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The disorder due to anti-site cation distribution is intrinsic to the double perovskites wherein the crystal orientations of the substrate template are predicted to offer different degrees of cation order in thin film form. To demonstrate this effect, epitaxial thin films of half-metallic double perovskite Ca2FeMoO6 (CFMO) were prepared on (100) and (111) oriented LaAlO3 substrates in vacuum and nitrogen atmospheres. The findings using X-ray absorption near-edge structure, Terahertz (THz) and Raman spectroscopies, in combination with magnetization show that (111) epitaxial template effectively restricts the Fe–Mo anti-site cation disorder. A resultantly enhanced cation order in (111) films induces dramatic transformations in its properties as follows: (i) significantly enhanced ferromagnetic exchange interactions and saturation magnetization, (ii) a significant increase in the Curie temperatures, (iii) a metallic behavior down to much lower temperature (∼75 K) compared to that down to 200 K for (100) film, (iv) an enhanced spin–phonon coupling. The complex THz optical conductivity spectra evaluated in the framework of Drude and Drude–Smith phenomenological models and the temperature-dependent Raman data fitted to the Balkanski model corroborate well to indicate an enhanced cation order in (111) films. While this study establishes a dominant role of crystallographic orientation in the much-desired control of cation order in double perovskites, a demonstration of the same in room temperature half-metallic CFMO system could reinforce its technological utility both as active and passive components in emergent spintronic functionalities.

Understanding the dynamics of phase-transitions, interpretations of their experimental observations and their agreement with theoretical predictions continue to be a long-standing research interest. Here, we present detailed phase-transition dynamics of rare earth nickelates associated with its first-order metal–insulator transition. The thermal hysteresis shows absence of training effect and defies the Preisach model. A large phase-coexistence in insulating state during cooling suggests kinetically arrested glassy dynamics of the phase-transition. Experimentally derived hysteresis scaling exponent is much larger than the mean-field predicted universal value of 2/3. In the phase-coexistence region, the quench and hold measurement depicts higher stability of the metallic state compare to that of the insulating one; highlighting the manifestation of phase-coexistence via asymmetric spinodal decomposition. All these observations for nickelates are in stark contrast to the phase-transition dynamics of canonically similar vanadates but are closer to those of glasses, alloys. A substantial disagreement between the experiment and theory emphasizes the necessity to incorporate system-dependent details for the accurate interpretation of the experimental results.

The disorder due to anti-site cation distribution is intrinsic to the double perovskites wherein the crystal orientations of the substrate template are predicted to offer different degrees of cation order in thin film form. To demonstrate this effect, epitaxial thin films of half-metallic double perovskite Ca 2 FeMoO 6 (CFMO) were prepared on (100) and (111) oriented LaAlO 3 substrates in vacuum and nitrogen atmospheres. The findings using X-ray absorption near-edge structure, Terahertz (THz) and Raman spectroscopies, in combination with magnetization show that (111) epitaxial template effectively restricts the Fe–Mo anti-site cation disorder. A resultantly enhanced cation order in (111) films induces dramatic transformations in its properties as follows: (i) significantly enhanced ferromagnetic exchange interactions and saturation magnetization, (ii) a significant increase in the Curie temperatures, (iii) a metallic behavior down to much lower temperature (∼75 K) compared to that down to 200 K for (100) film, (iv) an enhanced spin–phonon coupling. The complex THz optical conductivity spectra evaluated in the framework of Drude and Drude–Smith phenomenological models and the temperature-dependent Raman data fitted to the Balkanski model corroborate well to indicate an enhanced cation order in (111) films. While this study establishes a dominant role of crystallographic orientation in the much-desired control of cation order in double perovskites, a demonstration of the same in room temperature half-metallic CFMO system could reinforce its technological utility both as active and passive components in emergent spintronic functionalities.

In complex oxides, the electrons under the influence of competing energetics are the cornerstone of coexistence (or phase-separation) of two or more electronic/magnetic phases in same structural configuration. Probing of growth and evolution of such phase-coexistence state is crucial to determine the correct mechanism of related phase-transition. Here, we demonstrate the combination of terahertz (THz) time-domain spectroscopy and DC transport as a novel strategy to probe the electronic phase-coexistence. This is demonstrated in disorder controlled phase-separated rare-earth nickelate thin films which exhibit metal-insulator transition in dc conductivity at around 180 K but lack this transition in terahertz (THz) dynamics conductivity down to low temperature. Such pronounced disparity exploits two extreme attributes: i) enormous sensitivity of THz radiation to a spatial range of its wavelength-compatible electronic inhomogeneities and ii) insensitivity to a range beyond the size of its wavelength. This feature is generic in nature (sans a photo-induced effect), depends solely on the size of insulating/metallic clusters and formulates a methodology with unique sensitivity to investigate electronic phase-coexistence and phase transition of any material system.

Terahertz high harmonic generation (THz HHG) is a common property of nonlinear systems. Recently it has been used to investigate fundamental principles that govern transport and nonlinear dynamics in novel quantum materials like graphene, Dirac semimetals or high-temperature superconductors. Here, we report on the observation of exceptionally large THz second harmonic and third harmonic generation in thin films of the highly conducting delafossite PdCoO\\(_2\\) down to low temperatures. The growth of this material on offcut substrate allows for a significant enhancement of the third harmonic intensity compared to ordinary \\(c\\)-axis grown thin films. Furthermore, it appears to be a necessity for the observation of THz second harmonic generation. We model the temperature dependence of the third harmonic generation by means of Boltzmann transport theory and provide an explanation for the second harmonic generation by comparing the system to the electric field induced second harmonic generation. The present investigation thus provides an important contribution to the ongoing discussion of low temperature origins of THz HHG and might serve as a new platform for THz high harmonic applications.

