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Submarine methane seepage can potentially be promoted by the dissociation of the marine hydrates surrounding the continental margins due to oceanic warming since the Last Glacial Maximum. This seepage could be archived by authigenic carbonates at seeping sites, but the time lag caused by heat transmission through the sediment column leads to an inconsistency between the ages of the carbonate and the period of bottom water warming. Here we present the records of the authigenic carbonate crust from drilling site D1 in the Mid‐Okinawa Trough. Uranium–thorium dating results show that the carbonate crust mainly grew downwards during 14–6 ka. Gas hydrates hosted in the relatively thin stability zone dissociated in a rapid response to bottom water warming and intensified the methane seepage. Our study better supports the hypothesis that a considerable amount of methane can be released from marine hydrates due to global climatic changes. Plain Language Summary Methane hydrates are ice‐like crystalline compounds and often found in deep‐ocean marine sediments. Ocean warming in the past could have destabilized methane hydrates and led to a rapid discharge of free methane gas. Geological information on this methane escape could be preserved by carbonate rocks. To date, the hypothesis of the control of ocean warming on hydrate melting since the Last Glacial Maximum (19,000–26,000 years ago) has not been fully tested. To examine this hypothesis, we used the rock samples of seep‐carbonate retrieved by seafloor drilling in the Mid‐Okinawa Trough. Uranium–thorium dating results show that the seep carbonates formed between 6,000 and 14,000 years ago. It took less time for heat to diffuse downwards from warming seawater to trigger hydrate melting at this location than in most of other oceans at similar water depths. The smaller time lag makes the carbonate rock age close to the period of ocean warming. Our results better support that global ocean warming could potentially release methane from gas hydrates during glacial–interglacial transitions. The consequent methane transport into the oceans and likely also the atmosphere might impact ocean acidification and climatic warming. Key Points Presentation of the chronology of methane seepage by dating authigenic carbonates collected from drilling core D1 in the Okinawa Trough Ocean warming–induced hydrate dissociation led to the downward growth of authigenic carbonate for 14–6 ka after the Last Glacial Maximum This carbonate record better supports the link of hydrate dissociation with ocean warming due to a smaller thermal lag effect

Submarine magmatic–hydrothermal systems, where magmatic volatiles and fluids possibly serve as major sources of mineralization elements, have been extensively documented in numerous felsic‐hosted hydrothermal fields. Previous studies have primarily focused on the contribution of magmatic volatiles in such hydrothermal systems. Although evidence has indicated that magmatic fluids have a greater capacity for transporting metals to overlying hydrothermal systems, their specific role in magmatic–hydrothermal systems remains inadequately understood. This study provides compelling evidence for the contribution of metal‐rich magmatic fluid to the Minami–Ensei (ME) hydrothermal system. Pulsed injections of metal‐rich magmatic fluids into the overlying hydrothermal system during mineralization process result in the elevated salinity (6.1–9.7 wt.% NaCl equiv) and δ18O values (1.1–8.0‰) in ME hydrothermal fluids, which are recorded by barite fluid inclusions and oxygen (O) isotope compositions, respectively. Laser‐induced breakdown spectroscopy analysis indicated that the magmatic fluids injected into the ME were likely Fe‐rich. Metal concentrations in magmatic fluids are several orders of magnitude higher than those in hydrothermal fluids generated via leaching, and their contribution to overlying hydrothermal systems can substantially enhance sulfide mineralization efficiency in magmatic–hydrothermal deposits. This study underscores the potential of magmatic–hydrothermal systems as promising targets for future sulfide ore exploration.

