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With increasing urbanization and industrialization, soil and forest resources are facing considerable pressure, as well as the demand for water for domestic, agricultural, and industrial activities. Therefore, it is essential to conduct regular assessments of water quality and ensure that water is consistently maintained in the context of ecosystem services (ESs). Our objective was to apply the driving forces–pressures–state–impacts–responses (DPSIR) model to understand the cause–effect relationships and interactions with anthropogenic pressures on deforestation and water quality in the Talgua River watershed and associated valley and plain areas in central-eastern Honduras. Physicochemical and microbiological analyses were conducted to determine the water quality index (NSF–WQI) and other contamination indexes. The results identified high contamination by coliforms, up to 920.00 NPM/100 mL, and high levels of contamination by organic matter (ICOMO, 0.65), solids (ICOSUS, 0.79), mineralization (ICOMI, 0.99), and the presence of bacteria (BPI, 8.50), as well as the development of eutrophication processes (ICOTRO), resulting in generally low water quality. These problems were caused by the socio-demographic and economic growth of the area, as well as the high demand for water, vulnerability to climate change, and intense agro-livestock and industrial activity, which led to deforestation processes, changes in land use, and contamination of natural water bodies that impacted the overexploitation of aquifers. After applying the DPSIR model, strategies are proposed for the management and administration of the watershed aimed at preserving the water, soils, and forest resources, while promoting stakeholder, business, education sector, and public administration participation.

Anthropogenic land cover change is directly responsible for the deforestation and degra-dation of tropical forests. In this context, assessing soil organic carbon (SOC) stocks is key to understanding the impact of anthropogenic activities on SOC so that we can implement management practices that effectively reduce emissions or promote carbon sequestration. Our objective was to assess the effect of land-use change on the dynamics and distribution of SOC in three systems (agriculture, pasture and agroforestry) after 40 years of deforestation in a tropical dry forest in the central–eastern region of Honduras. For this purpose, the bulk density, percentage of coarse fragments (>2 mm) and soil organic carbon content were determined at three depths (0.00–0.10 m, 0.10–0.20 m and 0.20–0.30 m). The results showed an increase in bulk density for all new uses, although soil compaction had not yet occurred. In terms of total soil organic carbon (TOC) stocks, deforestation caused a decrease from 17% to 48% in agricultural and agroforestry soils, respectively; on the other hand, grasslands did not show significant differences compared to tropical dry forest, suggesting that they have a high potential as carbon sinks in deforested tropical areas. However, this did not imply a better state of the system, as the greatest increases in bulk density were found in pastures.

Growth alterations have been described in patients operated on for oral clefts. The purpose of this work was to analyze the craniofacial and palate morphology and dimensions of young adults operated on for oral clefts in early childhood in Spain. Eighty-three patients from eight different hospitals were divided into four groups based on their type of cleft: cleft lip (CL, n = 6), unilateral cleft lip and palate (UCLP, n = 37), bilateral cleft lip and palate (BCLP, n = 16), and cleft palate only (CPO, n = 24). A control group was formed of 71 individuals. Three-dimensional (3D) digital models were obtained from all groups with an intraoral scanner, together with cephalometries and frontal, lateral, and submental facial photographs. Measurements were obtained and analyzed statistically. Our results showed craniofacial alterations in the BCLP, UCLP, and CPO groups with an influence on the palate, maxilla, and mandible and a direct impact on facial appearance. This effect was more severe in the BCLP group. Measurements in the CL group were similar to those in the control group. Cleft characteristics and cleft type seem to be the main determining factors of long-term craniofacial growth alterations in these patients. Prospective research is needed to clearly delineate the effects of different treatments on the craniofacial appearance of adult cleft patients.

This study deals with a circular economy model to manage biomass of L. derived from the phytoremediation of soils with Pb, Zn and Tl metal(oid)s. The species showed high efficacy in phytostabilization, retaining 65% of the metals in the roots. Bioconcentration factors (BAF < 0.5) and translocation (TF < 1) confirmed its behavior as an excluder, minimizing the risk of trophic transfer. This research validated the transformation of this biomass under a zero-residue approach. Via hydrodistillation, essential oils and hydrosols (yield > 0.4%; 0.93 g/mL) were obtained, whose chemical safety was guaranteed by the absence of heavy metals (ICP-MS). Subsequently, the residual biomass was recovered by pyrolysis at 600 °C, obtaining a biochar with a specific surface area (SSA) of 393.7 m /g and an electrical conductivity of 35 S/cm. This performance can be attributed to the synergistic effect of the carbonaceous matrix and encapsulated metals, which act as natural dopants for supercapacitor electrodes. In conclusion, the work demonstrated the transition from hazardous waste to advanced industrial byproducts, integrating environmental remediation with the production of materials for energy storage under safety and sustainability criteria.

The transformation of natural ecosystems into agroecosystems due to changes in land use/land cover (LULC) has been shown to significantly affect soil characterization and classification. The impact of LULC on soil taxonomy was assessed in a primary forest located in central–eastern Honduras, which had been deforested approximately forty years prior to the study. Morphological, physical, and physicochemical analyses were performed by describing 10 representative profiles, applying the Soil Taxonomy (ST) and World Reference Base for Soil Resources (WRB) nomenclatures. LULC resulted in physical degradation in agricultural areas, as evidenced by lighter-colored horizons (P02), reduced granular structure (P01, P02, P05), higher bulk densities (≤1.73 Mg m−3), and surface crusting (P02, P05); this phenomenon was also observed in pastures (P06–P09). SOC loss was 62% in croplands, 47–53% in agroforestry systems (P03) and fruit tree plantations (P04), and 25% in pastures. All profiles exhibited pH values between 6.5 and 8.4 and complete base saturation (BS), except for P08 and P09, which had pH values below 5.5, high levels of Al3+, and reduced BS (50–60%). Mollic epipedons and variability in the endopedons were also observed. According to the ST of the System of Soil Classification (SSC), the soils were classified as Mollisols, Entisols, Vertisols, and Alfisols; and as Phaeozems, Fluvisols, Gleysols, Anthrosols, Gypsisols, and Plinthosols by the WRB. We advocate for the inclusion of Anthropogenic Soils as a distinct Order within Soil Taxonomy (ST). The implementation of sustainable agricultural practices, in conjunction with the formulation of regulatory frameworks governing land use based on capacity and suitability, is imperative, particularly within the context of fragile tropical systems.

