Explore the vast range of titles available.

Recent experiments in multiband Fe-based and heavy-fermion superconductors have challenged the long-held dichotomy between simple s- and d-wave spin-singlet pairing states. Here, we advance several time-reversal-invariant irreducible pairings that go beyond the standard singlet functions through a matrix structure in the band/orbital space, and elucidate their naturalness in multiband systems. We consider the sτ3 multiorbital superconducting state for Fe-chalcogenide superconductors. This state, corresponding to a d + d intra- and inter-band pairing, is shown to contrast with the more familiar d + id state in a way analogous to how the B- triplet pairing phase of 3He superfluid differs from its A- phase counterpart. In addition, we construct an analog of the sτ3 pairing for the heavy-fermion superconductor CeCu2Si2, using degrees-of-freedom that incorporate spin-orbit coupling. Our results lead to the proposition that d-wave superconductors in correlated multiband systems will generically have a fully-gapped Fermi surface when they are examined at sufficiently low energies.

The surface states of 3D topological insulators in general have negligible quantum oscillations (QOs) when the chemical potential is tuned to the Dirac points. In contrast, we find that topological Kondo insulators (TKIs) can support surface states with an arbitrarily large Fermi surface (FS) when the chemical potential is pinned to the Dirac point. We illustrate that these FSs give rise to finite-frequency QOs, which can become comparable to the extremal area of the unhybridized bulk bands. We show that this occurs when the crystal symmetry is lowered from cubic to tetragonal in a minimal two-orbital model. We label such surface modes as ‘shadow surface states’. Moreover, we show that the sufficient next-nearest neighbor out-of-plane hybridization leading to shadow surface states can be self-consistently stabilized for tetragonal TKIs. Consequently, shadow surface states provide an important example of high-frequency QOs beyond the context of cubic TKIs.

An important challenge in condensed matter physics is understanding iron-based superconductors. Among these systems, the iron selenides hold the record for highest superconducting transition temperature and pose especially striking puzzles regarding the nature of superconductivity. The pairing state of the alkaline iron selenides appears to be of d -wave type based on the observation of a resonance mode in neutron scattering, while it seems to be of s -wave type from the nodeless gaps observed everywhere on the Fermi surface. Here we propose an orbital-selective pairing state, dubbed sτ 3 , as a natural explanation of these disparate properties. The pairing function, containing a matrix τ 3 in the basis of 3 d -electron orbitals, does not commute with the kinetic part of the Hamiltonian. This dictates the existence of both intraband and interband pairing terms in the band basis. A spin resonance arises from a d -wave-type sign change in the intraband pairing component, whereas the quasiparticle excitation is fully gapped on the FS due to an s -wave-like form factor associated with the addition in quadrature of the intraband and interband pairing terms. We demonstrate that this pairing state is energetically favored when the electron correlation effects are orbitally selective. More generally, our results illustrate how the multiband nature of correlated electrons affords unusual types of superconducting states, thereby shedding new light not only on the iron-based materials but also on a broad range of other unconventional superconductors such as heavy fermion and organic systems. Unconventional superconductivity: Orbital selective pairing in iron selenides Orbital-selective pairing could explain the unusual properties observed in the unconventional superconductor iron selenide. Conventional superconductivity arises when electrons form Cooper pairs due to electron-phonon coupling. In some materials, however, unconventional superconductivity can arise, which is driven by electron-electron rather than electron-phonon couplings. The detailed mechanism that facilitates electron pairing in unconventional systems remains elusive but iron selenide systems could help to provide insights as they exhibit both relatively high temperature superconductivity, and also strong electron correlations. With different experiments suggesting different pairing mechanisms, however, these systems are somewhat puzzling. An international team of researchers led by Qimiao Si from Rice University now theoretically demonstrate that an orbital-selective pairing state could explain this unusual behaviour, which may also be at play in other unconventional superconductors such as heavy fermion and organic systems.

Complex and correlated quantum systems with promise for new functionality often involve entwined electronic degrees of freedom. In such materials, highly unusual properties emerge and could be the result of electron localization. Here, a cubic heavy fermion metal governed by spins and orbitals is chosen as a model system for this physics. Its properties are found to originate from surprisingly simple low-energy behavior, with 2 distinct localization transitions driven by a single degree of freedom at a time. This result is unexpected, but we are able to understand it by advancing the notion of sequential destruction of an SU(4) spin–orbital-coupled Kondo entanglement. Our results implicate electron localization as a unified framework for strongly correlated materials and suggest ways to exploit multiple degrees of freedom for quantum engineering.

Since the discovery of high-temperature superconductivity in copper oxide materials 1 , there have been sustained efforts to both understand the origins of this phase and discover new cuprate-like superconducting materials 2 . One prime materials platform has been the rare-earth nickelates and, indeed, superconductivity was recently discovered in the doped compound Nd 0.8 Sr 0.2 NiO 2 (ref. 3 ). Undoped NdNiO 2 belongs to a series of layered square-planar nickelates with chemical formula Nd n +1 Ni n O 2 n +2 and is known as the ‘infinite-layer’ ( n  =  ∞ ) nickelate. Here we report the synthesis of the quintuple-layer ( n  = 5) member of this series, Nd 6 Ni 5 O 12 , in which optimal cuprate-like electron filling ( d 8.8 ) is achieved without chemical doping. We observe a superconducting transition beginning at ~13 K. Electronic structure calculations, in tandem with magnetoresistive and spectroscopic measurements, suggest that Nd 6 Ni 5 O 12 interpolates between cuprate-like and infinite-layer nickelate-like behaviour. In engineering a distinct superconducting nickelate, we identify the square-planar nickelates as a new family of superconductors that can be tuned via both doping and dimensionality. The authors report a superconducting transition beginning at 13 K in films of the quintuple-layer nickelate Nd 6 Ni 5 O 12 .