Cardiovascular diseases are the most distributed cause of death worldwide. Stenting of arteries as a percutaneous transluminal angioplasty procedure became a promising minimally invasive therapy based on re-opening narrowed arteries by stent insertion. In order to improve and optimize this method, many research groups are focusing on designing new or improving existent stents. Since the beginning of the stent development in 1986, starting with bare-metal stents (BMS), these devices have been continuously enhanced by applying new materials, developing stent coatings based on inorganic and organic compounds including drugs, nanoparticles or biological components such as genes and cells, as well as adapting stent designs with different fabrication technologies. Drug eluting stents (DES) have been developed to overcome the main shortcomings of BMS or coated stents. Coatings are mainly applied to control biocompatibility, degradation rate, protein adsorption, and allow adequate endothelialization in order to ensure better clinical outcome of BMS, reducing restenosis and thrombosis. As coating materials (i) organic polymers: polyurethanes, poly(ε-caprolactone), styrene-b-isobutylene-b-styrene, polyhydroxybutyrates, poly(lactide-co-glycolide), and phosphoryl choline; (ii) biological components: vascular endothelial growth factor (VEGF) and anti-CD34 antibody and (iii) inorganic coatings: noble metals, wide class of oxides, nitrides, silicide and carbide, hydroxyapatite, diamond-like carbon, and others are used. DES were developed to reduce the tissue hyperplasia and in-stent restenosis utilizing antiproliferative substances like paclitaxel, limus (siro-, zotaro-, evero-, bio-, amphi-, tacro-limus), ABT-578, tyrphostin AGL-2043, genes, etc. The innovative solutions aim at overcoming the main limitations of the stent technology, such as in-stent restenosis and stent thrombosis, while maintaining the prime requirements on biocompatibility, biodegradability, and mechanical behavior. This paper provides an overview of the existing stent types, their functionality, materials, and manufacturing conditions demonstrating the still huge potential for the development of promising stent solutions.

Low-strength sediment layers within continental slope strata precondition submarine sediment for failure, potentially leading to destructive tsunamis. Using geophysical and Ocean Drilling Program well data, here we show that the glide planes of widespread submarine failures in the northern South China Sea, dated to the glacial stages following the Mid-Pleistocene Transition, have higher opal content, particle size, and porosity, which reduce the undrained shear strength. Cyclic weak-layer deposition, modulated at Milankovitch time scale, was controlled by increased ocean primary productivity and sedimentation rates linked to high-amplitude sea-level fluctuations and intensified winter monsoons. This study represents an important step forward for understanding how climate influences the formation of weak layers and the stability of continental slope globally. This work demonstrates for the first time that Milankovitch-scale sea level and climate oscillations drove the cyclic formation of weak layers by enhancing ocean primary productivity and sedimentation rates after the Middle Pleistocene Transition.

As a powerful in situ detection technique, Raman spectroscopy is becoming a popular underwater investigation method, especially in deep-sea research. In this paper, an easy-to-operate underwater Raman system with a compact design and competitive sensitivity is introduced. All the components, including the optical module and the electronic module, were packaged in an L362 × Φ172 mm titanium capsule with a weight of 20 kg in the air (about 12 kg in water). By optimising the laser coupling mode and focusing lens parameters, a competitive sensitivity was achieved with the detection limit of SO42− being 0.7 mmol/L. The first sea trial was carried out with the aid of a 3000 m grade remotely operated vehicle (ROV) “FCV3000” in October 2018. Over 20,000 spectra were captured from the targets interested, including methane hydrate, clamshell in the area of cold seep, and bacterial mats around a hydrothermal vent, with a maximum depth of 1038 m. A Raman peak at 2592 cm−1 was found in the methane hydrate spectra, which revealed the presence of hydrogen sulfide in the seeping gas. In addition, we also found sulfur in the bacterial mats, confirming the involvement of micro-organisms in the sulfur cycle in the hydrothermal field. It is expected that the system can be developed as a universal deep-sea survey and detection equipment in the near future.

Background Deep-sea mussels living in the cold seeps with enormous biomass act as the primary consumers. They are well adapted to the extreme environment where light is absent, and hydrogen sulfide, methane, and other hydrocarbon-rich fluid seepage occur. Despite previous studies on diversity, role, evolution, and symbiosis, the changing adaptation patterns during different developmental stages of the deep-sea mussels remain largely unknown. Results The deep-sea mussels ( Bathymodiolus platifrons ) of two developmental stages were collected from the cold seep during the ocean voyage. The gills, mantles, and adductor muscles of these mussels were used for the Illumina sequencing. A total of 135 Gb data were obtained, and subsequently, 46,376 unigenes were generated using de-novo assembly strategy. According to the gene expression analysis, amounts of genes were most actively expressed in the gills, especially genes involved in environmental information processing. Genes encoding Toll-like receptors and sulfate transporters were up-regulated in gills, indicating that the gill acts as both intermedium and protective screen in the deep-sea mussel. Lysosomal enzymes and solute carrier responsible for nutrients absorption were up-regulated in the older mussel, while genes related to toxin resistance and autophagy were up-regulated in the younger one, suggesting that the older mussel might be in a vigorous stage while the younger mussel was still paying efforts in survival and adaptation. Conclusions In general, our study suggested that the adaptation capacity might be formed gradually during the development of deep-sea mussels, in which the gill and the symbionts play essential roles.

