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We report the first detailed characterization of the sheet third-harmonic optical susceptibility, χ (3) s , of tungsten diselenide (WSe 2 ). With a home-built multiphoton microscope setup developed to study harmonics generation, we map the second and third-harmonic intensities as a function of position in the sample, pump power and polarization angle, for single- and few-layers flakes of WSe 2 . We register a value of | χ (3) s | ≈ 0.9 × 10 −28  m 3 V −2 at a fundamental excitation frequency of ℏω  = 0.8 eV, which is comparable in magnitude to the third-harmonic susceptibility of other group-VI transition metal dichalcogenides. The simultaneously recorded sheet second-harmonic susceptibility is found to be | χ (2) s | ≈ 0.7 × 10 −19  m 2  V −1 in very good agreement on the order of magnitude with recent reports for WSe 2 , which asserts the robustness of our values for | χ (3) s |.

Nitrogen (N) is a limiting ecological factor for plant growth in most agroecosystems. Biological N fixation, especially from nodulated legumes, has been promoted in recent decades as an alternative or complement to industrially synthesized N fertilizers. The possibility of utilizing N-fixing organisms from the phyllosphere that demonstrate effectiveness across a wide range of crops is particularly exciting. In this study, we examined the N-fixing capacity and the impact on lettuce growth of an inoculant recently introduced to the market, which contains the microorganism Methylobacterium symbioticum and is recommended for various cultivated species. A pot experiment was conducted using a factorial design, which included the inoculant (No and Yes) and four N rates (0 (N0), 25 (N25), 50 (N50), and 100 (N100) kg ha−1 of N), with four replicates, over four lettuce growing cycles. The inoculant had a significant effect on dry matter yield (DMY) only during the second of the four growing cycles. The mean values of the four growing cycles ranged from 9.9 to 13.7 g pot−1 and 9.9 to 12.6 g kg−1 in pots that received and did not receive the inoculant, respectively. On the other hand, plants exhibited a robust response to N applied to the soil, showing significant increases in both DMY and tissue N concentration across all growing cycles. Mean values of DMY in the treatments N0 and N100 ranged from 5.6 to 8.9 g pot−1 and 12.5 to 16.1 g pot−1, respectively. N concentration in tissues varied inversely with DMY, indicating a concentration/dilution effect. The difference in N concentration between treated and untreated plants, used as an estimate of fixed N, was very low for each of the soils’ applied N rates, assuming average values for the four growing cycles of −1.5, −0.9, 2.4, and 6.3 kg ha−1 for N0, N25, N50, and N100, respectively. This study emphasized the low amount of N supplied to lettuce by the inoculant and its limited effect on DMY. Generally, in biological systems with N-fixing microorganisms, achieving high fixation rates requires a high level of specificity between the microorganism and host plant, a condition that seems not to have been met with lettuce. Considering the importance of the subject, is imperative that further studies be conducted to determine more precisely in which crops and under what growing conditions the inoculant proves to be a valuable input for farmers and an effective method for reducing N mineral fertilization.

Sub-Saharan African smallholder farmers face challenges due to limited access to commercial fertilizers, affecting food security. Exploring the benefits of intercropping is promising, but evaluating crop performance in specific agroecological contexts is crucial. This study in Vilankulo, Mozambique, conducted over two growth seasons (2018 and 2019), aimed to assess the benefits of intercropping maize (Zea mays L.) and cowpea (Vigna unguiculata L., Walp) (M+C) compared to maize (M) and cowpea (C) as sole crops. Key variables for comparison included dry matter yield (DMY), land equivalent ratio (LER), competitive ratio (CR), tissue nutrient concentration, nutrient recovery, and apparent N fixation (ANF). This study also examined the effects on cabbage (Brassica oleracea L.), cultivated as a succeeding crop, and soil properties. In 2018, maize plants were severely affected by drought and did not produce grain. This year, cowpea grain yields were 2.26 and 1.35 t ha−1 when grown as sole crop or intercropped. In 2019, maize grain yield was 6.75 t ha−1 when intercropped, compared to 5.52 t ha−1 as a sole crop. Cowpea grain yield was lower when intercropped (1.51 vs. 2.25 t ha−1). LER values exceeded 1 (1.91 and 1.53 for grain and straw in 2019), indicating improved performance in intercropping compared to sole crops. In 2019, CR was 1.96 for maize grain and 0.58 for cowpea grain, highlighting the higher competitiveness of maize over cowpea. Cowpea exhibited higher average leaf nitrogen (N) concentration (25.4 and 37.6 g kg−1 in 2018 and 2019, respectively) than maize (13.0 and 23.7 g kg−1), attributed to its leguminous nature with access to atmospheric N, benefiting the growth of maize in intercropping and cabbage cultivated as a succeeding crop. Cowpea also appears to have contributed to enhanced phosphorus (P) absorption, possibly due to access to sparingly soluble P forms. In 2019, ANF in M+C was 102.5 kg ha−1, over 4-fold higher than in C (25.0 g kg−1), suggesting maize accessed more N than could cowpea provide, possibly through association with endophytic diazotrophs commonly found in tropical grasses.

In this paper, we will use the coincident gauge to investigate new solutions of the f ( Q ) theory applied in the context of black holes, regular black holes, and the black-bounce spacetime. For each of these approaches, we compute the linear solutions and the solutions with the constraint that the non-metricity scalar is zero. We also analyze the geodesics of each solution to interpret whether the spacetime is extensible or not, find the Kretschmann scalar to determine the regularity along spacetime, and in the context of regular black holes and black-bounce, we calculate the energy conditions. In the latter black-bounce case we realize that the null energy condition ( NEC ), specifically the N E C 1 = W E C 1 = S E C 1 ↔ ρ + p r ≥ 0 , is satisfied outside the event horizon.

