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Alumina (Al 2 O 3 ) is believed to be the first major condensate to form in the gas outflow from oxygen-rich evolved stars because of the refractoriness and that α-Al 2 O 3 (corundum, most stable polymorph) is a potential origin of a 13 μm feature that appears close to stars. However, no one has directly reproduced the 13 μm feature experimentally, and it has remained as a noteworthy unidentified infrared band. Here, we report nucleation experiments on Al 2 O 3 nanoparticles monitored by a specially designed infrared spectrometer in the microgravity environment of a sounding rocket. The conditions approximate to those around asymptotic giant branch (AGB) stars. The measured spectra of the nucleated Al 2 O 3 show a sharp feature at a wavelength of 13.55 μm and comparable in width to that observed near oxygen-rich AGB stars. Our finding that α-Al 2 O 3 nucleates under certain condition provides a solid basis to elaborate condensation models of dust around oxygen-rich evolved stars. Alumina is thought to be the main condensate to form in the gas outflow from oxygen-rich evolved stars. Here, the authors perform a condensation experiment with alumina in a low-gravity environment, and find spectroscopic evidence for a sharp feature at a wavelength of 13.55 μm.

The Universe has never been seen like this before. The window into the infrared opens only above Earth's atmosphere, and humanity has barely glimpsed outside. About half of the light emitted by stars, planets, and galaxies over the lifetime of the Universe emerges in the infrared. With an unparalleled sensitivity increase — up to a factor of 1,000 more than any previous or planned mission — the advance offered by the Origins Space Telescope (OST) is akin to that from the naked eye to humanity's first telescope, or from Galileo's first telescope to the first telescope in space. While key path-finding missions have glimpsed a rich infrared cosmos, extraordinary discovery space awaits; the time for a far-infrared revolution has begun.Are we alone or is life common in the Universe? OST will directly address this long-standing question by searching for signs of life in the atmospheres of potentially habitable terrestrial planets transiting M dwarf stars. How do planets become habitable? OST will trace the trail of cold water from the interstellar medium, through protoplanetary disks and into the outer reaches of our own Solar System. How do stars, galaxies, black holes and the elements of life form, from the cosmic dawn to today? With broad wavelength coverage and fast mapping speeds, OST will map millions of galaxies, simultaneously measuring star formation rates and black hole growth across cosmic time, peering deeper into the far reaches of the Universe than ever before.OST will be maintained at a temperature of 4 K, enabling its tremendous sensitivity gain, and will operate from 5 m to 600 m, encompassing the mid- and far-infrared. OST has two Mission Concepts: Concept 1 with a 9.1-m deployed off-axis primary, and Concept 2, described here, a non-deployed 5.9-m on-axis telescope with the equivalent collecting area of the James Webb Space Telescope (JWST). Concept 2 includes four instruments with capabilities for imaging (large surveys and pointed), spectroscopy (survey and high-resolution modes) and polarimetry, as well as an instrument for high-precision spectroscopy of transiting exoplanets. Concept 2 is optimized for maximum science return and minimal complexity, and offers fast mapping (approximately 60 arcseconds per second). We describe here the three key science themes for OST and the basic mission specifications.

We have succeeded in synthesizing organics, ‘Quenched Nitrogen-included Carbonaceous Composite (QNCC)’, via plasma chemical vapor deposition (CVD) method, whose infrared spectral properties reproduce the characteristics of the unidentified infrared (UIR) bands observed around classical novae. Past studies have shown that the UIR bands observed around novae appear somewhat differently from those observed in other astrophysical environment and are predominantly characterized by the presence of a broad 8μm feature. The remarkable similarity between the infrared properties of QNCC and the UIR bands in novae indicates that QNCC should be considered as a strong candidate of the carriers of the UIR bands in novae. Finally, we have started a space exposure experiment of QNCC aiming to explore the evolutional link between the QNCC and the insoluble organic molecule (IOM) in carbonaceous condrite and, thus, to infer the origins of organics in our solar system.

The unidentified infrared (UIR) bands have been ubiquitously observed in various astrophysical environments and consist of a series of emission features arising from aromatic and/or aliphatic C-C and C-H bonds [1]. Therefore, their carriers are thought to be related to interstellar organics. However, our knowledge on the true carriers of the UIR bands is still limited. Recently [4] has proposed Mixed Aromatic Aliphatic Organic Nanoparticles, which contains hetero atoms in addition to conventional hydrocarbon models, as a more realistic interpretation of the band carriers. The challenges toward identifying the carriers of the UIR bands are still ongoing. Past studies have shown that the UIR bands observed around classical novae, which characterized by the presence of broad feature around 8μm[2], are somewhat different from those observed in other astrophysical environment. Here we report the success of experimentally synthesizing the organics called Nitrogen-included Carbonaceous Compounds (NCC; [7]) whose infrared properties can reproduce the UIR bands observed in classical novae.