Dissolved carbon (dissolved organic carbon and dissolved inorganic carbon) is the major component of the ocean carbon cycle, representing one of the largest carbon pools on Earth. Cold seeps and hydrothermal systems serve as the two main windows for the material and energy recycling exchange between the lithosphere and outer spheres (biosphere, hydrosphere and atmosphere). However, recent studies have found that the dynamic activities of fluids in these two extreme systems are a crucial source of ‘new’ carbon in the deep ocean. These carbon sources may become vital contributors to carbon and energy in marine ecosystems, which affect the global deep-sea carbon budget, and the marine ecosystems as well. In this review, we summarize the sources and formation mechanisms of dissolved carbon in the seep fluids from the cold seeps and hydrothermal vents, the contribution of methane oxidation to dissolved carbon, and the characteristics of the carbon isotope composition in the fluid. Furthermore, we analyze and discuss the influence of carbon discharged from seabed on the seawater carbon cycle by comparing and contrasting these two extreme environments. The research may assist in promoting a deeper understanding of the carbon cycle and material interaction in the ocean, particularly further carbon cycle research in the back-arc basin where cold seeps and hydrothermal vents commonly prevail.

Hilly and mountainous areas are important agricultural production regions globally. Their dramatic topography, dense fruit tree planting, and steep slopes severely restrict the application of traditional plant protection machinery. Pest and disease control has long relied on manual spraying, resulting in high labor intensity, low efficiency, and pesticide utilization rates of less than 30%. Plant protection UAVs, with their advantages of flexibility, high efficiency, and precise application, provide a feasible technical approach for plant protection operations in hilly and mountainous areas. However, steep slopes and dense orchard environments place higher demands on key technologies such as drone positioning and navigation, attitude control, trajectory planning, and terrain following. Achieving accurate identification and adaptive following of the undulating fruit tree canopy while maintaining a constant spraying distance to ensure uniform pesticide coverage has become a core technological bottleneck. This paper systematically reviews the key technologies and research progress of plant protection UAVs in hilly and mountainous operations, focusing on the principles, advantages, and limitations of core methods such as multi-sensor fusion positioning, intelligent SLAM navigation, nonlinear attitude control and intelligent control, three-dimensional trajectory planning, and multimodal terrain following. It also discusses the challenges currently faced by these technologies in practical applications. Finally, this paper discusses and envisions the future of plant protection UAVs in achieving intelligent, collaborative, and precise operations on steep slopes and in dense orchards, providing theoretical reference and technical support for promoting the mechanization and intelligentization of mountain agriculture.

The Okinawa Trough (OT) has been a focus of scientific research for many years due to the presence of vibrant hydrothermal and cold seep activity within its narrow basin. However, the spatial distribution and environmental drivers of microbial communities in OT sediments remain poorly understood. The present study aims to address this knowledge gap by investigating microbial diversity and abundance at ten different sampling sites in a transitional zone between hydrothermal vents and cold seeps in the OT. The microbial community at two sampling sites (G08 and G09) in close proximity to hydrothermal vents showed a high degree of similarity. However, lower bacterial and archaeal abundances were found in these sites. The archaeal groups, classified as Hydrothermarchaeota and Thermoplasmata, showed a comparatively higher relative abundance at these sites. In addition, ammonia-oxidizing archaea (AOA), from the family Nitrosopumilaceae, were found to have a higher relative abundance in the OT surface sediments at sampling sites G03, G04, G05, G06, and G07. This result suggests that ammonia oxidation may be actively occurring in these areas. Furthermore, Methylomirabilaceae, which are responsible for methane oxidation coupled with nitrite reduction, dominated three sampling sites (G07, G08, and G09), implying that N-DAMO may play an important role in mitigating methane emissions. Using the FAPROTAX database, we found that predicted prokaryotic microbial functional groups involved in methyl-reducing methanogenesis and hydrogenotrophic methanogenesis were most abundant at sites G08 and G09. At sampling sites G01 and G02, functional groups such as hydrocarbon degradation, methanotrophy, methanol oxidation, denitrification, sulfate respiration, and sulfur oxidation were more abundant. Nitrogen content is the most important environmental factor determining the bacterial and archaeal communities in the OT surface sediments. These results expand our knowledge of the spatial distribution of microbial communities in the transitional zone between hydrothermal vents and cold seeps in the OT.