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WOOD DETERIORATION, PROTECTION AND MAINTENANCE Wood has low embodied energy, is a renewable resource and can perform extremely well in a range of construction applications, so it is not surprising that there is growing interest in the use of wood in new buildings.

Timber suffers from various biological damages. Recent efforts aim on nature-friendly sustainable technologies of wood protection to replace classical synthetic agents having usually negative impact on many non-target organisms including man. This research investigated the biocidal effectiveness of lavender oil (LO) in protecting the Norway spruce ( Picea abies ) wood against the termites Reticulitermes flavipes and the brown-rot fungus Rhodonia placenta . Following, selected physical characteristics of spruce wood treated with LO were evaluated: colour changes, roughness, surface wetting with water and surface free energy (SFE). Experiments showed that LO increased the resistance of spruce wood to termites nearly to the level of its treatment with commercial biocide based on trivalent boron and quaternary ammonium salt. The additional hydrophobic treatment of wood ensured its full termite-resistance even after artificial weathering in Xenotest and leaching in water according to EN 84, respectively. It shows a high potential of LO to protect wood against termites. Adversely, the effectiveness of 5% LO against rot was not sufficient. The colour of the oil-treated wood was preserved, its roughness increased slightly, and wetting and SFE led to a positive change, improving the adhesion of potentially applied coatings or adhesives for exterior exposures.

Recycled recovered wood, for example, from historic buildings, containing biocides, fire retardants or anti-weather paints is an attractive material for manufacturing composite wood panels which can be used for decoration as well as load-bearing walls with a typical patina. This paper investigates the effect of four inorganic wood preservatives—CuSO4·5H2O, ZnCl2, H3BO3 and (NH4)2SO4—commonly used in the past, with the focus on their effect on the quality of wood bonding. The milled surfaces of Norway spruce (Picea abies Karst L.) wood were treated with 0.5, 1 and 2% aqueous solutions of these preservatives. The effect of preservatives in spruce wood was evaluated: (1) by its wettability with the drops of redistilled water, measuring the contact angles; (2) by the shear strength of the “spruce wood—polyurethane (PUR) Kestopur 1030 glue” interphases according to the standard EN 205; (3) by microscopic analysis of the “wood—PUR” interphases. The wettability of spruce wood worsened when using ZnCl2, by a maximum of 28.2%, but on the contrary, it improved due to other preservatives mainly by using (NH4)2SO4, at a maximum of 22.9%. In general, the shear strength of glued joints “wood—PUR” continually decreased with higher concentrations of all the preservatives. The most significant decrease of adhesion “wood—PUR”, by 19.8% from 10.66 MPa to 8.55 MPa, was caused by 2% ZnCl2 used for the treatment of both spruce wood specimens in interphase with the PUR glue. On the contrary, the less significant decrease of adhesion “wood—PUR”, by 2.5%, was caused by 0.5% (NH4)2SO4 applied only on one surface of the two inter-bonded spruce wood specimens. The effects of preservatives on the wood wettability and its adhesion with PUR glue were partly confirmed by microscopic analysis.

The bonding of wood with assembly adhesives is crucial for manufacturing wood composites, such as solid wood panels, glulam, furniture parts, and sport and musical instruments. This work investigates 13 hardwoods—bangkirai, beech, black locust, bubinga, ipé, iroko, maçaranduba, meranti, oak, palisander, sapelli, wengé and zebrano—and analyzes the impact of their selected structural and physical characteristics (e.g., the density, cold water extract, pH value, roughness, and wettability) on the adhesion strength with the polyvinyl acetate (PVAc) adhesive Multibond SK8. The adhesion strength of the bonded hardwoods, determined by the standard EN 205, ranged in the dry state from 9.5 MPa to 17.2 MPa, from 0.6 MPa to 2.6 MPa in the wet state, and from 8.5 MPa to 19.2 MPa in the reconditioned state. The adhesion strength in the dry state of the bonded hardwoods was not influenced by their cold water extracts, pH values, or roughness parallel with the grain. On the contrary, the adhesion strength was significantly with positive tendency influenced by their higher densities, lower roughness parameters perpendicular to the grain, and lower water contact angles.