The Infrared Camera (IRC) onboard AKARI has a near-infrared (2--5μm) spectroscopic capability with high sensitivity that allows us to study the major ice components in various objects. In particular, H2O and CO2 ice absorption features have been detected towards nearby galaxies, including several young stellar objects (YSOs) in the Large Magellanic Cloud (LMC), as well as a number of HII region-PDR complexes for the first time by IRC spectroscopy. While observations in the LMC show a high ratio (~0.34) of the CO2 to H2O ice column densities, the ratios in Galactic HII-region-PDR complexes are in the range of 0.1--0.2, being compatible with those found in Galactic massive YSOs in previous studies. The good correlation supports concurrent formation of the two ice species on the grain surface and the higher ratio in the low-metallicity LMC suggests possible environmental effects in the formation process.

Using the reconstructed imaging data obtained with the Infrared Camera (IRC) on board AKARI, mid-infrared (MIR; 5-30 μm) emission characteristics of the superwind galaxy M82 are studied. The MIR images at four wavelengths (7, 11, 15, and 24 μm) show extended (out to distances of 4 kpc) emission mainly from polycyclic aromatic hydrocarbons (PAHs). The MIR SED of M82 halo is surprisingly constant. Using far-infrared imaging data obtained by Herschel/SPIRE, we reveal that the PAH abundance relative to the big (sub-micron sized) grains radially increases by about a factor of three. These results imply that PAHs may be formed in small and dense molecular clumps in the halo and efficiently supplied to the intergalactic space by the galactic superwind.

With AKARI, we have performed a systematic study of interstellar dust grains in various environments of galaxies. In many cases, the IR emission of dust is an important tool to trace star-forming activities in galaxies. However it is much more than just star-formation tracers. AKARI has revealed the detailed properties of dust grains in regions not relevant to star formation as well, some of which are found not to follow our old empirical knowledge. Because of its unique capabilities, such as near- and far-IR spectroscopy, and all-sky coverage, AKARI has provided new knowledge on the processing of carbonaceous grains including polycyclic aromatic hydrocarbons. We present the latest results obtained from our AKARI observations of the ISM in our Galaxy and nearby galaxies.

We investigate the infrared emission bands from Polycyclic Aromatic Hydrocarbons (PAHs) in Galactic planetary nebulae (PNe). PAHs in PNe are assumed to be in transition from circumstellar to interstellar PAHs. We select 15 evolved PNe taking account of effective stellar temperatures and obtain infrared spectra of PNe from AKARI (2.5–5 μm) and Spitzer (5–14 μm) observations. Their evolutionary phase is estimated using [SIV]10.51/[NeII]12.81. We find that the near-infrared PAH bands are significantly enhanced along with stellar evolution sequence. We also find that the ratio of 3.4 to 3.3 μm bands is enhanced. The enhancement might indicate some chemical processing, such as hydrogenation, on small PAHs.

The unidentified infrared (UIR) emission bands in the near- to mid-infrared are thought to originate from organic compounds in the interstellar medium. Recent space observations with Spitzer and AKARI have clearly revealed that the UIR bands are commonly seen in external galaxies, including elliptical galaxies, except for very metal-poor dwarf galaxies. They are also detected in extended structures of galaxies, such as extra-planar components and filaments produced by outflows, suggesting that the band carriers are ubiquitous organic compounds in galaxies. Since the UIR bands are prominent features in the infrared spectrum of galaxies and are linked to the star-formation activity, it is highly important to understand the nature, formation, processing, and destruction of the UIR band carriers in galaxies. While there is no systematic variation detected in the UIR spectrum in normal galaxies, significantly low values are derived for the ratio of the 7.7 μm to 11.2 μm bands in elliptical galaxies as well as in galaxies with low-luminosity AGNs compared to normal star-forming galaxies. Relatively low band ratios are also seen in the UIR band spectrum of extended structures in galaxies. If the same mechanism leads to the low band ratio, it would provide important information on the band carrier properties. It should also be noted that the band carriers are believed to be destroyed in a short time scale in environments where low band ratios are detected. The survival and supply processes in these environments are a key to understand the nature of the band carriers.

We have observed 18 nearby dusty elliptical galaxies in the near- to far-infrared with Spitzer and AKARI. We have found that polycyclic aromatic hydrocarbons are present in 14 out of the 18 elliptical galaxies.