SignificanceIdentifying the gap structure of superconductors is vital for understanding the underlying pairing mechanism of the Cooper pairs. The first heavy fermion superconductor to be discovered, CeCu2Si2, was thought to be a d-wave superconductor with gap nodes, until recent specific heat measurements provided evidence that the gap is fully open across the Fermi surface. We propose a resolution to this puzzle from measurements of the London penetration depth, which give further evidence for fully gapped superconductivity. We analyze the data using a d-wave band-mixing pairing model, which leads to a fully open superconducting gap. Our model accounts well for the penetration depth and specific heat data, while reconciling the nodeless and sign-changing nature of the gap function. The nature of the pairing symmetry of the first heavy fermion superconductor CeCu2Si2 has recently become the subject of controversy. While CeCu2Si2 was generally believed to be a d-wave superconductor, recent low-temperature specific heat measurements showed evidence for fully gapped superconductivity, contrary to the nodal behavior inferred from earlier results. Here, we report London penetration depth measurements, which also reveal fully gapped behavior at very low temperatures. To explain these seemingly conflicting results, we propose a fully gapped d+d band-mixing pairing state for CeCu2Si2, which yields very good fits to both the superfluid density and specific heat, as well as accounting for a sign change of the superconducting order parameter, as previously concluded from inelastic neutron scattering results.

Identifying the gap structure of superconductors is vital for understanding the underlying pairing mechanism of the Cooper pairs. The first heavy fermion superconductor to be discovered, CeCu 2 Si 2 , was thought to be a d -wave superconductor with gap nodes, until recent specific heat measurements provided evidence that the gap is fully open across the Fermi surface. We propose a resolution to this puzzle from measurements of the London penetration depth, which give further evidence for fully gapped superconductivity. We analyze the data using a d -wave band-mixing pairing model, which leads to a fully open superconducting gap. Our model accounts well for the penetration depth and specific heat data, while reconciling the nodeless and sign-changing nature of the gap function. The nature of the pairing symmetry of the first heavy fermion superconductor CeCu 2 Si 2 has recently become the subject of controversy. While CeCu 2 Si 2 was generally believed to be a d -wave superconductor, recent low-temperature specific heat measurements showed evidence for fully gapped superconductivity, contrary to the nodal behavior inferred from earlier results. Here, we report London penetration depth measurements, which also reveal fully gapped behavior at very low temperatures. To explain these seemingly conflicting results, we propose a fully gapped d + d band-mixing pairing state for CeCu 2 Si 2 , which yields very good fits to both the superfluid density and specific heat, as well as accounting for a sign change of the superconducting order parameter, as previously concluded from inelastic neutron scattering results.

The nature of the pairing symmetry of the first heavy fermion superconductor CeCu₂Si₂ has recently become the subject of controversy. While CeCu₂Si₂ was generally believed to be a d-wave superconductor, recent low-temperature specific heat measurements showed evidence for fully gapped superconductivity, contrary to the nodal behavior inferred from earlier results. Here, we report London penetration depth measurements, which also reveal fully gapped behavior at very low temperatures. To explain these seemingly conflicting results, we propose a fully gapped d + d band-mixing pairing state for CeCu₂Si₂, which yields very good fits to both the superfluid density and specific heat, as well as accounting for a sign change of the superconducting order parameter, as previously concluded from inelastic neutron scattering results.

The nature of the pairing symmetry of the first heavy fermion superconductor CeCu2Si2 has recently become the subject of controversy. While CeCu2Si2 was generally believed to be a d-wave superconductor, recent low-temperature specific heat measurements showed evidence for fully gapped superconductivity, contrary to the nodal behavior inferred from earlier results. Here, we report London penetration depth measurements, which also reveal fully gapped behavior at very low temperatures. To explain these seemingly conflicting results, we propose a fully gapped d+d band-mixing pairing state for CeCu2Si2, which yields very good fits to both the superfluid density and specific heat, as well as accounting for a sign change of the superconducting order parameter, as previously concluded from inelastic neutron scattering results.

Motivated by the recent discovery of superconductivity in square-planar nickelates as well as by longstanding puzzling experiments in heavy-fermion superconductors, we study Cooper pairing between correlated \\(d\\)-electrons coupled to a band of weakly-correlated electrons. We perform self-consistent large N calculations on an effective \\(t-J\\) model for the \\(d\\)-electrons with additional hybridization. Unlike previous studies of mixed-valent systems, we focus on parameter regimes where both hybridized bands are relevant to determining the pairing symmetry. For sufficiently strong hybridization, we find a robust \\(s+id\\) pairing which breaks time-reversal and point-group symmetries in the mixed-valent regime. Our results illustrate how intrinsically multi-band systems such as heavy-fermions can support a number of highly non-trivial pairing states. They also provide a putative microscopic realization of previous phenomenological proposals of \\(s+id\\) pairing and suggest a potential resolution to puzzling experiments in heavy-fermion superconductors such as U\\(_{1-x}\\)Th\\(_x\\)Be\\(_{13}\\) which exhibit two superconducting phase transitions and a full gap at lower temperatures.