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This article presents an analysis of porous materials subjected to oblique loading. The analysis was carried out with the Abaqus software using the finite element method. The material model used for numerical analysis was Crushable Foam. The subject of the study involved solid elements located on a base with a variable angle of inclination. The values of the base angle were 15, 30, 45, 60 degrees. All samples were loaded with the same boundary conditions. During the test, the normal and shear forces were determined. The crushing efficiency indicators were calculated from the measured forces. The aim of the tests was to define the distribution of forces in the foam element.

We investigate the thermal reduction of TiO 2 in ultra-high vacuum. Contrary to what is usually assumed, we observe that the maximal surface reduction occurs not during the heating, but during the cooling of the sample back to room temperature. We describe the self-reduction, which occurs as a result of differences in the energies of defect formation in the bulk and surface regions. The findings presented are based on X-ray photoelectron spectroscopy carried out in - operando during the heating and cooling steps. The presented conclusions, concerning the course of redox processes, are especially important when considering oxides for resistive switching and neuromorphic applications and also when describing the mechanisms related to the basics of operation of solid oxide fuel cells.

The purpose of this study was to ascertain the relationships between the amplitude of the corneal pulse (CP) signal and the parameters of corneal biomechanics during ex-vivo intraocular pressure (IOP) elevation experiments on porcine eyes with artificially induced ocular pulse cycles. Two experiments were carried out using porcine eyes. In the first one, a selected eye globe was subjected to three IOP levels (15, 30 and 45 mmHg), where changes in physical ocular pulse amplitude were controlled by infusion/withdrawal volumes (ΔV). In the second experiment, six eyes were subjected to IOP from 15 mmHg to 45 mmHg in steps of 5 mmHg with a constant ΔV, where corneal deformation parameters were measured using Corvis ST. In both experiments, at each IOP, the CP and IOP signals were acquired synchronically using a non-contact ultrasonic distance sensor and a pressure transmitter, respectively. Based on the amplitudes of the CP and IOP signals ocular pulse based corneal rigidity index (OPCRI) was calculated. Results indicate positive correlations between ΔV and the physical ocular pulse amplitude, and between ΔV and the corneal pulse amplitude (both p < 0.001). OPCRI was found to increase with elevated IOP. Furthermore, IOP statistically significantly differentiated changes in OPCRI, the amplitudes of CP and IOP signals and in most of the corneal deformation parameters (p < 0.05). The partial correlation analysis, with IOP as a control variable, revealed a significant correlation between the length of the flattened cornea during the first applanation (A1L) and the corneal pulse amplitude (p = 0.002), and between A1L and OPCRI (p = 0.003). In conclusion, this study proved that natural corneal pulsations, detected with a non-contact ultrasonic technique, reflect pressure-volume dynamics and can potentially be utilized to assess stiffness of the cornea. The proposed new rigidity index could be a simple approach to estimating corneal rigidity.

This article presents the use of artificial neural networks in data analysis. The subject of the research were energy-absorbing materials under oblique loading. The forces obtained during the analysis were used to determine the crushing indicators. The numerical analysis was performed using the FEM Abaqus software. The specimens were loaded with the same force at different angles, i.e. 15, 30, 45, 60 degrees. During the numerical analyses, the normal and shear forces were measured. The tests were carried out under both static and dynamic load. On the basis of the MLP and RBF networks, analyses were carried out to study the relationship between the foam properties and the crushing efficiency indicators.

AFO (Ankle-Foot Orthosis), which covers the ankle and foot, protects and supports the ankle joint as well as the structures around it. It contributes to the maintenance of the correct gait cycle. Owing to orthoses, the functional capacity of the body part is significantly improved, and so is the quality of life for the user. Personalized orthoses, which are adapted to the anatomy of the user, are more and more often produced by the additive methods. The use of 3D printing for the manufacturing medical devices is becoming increasingly common due to the low cost of the whole process, short production time and the possibility of the product personalization. One of the stages in manufacturing AFOs with the additive method is to create a three-dimensional model of the orthosis in CAD software. Finite element analysis was performed to assess the mechanical properties of the orthosis. The influence of geometry and the materials used were investigated with FEM analysis software. As a result of structural analysis during the design stage, the assessment of the medical device in terms of its durability and mechanical resistance without putting the user at risk is possible. On the basis of the obtained results, the structure strength was compared.

This paper presents the results of the numerical analysis of thin-walled structures with a square cross-section. Aluminium models contain different types of triggers and distance to the base. Postbuckling analyses were compared with the form of the buckle to find the most beneficial location of the trigger. The study problem was approachedwith FEM Abaqus.Numerical analysis results are shown in theLoad-Shortening diagram. The data obtained during numerical analysis were used to determine the crushing efficiency indicators such as SE, CLE, TE. The aim of the research was to obtain the best efficiency indicators for the tested positions of triggers.

We investigate the thermal reduction of TiO in ultra-high vacuum. Contrary to what is usually assumed, we observe that the maximal surface reduction occurs not during the heating, but during the cooling of the sample back to room temperature. We describe the self-reduction, which occurs as a result of differences in the energies of defect formation in the bulk and surface regions. The findings presented are based on X-ray photoelectron spectroscopy carried out in-operando during the heating and cooling steps. The presented conclusions, concerning the course of redox processes, are especially important when considering oxides for resistive switching and neuromorphic applications and also when describing the mechanisms related to the basics of operation of solid oxide fuel cells.

The analysis of the electronic surface properties of transition metal oxides being key materials for future nanoelectronics requires a direct characterization of the conductivity with highest spatial resolution. Using local conductivity atomic force microscopy (LC-AFM) we demonstrate the possibility of recording current maps with true atomic resolution. The application of this technique on surfaces of reduced TiO\\(_2\\) and SrTiO\\(_3\\) reveals that the distribution of surface conductivity has a significant localized nature. Assisted by density functional theory (DFT) we propose that the presence of oxygen vacancies in the surface layer of such materials can introduce short range disturbances of electronic structure with confinement of metallic states on the nanoscale.

The influence of intrinsic defects of 1T-TaS2 on charge density waves (CDW) is studied using scanning tunneling microscopy and spectroscopy (STM, STS), angle-resolved photoelectron spectroscopy (ARPES), and density functional theory (DFT). We identify several types of structural defects and find that most have a local character limited to the single CDW site, with single exception which effectively behaves as a dopant, leading to band bending and affecting multiple neighboring sites. While only one type of defect can be observed by STM topographic imaging, all defects are easily resolved by local density of states (LDOS) mapping with STS. We correlate atomically-resolved STM periodicity of defect-free 1T-TaS2 to top sulfur atoms and introduce tiling of the surface using equiangular hexagon. DFT calculations (with included Coulomb interactions) are used to investigate the electronic structure by introducing sulfur vacancy or substituting sulfur with oxygen. The sulfur vacancy is characterized by metallic properties and is identified as an origin of one of observed experimentally defects. Whereas in the case of the latter, the oxidation of 1T-TaS2 is found to result in the loss of magnetic properties expected in defect-free material.