Fungi play a critical role in the decomposition of wood and wood-based products in use. The ability of decaying fungi to cause degradation of polysaccharides and lignin in the thermally modified Norway spruce (Picea abies L. Karst.) wood was examined with pure culture decomposition tests in laboratory conditions using the brown-rot fungus Serpula lacrymans (Schumacher ex Fries) S.F. Gray and white-rot fungus Trametes versicolor (Linnaeus ex Fries) Pilat. Spruce wood samples were primary thermally treated under atmospheric pressure at the temperatures of 100, 150, 200, 220, 240 and 260 °C during 1, 3 and 5 h, whereby larger losses in their mass, holocellulose, mannose and xylose were achieved at harder thermal regimes. Meanwhile, the holocellulose percent content reduced considerably, and the percent content of lignin increased sharply. Spruce wood thermally modified at and above 200 °C better resisted to brown-rot fungus S. lacrymans than the white-rot fungus T. versicolor. Due to the decay processes, the mass fractions of holocellulose, cellulose and hemicelluloses were lower in those spruce wood samples in which thermal degradation was more intensive, with achieving the highest mass loss values after thermal treatments, after which the decay attacks were poorer or even none with the minimal mass loss values due to action by the brown-rot fungus S. lacrymans and the white-rot fungus T. versicolor. The mannose and glucose percent content in thermally–fungally attacked spruce wood was intensive reduced, e.g., by 17% to 98% in wood after thermal treatments at temperature equal and above 200 °C.

Special particleboards (PBs) proposed for kitchens, bathrooms, hospitals, and some other specific products for interiors should have a sufficient resistance against bacteria, molds, and decaying fungi. This work deals about effects of zinc oxide nanoparticles (nano-ZnO) added into melamine-urea-formaldehyde (MUF) glue in the amounts of 0, 2, 6, 12, or 24% wt. on selected biological, moisture, and strength properties of laboratory-produced one-layer PBs. The nano-ZnO-treated PBs had a higher biological resistance: (1) against the Gram-positive bacterium Staphylococcus aureus by up to ca. 70% and the Gram-negative bacterium Escherichia coli by up to 50%, since their bacterial activities at using 1.0 McFarland bacterial inoculum decreased from 0.38–0.40 by up to 0.12–0.19 × 108 CFU/ml; (2) against the molds Penicillium brevicompactum and Aspergillus niger by up to ca. 50–63%, since their growth intensities (0–4) on the top surfaces of treated PBs decreased according to a modified EN 15457 from 2.33–2.67 by up to 1.17–1.0; (3) against the brown-rot fungus Coniophora puteana by up to 85.7%, since their weight losses reduced according to a modified ENV 12038 from 17.4% by up to 2.5%. The presence of nano-ZnO in PBs uninfluenced their swelling, water absorption, and bending strength; however, it decreased their internal bond strength by up to 38.8%.

Glued laminated (glulam) beams are used in the roofs, ceilings and walls of buildings as well as in bridges and towers. At present, with the limitation of tree harvesting, the production of glulam beams from recycled wood sources is implemented with the proviso that their mechanical properties and resistance to pests, fire and weathering will not be aggravated. This work deals with the primary effect of aging Norway spruce wood (Picea abies Karst. L.) lamellas on the moduli of rupture (MOR) and elasticity (MOE) in bending of three-layer glulam beams composed of sound and aged lamellas and polyurethane (PUR) glue. Three methods of lamella aging were used: (A) natural, lasting 60 years in the form of roof trusses with a greater or lesser degree of bio-attack by woodworm (Anobium punctatum De Geer); (B) artificial, caused by increased temperatures from 160 to 220 °C for 4 h; (C) artificial, caused by 2% water solutions of inorganic preservatives, namely, CuSO4 × 5H2O, ZnCl2, H3BO3 or (NH4)2SO4, for 28 days. The lowest MOR values were determined for glulam beams in which all three lamellas or two surface lamellas had a greater degree of bio-attack (60.5 MPa, a decrease of 25.9%) or were exposed to primary aging at 220 °C (62.6 MPa, a decrease of 23.3%). On the contrary, the exposure of lamellas to 160 or 180 °C did not significantly influence the MOR of beams (76.0–82.7 MPa, an average decrease of 1.6%). The MOE of glulam beams ranged from 7540 to 10,432 MPa without an obvious influence of the method of lamella aging or their location in the beams. Linear correlations between the MOR or MOE of glulam beams and the shear strength (σ) of glued joints, if both composite types consisted of similarly aged lamellas, were only slightly significant or insignificant.

