Explore the vast range of titles available.

As an essential micronutrient, iron plays a key role in oceanic biogeochemistry. It is therefore linked to the global carbon cycle and climate. Here, we report a dissolved iron (DFe) isotope section in the South Atlantic and Southern Ocean. Throughout the section, a striking DFe isotope minimum (light iron) is observed at intermediate depths (200–1,300 m), contrasting with heavier isotopic composition in deep waters. This unambiguously demonstrates distinct DFe sources and processes dominating the iron cycle in the intermediate and deep layers, a feature impossible to see with only iron concentration data largely used thus far in chemical oceanography. At intermediate depths, the data suggest that the dominant DFe sources are linked to organic matter remineralization, either in the water column or at continental margins. In deeper layers, however, abiotic non-reductive release of Fe (desorption, dissolution) from particulate iron—notably lithogenic—likely dominates. These results go against the common but oversimplified view that remineralization of organic matter is the major pathway releasing DFe throughout the water column in the open ocean. They suggest that the oceanic iron cycle, and therefore oceanic primary production and climate, could be more sensitive than previously thought to continental erosion (providing lithogenic particles to the ocean), particle transport within the ocean, dissolved/particle interactions, and deep water upwelling. These processes could also impact the cycles of other elements, including nutrients.

With the aim to better understand the cause of the iron isotope heterogeneity of mantle-derived bulk peridotites, we compared the petrological, geochemical and iron isotope composition of four xenolith suites from different geodynamic settings; sub-arc mantle (Patagonia); subcontinental lithospheric mantle (Cameroon), oceanic mantle (Kerguelen) and cratonic mantle (South Africa). Although correlations were not easy to obtain and remain scattered because these rocks record successive geological events, those found between δ 57 Fe, Mg#, some major and trace element contents of rocks and minerals highlight the processes responsible for the Fe isotope heterogeneity. While partial melting processes only account for moderate Fe isotope variations in the mantle (<0.2 ‰, with bulk rock values yielding a range of δ 57 Fe ± 0.1 ‰ relative to IRMM-14), the main cause of Fe isotope heterogeneity is metasomatism (>0.9 ‰). The kinetic nature of rapid metasomatic exchanges between low viscosity melts/fluids and their wall-rocks peridotite in the mantle is the likely explanation for this large range. There are a variety of responses of Fe isotope signatures depending on the nature of the metasomatic processes, allowing for a more detailed study of metasomatism in the mantle with Fe isotopes. The current database on the iron isotope composition of peridotite xenoliths and mafic eruptive rocks highlights that most basalts have their main source deeper than the lithospheric mantle. Finally, it is concluded that due to a complex geological history, Fe isotope compositions of mantle xenoliths are too scattered to define a mean isotopic composition with enough accuracy to assess whether the bulk silicate Earth has a mean δ 57 Fe that is chondritic, or if it is ~0.1 ‰ above chondrites as initially proposed.

Subduction processes may have operated very early in Earth’s history according to the heavy silicon isotope compositions of Archaean igneous rocks. The silicon that precipitated out of the Archaean oceans as chert was subducted and melted to yield seawater-like heavy isotope signatures in early granitic rocks.

Laboratory studies detected non-mass-dependent Fe-isotope fractionation during magnetotactic-bacteria-controlled iron (III) reduction, suggesting its potential as a biomineralization proxy. In nature, the preservation of the non-mass-dependent Fe-isotope signature may be difficult due to the abundance of other Fe-rich materials. Here we report a set of distinctly large non-mass-dependent Fe-isotope composition in the top 6.5 cm of the oxic-anoxic transition zone from a sediment core of Lake Aha, southwestern China. Negative ∆' 57 Fe d -δ' 56 Fe d and positive ∆' 57 Fe d -[Mn] correlations support that an abundance of manganese (IV) and ongoing sulfate reduction created a zone of Fe-limited porewaters in the top 6.5 cm of the sediment where magnetotactic bacteria thrived. Non-mass-dependent Fe-isotope signatures were not detected in a sediment core taken at a nearby site in the same lake where in the oxic-anoxic transition zone porewater Fe concentrations were orders-of-magnitude higher. The discovery of non-mass-dependent Fe-isotope signatures in natural sediment offers clues to detecting similar biosignatures. Natural occurrence of large non-mass-dependent iron isotope fractionation was discovered in sediments of Lake Aha, southwestern China, where the magnetotactic bacteria thrived top centimeters are iron concentration limited in pore water due to abundant manganese (IV) and ongoing sulphate reduction.

Allanite is, with monazite, the main repository for light rare earth elements (REE) in the continental crust and can be used in U-Th-Pb geochronology. This mineral has been shown to be prone to alteration. The geochemical exchanges occurring between allanite and hydrothermal fluids were explored using backscattered scanning electron microscopy, electron microprobe, and laser ablation-inductively coupled plasma-mass spectrometry (LAICP-MS).

Iron isotopes may be witnesses of the interplanetary impact that formed the Moon or probes of processes occurring at Earth's core-mantle interface.

The bulk chemical compositions of planets are uncertain, even for major elements such as Mg and Si. This is due to the fact that the samples available for study all originate from relatively shallow depths. Comparison of the stable isotope compositions of planets and meteorites can help overcome this limitation. Specifically, the non-chondritic Si isotope composition of the Earth's mantle was interpreted to reflect the presence of Si in the core, which can also explain its low density relative to pure Fe-Ni alloy. However, we have found that angrite meteorites display a heavy Si isotope composition similar to the lunar and terrestrial mantles. Because core formation in the angrite parent-body (APB) occurred under oxidizing conditions at relatively low pressure and temperature, significant incorporation of Si in the core is ruled out as an explanation for this heavy Si isotope signature. Instead, we show that equilibrium isotopic fractionation between gaseous SiO and solid forsterite at 1370 K in the solar nebula could have produced the observed Si isotope variations. Nebular fractionation of forsterite should be accompanied by correlated variations between the Si isotopic composition and Mg/Si ratio following a slope of 1, which is observed in meteorites. Consideration of this nebular process leads to a revised Si concentration in the Earth's core of 3.6 (+6.0/-3.6) wt% and provides estimates of Mg/Si ratios of bulk planetary bodies.