abundant degassing and cooling in the uppermost part of the plumbing system and at subaerial conditions where most of the crystallization occurs after the development of pahoehoe surface crusts.

Laboratory experiments can represent a valid approach to unravel the complex interplay between the geochemical behaviour of radon and rock deformation mechanisms. In light of this, we present a new real-time experimental setup for analysing in continuum the alpha-emitting 222Rn and 220Rn daughters over variable stress–strain regimes. The most innovative segment of this setup consists of the radon accumulation chamber obtained from a tough and durable material that can host large cylindrical rock samples. The accumulation chamber is connected, in a closed-loop configuration, to a gas-drying unit and to a RAD7 radon monitor. A recirculating pump moves the gas from the rock sample to a solid-state detector for alpha counting of radon and thoron progeny. The measured radon signal is enhanced by surrounding the accumulation chamber with a digitally controlled heating belt. As the temperature is increased, the number of effective collisions of radon atoms increases favouring the diffusion of radon through the material and reducing the analytical uncertainty. The accumulation chamber containing the sample is then placed into a uniaxial testing apparatus where the axial deformation is measured throughout a linear variable displacement transducer. A dedicated software allows obtaining a variety of stress–strain regimes from fast deformation rates to long-term creep tests. Experiments conducted with this new real-time setup have important ramifications for the interpretation of geochemical anomalies recorded prior to volcanic eruptions or earthquakes.

Background: Executive functions are higher order cognitive processes occurring in the frontal lobe that influence cognitive, emotional, and behavioral functions. Adolescents with executive functioning deficits are at risk for difficulties in all domains of occupational functioning. Parents of these adolescents often live in a persistent state of stress that leads to highly reactive exchanges with their children. Studies have shown that a mindful approach to parenting can enhance a parent's caregiving ability and self-awareness in the family unit. Methods: A pretest/posttest study evaluated the effectiveness of a 6-week mindful parenting program. Four parents of adolescents with executive function deficits participated in six consecutive group sessions for 1.5 hr each, one time per week, to learn mindful strategies. Results: Although most results were not found to be statistically significant, findings demonstrated promising trends for three of the parents. Statistically significant results indicated that one parent experienced improved communication with his or her adolescent, two had fewer concerns at school for their adolescent, three showed increased ability to problem-solve, one decreased his or her perfectionistic parenting skills, and one was more likely to be in the middle between the other parent and their adolescent. Conclusions: Support for parents after program conclusion may be necessary to promote lasting change. Further research is needed with larger groups and longer periods to determine the effectiveness of mindfulness programs for parents with adolescents with executive functioning deficits. Comments This study was unfunded and completed in partial fulfillment for the requirements for the degree of occupational therapy doctorate at Chatham University, Pittsburgh, PA. IRB approval was obtained from Thomas Jefferson University, Philadelphia, PA Disclosure statement: The authors report no conflicts of interest. Keywords mindfulness, mindful parenting, consistent parenting, adolescents, executive functioning, occupational therapy Cover Page Footnote The authors would like to thank Arlene Lorch, OTD, OTR/L, CHES; Adel Herge, OTD, OTR/L, FAOTA; Kathryn Dent, BS; and Daniel Kipnis, MSI, for their gracious contributions toward this project. Complete Author List Kimberly S. Mollo, Bernardo A. Merizalde, and Jennifer E. Lape

Background Interprofessional education represents an opportunity for healthcare and design students to deepen their understanding of users and enhance skill development through collaborative experiences. Embedding these collaborative experiences within entire curricula moves the notion of experiential learning from stand-alone projects towards the nuanced learning opportunities only available with sustained regular contact. Methods Occupational therapy doctoral students were integrated into two cohorts of Master of Industrial Design (MSID) student courses for one academic year. Interviews were conducted to gather qualitative information about the student experiences, which were then transcribed, coded, and analyzed for themes.Results Industrial design students reported positive learning experiences when collaborating with occupational therapy students that deepened understanding of user-centeredness, improved communication skills, and more well-developed student projects than would have been possible alone. Conclusion The contribution of occupational therapy and industrial design students into collaborative courses and projects may result in a greater topical understanding and more advanced skill development than any singular discipline’s program. Further research to compare development against students without collaborative experiences is needed to understand the magnitude of a collaboration’s potential impact.