The Mg–Al cycle is characteristic of the high-temperature (T ∼ 0.055 GK) H-burning of evolved stars and their nucleosynthesis. A proper comprehension of this reaction network can help in solving debated questions such as the occurrence of anticorrelation in Mg–Al abundances in globular clusters. Recent high-resolution surveys have shown that such an anticorrelation may hide the existence of multiple stellar populations and that the relative abundances of Mg isotopes may not be correlated with Al. Proton-induced reactions on 27Al play a key role in this respect, in particular the interplay between the (p, α) and (p, γ) channels, determining the closure (or not) of the Mg–Al cycle. Presently, the situation is still debated owing to the large uncertainty affecting existing experimental nuclear data. A recent indirect measurement indicates a further reduction in the 27Al(p, α)24Mg reaction rate with respect to the ones commonly adopted in astrophysical models. In the present work, we update the 27Al(p,γ)28Si reaction rate based on the same indirect measurement results. In the case of AGB stars experiencing hot bottom burning, the revised rate would lead to a ∼35% increase in 27Al abundance with respect to what is presently foreseen, with interesting astrophysical consequences.

In this paper we present the first measurement of a Gallium Arsenide (GaAs) crystal as a scintillating calorimeter with dual heat and light readout within the DAREDEVIL project. The experimental setup features a 4.3 g GaAs ( GaAs-1) crystal, operated at approximately 10 mK coupled with a Neutron Transmutation Doped (NTD) thermal sensor for phonon detection and an auxiliary calorimeter for the detection of scintillation light. For the GaAs-1 crystal, a baseline resolution of 121 ± 2 eV has been achieved. While, with a 3.5 g GaAs (GaAs-2) crystal an even better baseline resolution of 44.5 ± 0.8 eV was achieved. Alpha and X-ray calibration sources were used to study the scintillation light response to different types of interacting radiation. The GaAs crystal exhibits a strong particle discrimination capability based on the emitted scintillation light, featuring a light yield (LY) of 0.9 ± 0.2 keV/MeV for α induced events and 0.07 ± 0.01 keV/MeV for β / γ events, both measured at 1 MeV. The unusual luminescence behavior, i.e. more light being produced under irradiation by α particles warrants further investigation, particularly due to its potential to enhance sensitivity to low-energy nuclear recoils from light dark matter scattering.

The abundance of 26Al carries a special role in astrophysics, since it probes active nucleosynthesis in the Milky Way and constrains the Galactic core-collapse supernovae rate. It is estimated through the detection of the 1809 keV γ-line and from the superabundance of 26Mg in comparison with the most abundant Mg isotope (A = 24) in meteorites. For this reason, high precision is necessary also in the investigation of the stable 27Al and 24Mg isotopes. Moreover, these nuclei enter the so-called MgAl cycle, playing an important role in the production of Al and Mg. Recently, high-resolution stellar surveys have shown that the Mg–Al anticorrelation in red-giant stars in globular clusters may hide the existence of multiple stellar populations, and that the relative abundances of Mg isotopes may not be correlated with Al. The common thread running through these astrophysical scenarios is the 27Al(p,α)24Mg reaction, which is the main 27Al destruction channel and directly correlates its abundance with the 24Mg one. Since available reaction rates show large uncertainties owing to the vanishingly small cross section at astrophysical energies, we have applied the Trojan Horse Method to deduce the reaction rate with no need of extrapolation. The indirect measurement made it possible to assess the contribution of the 84 keV resonance and to lower upper limits on the strength of nearby resonances. In intermediate-mass AGB stars experiencing hot bottom burning, a sizeable increase in surface aluminum abundance is observed at the lowest masses, while 24Mg is essentially unaffected by the change in the reaction rate.

Background: Yoga is a physical, mental, and spiritual discipline. The effect of yoga on mental health has been studied extensively in India but less in the context of physical health. Objective: The objective was to explore the effect of long-term regular yoga on physical health of yoga practitioners. Materials and Methods: It was an interventional study. Inclusion criteria were students who enrolled for 1-year diploma course at the yoga center. Exclusion criteria were nonregular yoga practitioners during the course. Physical health parameters considered for assessment before and after the yoga course were pulmonary function tests, maximum oxygen consumption (VO2 max) using Bruce treadmill test, flexibility, body composition analysis, and hemoglobin level. Paired sample t-test and Chi-square test were used for statistical analysis. Results: The aerobic capacity improved significantly in terms of mean (standard deviation [SD]) forced vital capacity (P < 0.001), forced expiration volume at the end of the first second (P < 0.001) as well as peak expiratory flow rate (P = 0.04). The mean (SD) flexibility score improved significantly (P < 0.001). Similarly, the endurance improved significantly in terms of mean (SD) Vo2 max (< 0.001) and treadmill time (P < 0.001). There was no significant change in body composition and hemoglobin level. Conclusions: Regular yoga practitioners demonstrated the improvement in pulmonary functions, cardiorespiratory fitness, endurance, and flexibility.

Nuclear reactions play a key role in the framework of the Big Bang Nucleosynthesis. A network of 12 principal reactions has been identified as the main path that drove the elemental nucleosynthesis in the first 20 min of the history of the Universe. Among them an important role is played by neutron-induced reactions, which, from an experimental point of view, are usually a difficult task to be measured directly. Nevertheless big efforts in the last decades have led to a better understanding of their role in the primordial nucleosynthesis network. In this work we apply the Trojan Horse Method to extract the cross section at astrophysical energies for the 3 He (n,p) 3 H reaction after a detailed study of the 2 H ( 3 He ,pt)H three-body process. Data extracted from the present measurement are compared with other published sets.