A polymorph of glycyl-L-alanine HI.H2O is synthesized from chiral cyclo-glycyl-L-alanine dipeptide. The dipeptide is known to show molecular flexibility in different environments, which leads to polymorphism. The crystal structure of the glycyl-L-alanine HI.H2O polymorph is determined at room temperature and indicates that the space group is polar (P21), with two molecules per unit cell and unit cell parameters a = 7.747 Å, b = 6.435 Å, c = 10.941 Å, α = 90°, β = 107.53(3)°, γ = 90° and V = 520.1(7) Å3. Crystallization in the polar point group 2, with one polar axis parallel to the b axis, allows pyroelectricity and optical second harmonic generation. Thermal melting of the glycyl-L-alanine HI.H2O polymorph starts at 533 K, close to the melting temperature reported for cyclo-glycyl-L-alanine (531 K) and 32 K lower than that reported for linear glycyl-L-alanine dipeptide (563 K), suggesting that although the dipeptide, when crystallized in the polymorphic form, is not anymore in its cyclic form, it keeps a memory of its initial closed chain and therefore shows a thermal memory effect. Here, we report a pyroelectric coefficient as high as 45 µC/m2K occurring at 345 K, one order of magnitude smaller than that of semi-organic ferroelectric triglycine sulphate (TGS) crystal. Moreover, the glycyl-L-alanine HI.H2O polymorph displays a nonlinear optical effective coefficient of 0.14 pm/V, around 14 times smaller than the value from a phase-matched inorganic barium borate (BBO) single crystal. The new polymorph displays an effective piezoelectric coefficient equal to deff=280 pCN−1, when embedded into electrospun polymer fibers, indicating its suitability as an active system for energy harvesting.

In this article, the implementation of black-bounce solutions in f ( R ) theories is investigated. Black-bounce solutions are regular configurations of the static spherically symmetric space-time, containing both black holes and wormholes structures. In General Relativity (GR), black-bounce solution implies violation of the energy conditions. We investigate the same issue in f ( R ) theories using two strategies: first, supposing a given form for the f ( R ) function and then determining the matter behavior; second, imposing a condition on the matter density and obtaining the resulting f ( R ) function. In all cases, a given structure for the metric functions is supposed. Violation of the energy conditions still occur but they are less severe than in the corresponding GR cases. We propose a zero-density model that has horizons, which differs from the GR case. We also propose a model with positive energy density and show that ρ + p r > 0 , which was not the case in GR.

The inspection of encapsulated MEMS devices typically relies on destructive methods which compromise the structural integrity of samples. In this work, we present the concept and preliminary experimental validation of a laser scanning setup to non-destructively inspect silicon-encapsulated microstructures by measuring small variations of transmitted light intensity in the near-infrared spectrum. This method does not require any particular sample preparation or damage, and it is based on the higher degree of transparency of silicon in the near-infrared and the transmission contrast resulting from the Fresnel reflections observed at the interfaces between the different materials of the MEMS device layers. We characterise the small feature resolving performance of the laser scanning setup using standard targets, and experimentally demonstrate the inspection of a MEMS latching device enclosed within silicon covers, comparing the contrast measurements with theoretical predictions.

In this work, we analyse black bounce solutions in the recently proposed “Conformal Killing gravity” (CKG), by coupling the theory to nonlinear electrodynamics (NLED) and scalar fields. The original motivation of the theory was essentially to fulfill specific criteria that are absent in existing gravitational theories, namely, to obtain the cosmological constant as an integration constant, derive the energy–momentum conservation law as a consequence of the gravitational field equations, rather than assuming it, and not necessarily considering conformally flat metrics as vacuum solutions. In this work, we extend the static and spherically symmetric solutions obtained in the literature, and explore the possibility of black bounces in CKG, coupled to NLED and scalar fields. We find novel NLED Lagrangian densities and scalar potentials, and extend the class of black bounce solutions found in the literature. Furthermore, within black bounce geometries, we find generalizations of the Bardeen-type and Simpson–Visser geometries and explore the regularity conditions of the solutions.

One of the main issues in gravitation is the presence of singularities in the most common space-time solutions of General Relativity, as the case of black holes. A way of constructing regular solutions that remove spacelike singularities consists in implement a bounce on such space-time, leading to what is usually known as black bounce space-times. Such space-times are known to describe regular black holes or traversable wormholes. However, one of the main issues lies on reconstructing the appropriate source that leads to such a solution. In this paper, a reconstruction method is implemented to show that such types of metrics can be well accommodated in non-linear electrodynamics with the presence of a scalar field. Some of the most important black bounces solutions are reconstructed in this framework, both in 3 + 1 as in 2 + 1 dimensions. For the first time in the literature, these solutions have an electrically charged source of matter from non-linear electrodynamics. Specific features are indicated that distinguish electric sources from magnetic ones, previously found for the same space-times.

When used as maintenance therapy, the PARP inhibitor olaparib provided a significant progression-free survival benefit in women with ovarian cancer who had a response to primary chemotherapy, particularly in those whose tumors were deficient in homologous recombination (e.g., BRCA -mutated tumors). Hematologic toxic effects were observed.