Background To determine whether there is greater employee satisfaction in organisations that have made more progress in implementation of the European Foundation for Quality Management (EFQM) model. Methods A series of cross-sectional studies (one for each assessment cycle) comparing staff satisfaction survey results between groups of healthcare organisations by degree of implementation of the EFQM model (assessed in terms of external recognition of management quality in each organisation). Setting: 30 healthcare organisations including hospitals, primary care and mental health providers in Osakidetza, the Basque public health service. Participants: Employees of 30 Osakidetza organisations. Intervention: Progress in implementation of EFQM model. Main outcome measures: Scores in 9 dimensions of employee satisfaction from questionnaires administered in healthcare organisations in 4 assessment cycles between 2001 and 2010. Results Comparing satisfaction results in organisations granted Gold or Silver Q Awards and those without this type of external recognition, we found statistically significant differences in the dimensions of training and internal communication. Then, comparing recipients of Gold Q Awards with those with no Q Certification, differences in leadership style and in policy and strategy also emerged as significant. Conclusions Progress of healthcare organisations in the implementation of the EFQM Excellence Model is associated with increases in their employee satisfaction in dimensions that can be managed at the level of each organisation, while dimensions in which no statistically significant differences were found represent common organisational elements with little scope for self-management.

An abandoned sphalerite mining area in the southwest (SW) of the Iberian Peninsula was studied to evaluate the impact that the presence of metal(loid)s has on soil and ecosystem health. Five zones were delimited: sludge, dump, scrubland, riparian zone, and dehesa. Critical total levels of lead (Pb), zinc (Zn), thallium (Tl), and chromium (Cr), well above the limit indicative of toxicity problems, were found in the areas close to the sources of contamination. Pb-Zn concentrations were very high in the riparian zone, reaching values of 5875 mg/kg Pb and 4570 mg/kg Zn. The whole area is classifiable as extremely contaminated with Tl, with concentrations above 370 mg/kg in the scrubland. Cr accumulation mainly occurred in areas away from the dump, with levels up to 240 mg/kg in the dehesa. In the study area, several plants were found growing luxuriantly despite the contamination. The measured metal(loid)s content is the cause of a significant decrease in ecosystem services, resulting in unsafe soils for food and water production, so the implementation of a decontamination program is advisable. The plant species Retama sphaerocarpa, present in the sludge, scrubland, riparian zone, and dehesa, is postulated as suitable for use in phytoremediation.

Silicon oxycarbide ceramers containing 5% aluminum, zirconium, and cobalt with respect to the total Si amount are prepared from a commercial polysiloxane and molecular precursors and pyrolyzed at temperatures ranging from 500 to 1000 °C. HF etching is carried out to partially digest the silica phase, thus revealing structural characteristics of the materials, which depend upon the incorporated heteroatom. From the structural and textural characterization, it was deduced that when Al enters into the ceramer structure, the crosslinking degree is increased, leading to lower carbon domain size and carbon incorporation as well. On the contrary, the substitution by Zr induced a phase-separated SiO2-ZrO2 network with some degree of mesoporosity even at high pyrolysis temperatures. Co, however, forms small carbidic crystallites, which strongly modifies the carbonaceous phase in such a way that even when it is added in a small amount and in combination with other heteroatoms, this transient metal dominates the structural characteristics of the ceramer material. This systematic study of the ceramer compounds allows the identification of the ultimate properties of the polymer-derived ceramic composites.

The synthesis of C-rich ceramers from a commercial polycarbosilane has been realized through the incorporation of divinylbenzene (DVB) to the polymer SMP-10. After pyrolysis, the obtained ceramers were dry etched to produce highly porous carbide-derived carbons (CDCs). The excess carbon was segregated in the form of amorphous carbon out from the ceramer matrix. The resulting CDCs possess a carbon nanocrystallite size which turns to be independent on the DVB incorporated or the pyrolysis and chlorination temperature. The electrochemical characterization reveals that the consolidation of the ceramer or ceramic network leads to a reduction of the carbon heterogeneities, thus improving its electric conductivity. When the ceramic network is formed, the behavior of the CDC as electrode supercapacitor is optimized and turns to be independent on the amount of DVB incorporated. Graphical Abstract

Ionic liquids (ILs) and deep eutectic solvents (DESs) are the two most widely used neoteric solvents. Recently, our group described how the simple addition of acetic acid (AcOH) to 1-Ethyl-3-methylimidazolium chloride (EMIMCl) could promote the transition from the original IL to an eutectic mixture of EMIMCl and AcOH. Herein, we studied how cellulose regeneration and EMIMCl recovery from EMIMCl solutions of cellulose could be benefited by the significant differences existing between EMIMCl- and EMIMCl·AcOH-based mixtures and the easy switching from one to the other. Finally, we also demonstrated that the transition could also be accomplished by addition of acetic anhydride and water so that the process could be eventually useful for the achievement of highly acetylated cellulose.