Building structures made from fir wood are often attacked by wood-destroying insects for which the terpenes it contains serve as attractants. One of the possibilities for extending the lifetime of structures is to use older wood with a lower content of terpenes and/or thermally modified wood. The study evaluated the levels of terpenes in naturally aged fir wood (108, 146, 279, 287 and 390 years) and their decrease by thermal treatment (the temperature of 60 °C and 120 °C, treatment duration of 10 h). Terpenes were extracted from wood samples by hexane and analyzed by gas-chromatography mass-spectrometry (GC-MS). The results indicate that recent fir wood contained approximately 60 times more terpenes than the oldest wood (186:3.1 mg/kg). The thermal wood treatment speeded up the release of terpenes. The temperature of 60 °C caused a loss in terpenes in the recent fir wood by 62%, the temperature of 120 °C even by >99%. After the treatment at the temperature of 60 °C the recent fir wood had approximately the same quantity of terpenes as non-thermally treated 108 year old wood, i.e., approximately 60–70 mg/kg. After the thermal treatment at the temperature of 120 °C the quantity of terpenes dropped in the recent as well as the old fir wood to minimum quantities (0.7–1.1 mg/kg). The thermal treatment can thus be used as a suitable method for the protection of fir wood from wood-destroying insects.

The effective recovery of wood waste generated in wood processing and also at the end of wood product life is important from environmental and economic points of view. In a laboratory, 16 mm-thick three-layer urea–formaldehyde (UF)-bonded particleboards (PBs) were produced at 5.8 MPa and 240 °C and with an 8 s/mm pressing factor, using wood particles prepared from (1) fresh spruce wood (C), (2) a mixture of several recycled wood products (R1), and (3) recycled faulty PBs bonded with UF resin (R2). Particles from spruce wood were combined with particles from R1 or R2 recyclates in weight ratios of 100:0, 80:20, 50:50 and 0:100. In comparison to the control spruce PB, the PBs containing the R1 recyclate from old wood products were characterized by lower thickness swelling after 2 and 24 h (TS-2h and TS-24h), lower by 18 and 31%; water absorption after 2 and 24 h (WA-2h and WA-24h), lower by 33 and 28%; modulus of rupture in bending (MOR), lower by 28%; modulus of elasticity in bending (MOE), lower by 18%; internal bond (IB), lower by 33%; and resistance to decay determined by the mass loss under the action of the brown-rot fungus Coniophora puteana (Δm), lower by 32%. The PBs containing the R2 recyclate from faulty PBs were also characterized by a lower TS-2h and TS-24h, lower by 45% and 59%; WA-2h and WA-24h, lower by 61% and 51%; MOR, lower by 37%; MOE, lower by 17%; and IB, lower by 33%; however, their biological resistance to C. puteana was more effective, with a decreased Δm in the decay test, lower by 44%.

This study investigates the effects of wood weathering on changes in its macroscopic and colour characteristics in connection with changes in its molecular and anatomical structure. Seven hardwoods suitable for outdoor architecture—bangkirai, cumaru, cumaru rosa, ipé, jatobá, kusia, and massaranduba—were exposed to the exterior out of ground contact for 1–36 months according to EN 927-3, and for 1–12 weeks in Xenotest with water spraying according to partly modified EN 927-6. With prolonged weathering, the following changes occurred in the top surfaces of all tropical woods: (1) visual—creation of longitudinal macro-cracks, (2) spectrophotometry and CIE- L ∗ a ∗ b ∗ —darkening in exterior exposure mainly due to pollutants, except for ipé, and vice versa lightening in Xenotest, as well as greening and blueing in both modes of exposure, (3) FTIR—faster decrease of guaiacyl than syringyl lignin, absolute decrease of conjugated and unconjugated carbonyl groups in the newly formed lignin-polysaccharide-extractive substrate in the photo-oxidized and washed-out cell walls, and decrease of cellulose crystallinity, (4) SEM—damaging of cell-walls by micro-cracks, and their degradation by thinning. Connections between changes of the individual characteristics of weathered woods, for example, between the colour ( ΔE *, etc.) and the molecular structure (carbonyls, etc.), were also determined.