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Using a customized time-domain ellipsometer operating in the THz range, the molecular dynamics of a liquid binary solution based on water and isopropyl alcohol (2-propanol) is investigated. The setup is capable of detecting small changes in the optical properties of the mixture within a single measurement. The complex dielectric response of samples with different concentrations is studied through the direct measurement of the ellipsometric parameters. The results are described using an effective Debye model, from which the relaxation parameters associated with different activation energies can be consistently extracted. Significant deviations between experimental data and the theoretical expectations at an intermediate volume percentage of 2-propanol in water are observed and interpreted as produced by competing effects: the creation/destruction of hydrogen bonding on the one hand, and the presence of cluster/aggregation between water and alcohol molecules on the other.

The transmission response of metallo-dielectric grid metasurfaces is experimentally investigated through Terahertz Time Domain Spectroscopy and the corresponding effective dielectric function is retrieved. Using a lumped element model we can determine the dependence of the effective plasma frequency (the transition frequency) on the metasurface filling factor F. The change of the transition frequency vs. F spans over one order of magnitude and sets the threshold between the metamaterial (homogeneous) and the photonic crystal (diffraction-like) regime, ruling the onset of two different Surface Plasmon Polaritons, spoof and high order. Field symmetry and spatial extension of such excitations are investigated for the possible applications of THz grid metasurfaces in bio- and chemical sensing and sub-wavelength imaging.

Towards new and improved techniques in liquid biopsy for the diagnosis of diseases, this study reports experimental evidence of a rapid and reliable method based on terahertz (THz) time-domain spectroscopic ellipsometry (TDSE) for the early diagnosis of kidney-related diseases, using the detection of uric acid (UA) content in urine. Employing a custom-built THz-TDSE system, we analyzed the absorption and dispersion response of synthetic urine samples with varying concentrations of UA. The technique provides a prompt indication of UA presence and concentration, thanks to the sensitivity of THz waves to intermolecular interactions such as hydrogen bonding. The results clearly show a linear correlation between the UA concentration and changes in the absorption spectra of urine in the frequency window 0.2–1.2 THz, with the minimum detectable UA concentration being approximately close to the upper limit of normal UA levels in urine. The increase in the absorption coefficient as a function of the UA concentration provides a means for a quantifiable measure of the UA biomarker in urine for assessing disease stage. This study proves that THz-TDSE is capable of detecting UA at concentrations relevant for early-stage diagnosis of renal diseases, with an estimated sensitivity of 0.2 g/L in the region where the material response is linear.

We describe an experimental strategy for the use of Terahertz (THz) metasurfaces as a platform for label-free wide range detection of the dielectric function in biological fluids. Specifically, we propose a metagrid (MG), opportunely infiltrated with a fluid and then capped, as the reference structure for sensing experiments with a high reproducibility character. By combining experiments and full-wave simulations of the transmission T of such a structure, we introduce a reliable set up where the volume of the involved analyte in each unit cell is precisely determined. The unavoidable decrease in the quality factor of the intrinsic resonances due to the lossy fluid and cap layer is circumvented using an appropriate transformation of T that amplifies the change in the MG intrinsic resonances, improving in such a way the sensor sensitivity to values close to the experimental limits. The transformed signal features delta-like peaks enabling an easy readout of frequency positions at resonances.

The monoclinic structures of vanadium dioxide are widely studied as appealing systems due to a plethora of functional properties in several technological fields. In particular, the possibility to obtain the VO2 material in the form of thin film with a high control of structure and morphology represents a key issue for their use in THz devices and sensors. Herein, a fine control of the crystal habit has been addressed through an in-depth study of the metal organic chemical vapor deposition (MOCVD) synthetic approach. The focus is devoted to the key operative parameters such as deposition temperature inside the reactor in order to stabilize the P21/c or the C2/m monoclinic VO2 structures. Furthermore, the compositional purity, the morphology and the thickness of the VO2 films have been assessed through energy dispersive X-ray (EDX) analyses and field-emission scanning electron microscopy (FE-SEM), respectively. THz time domain spectroscopy is used to validate at very high frequency the functional properties of the as-prepared VO2 films.

We report a study on the hydrogen bonding mechanisms of three aliphatic alcohols (2-propanol, methanol, and ethanol) and one diol (ethylene glycol) in water solution using a time-domain ellipsometer in the THz region. The dielectric response of the pure liquids is nicely modeled by the generalized Debye–Lorentz equation. For binary mixtures, we analyze the data using a modified effective Debye model, which considers H-bond rupture and reformation dynamics and the motion of the alkyl chains and of the OH groups. We focus on the properties of the water-rich region, finding anomalous behavior in the absorption properties at very low solute molar concentrations. These results, first observed in the THz region, are in line with previous findings from different experiments and can be explained by taking into account the amphiphilic nature of the alcohol molecules.

This paper describes a reliable, handy, and inexpensive measurement system to characterize, in the sub-THz frequency range, the coating materials used in the beam pipes of accelerators. The method is based on time domain measurements of an electromagnetic wave passing through a waveguide having a thin central slab, where the coating material is deposited on both sides. Two horn antennas are integrated on both sides of the device to optimize the signal collection and detection. This novel technique is tested on slabs coated with a nonevaporable getter (NEG) and allows to evaluate the surface impedance in the frequency range from 0.1 to 0.3 THz.

Coding metasurfaces, composed of only two types of elements arranged according to a binary code, are attracting a steadily increasing interest in many application scenarios. In this study, we apply this concept to attain diffuse scattering at THz frequencies. Building up on previously derived theoretical results, we carry out a suboptimal metasurface design based on a simple, deterministic and computationally inexpensive algorithm that can be applied to arbitrarily large structures. For experimental validation, we fabricate and characterize three prototypes working at 1 THz, which, in accordance with numerical predictions, exhibit significant reductions of the radar cross-section, with reasonably good frequency and angular stability. Besides the radar-signature control, our results may also find potentially interesting applications to diffusive imaging, computational imaging, and (scaled to optical wavelengths) photovoltaics.

High-resolution focused ion beam lithography has been used to fabricate YBa2Cu3O7-x (YBCO) wires with nanometric lateral dimensions. In the present work, we investigate Flux-flow instabilities in nanowires of different widths, showing sudden voltage switching jumps from the superconducting to the normal state. We present an extensive study on the temperature and field dependence of the switching characteristics which reveal that voltage jumps become less abrupt as the temperature increases, and disappear at the vortex-liquid state. On the contrary, the current distribution at the critical point becomes narrower at high temperatures. Sharp voltage switchings very close to the critical current density can be obtained by reducing the width of the nanowires, making them very appealing for practical applications.

The exponential factor in Equation (1) of the paper published in [1] reports a misprintand the correct expression of the transmission function is [...].