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Raman spectroscopy is one of the main analytical techniques used in optical metrology. It is a vibration, marker-free technique that provides insight into the structure and composition of tissues and cells at the molecular level. Raman spectroscopy is an outstanding material identification technique. It provides spatial information of vibrations from complex biological samples which renders it a very accurate tool for the analysis of highly complex plant tissues. Raman spectra can be used as a fingerprint tool for a very wide range of compounds. Raman spectroscopy enables all the polymers that build the cell walls of plants to be tracked simultaneously; it facilitates the analysis of both the molecular composition and the molecular structure of cell walls. Due to its high sensitivity to even minute structural changes, this method is used for comparative tests. The introduction of new and improved Raman techniques by scientists as well as the constant technological development of the apparatus has resulted in an increased importance of Raman spectroscopy in the discovery and defining of tissues and the processes taking place in them.

The present review covers reports discussing potential applications of the specificity of Raman techniques in the advancement of digital farming, in line with an assumption of yield maximisation with minimum environmental impact of agriculture. Raman is an optical spectroscopy method which can be used to perform immediate, label-free detection and quantification of key compounds without destroying the sample. The authors particularly focused on the reports discussing the use of Raman spectroscopy in monitoring the physiological status of plants, assessing crop maturity and quality, plant pathology and ripening, and identifying plant species and their varieties. In recent years, research reports have presented evidence confirming the effectiveness of Raman spectroscopy in identifying biotic and abiotic stresses in plants as well as in phenotyping and digital selection of plants in farming. Raman techniques used in precision agriculture can significantly improve capacities for farming management, crop quality assessment, as well as biological and chemical contaminant detection, thereby contributing to food safety as well as the productivity and profitability of agriculture. This review aims to increase the awareness of the growing potential of Raman spectroscopy in agriculture among plant breeders, geneticists, farmers and engineers.

Biochar can be regarded as a high-energy type of solid fuel produced via pyrolysis, which is the thermal modification of biomass of plant or animal origins. The biggest advantage of biomass relative to classic fossil fuels is the significant reduction in carbon dioxide emissions in the combustion process. Biochar is also considered a natural soil additive for improving soil parameters, increasing crop yields, remediating pollutants, and reducing emissions of methane, among other things. Over the past few years, the range of biochar applications has expanded significantly, as reflected in the number of scientific articles on the topic. Pyrolysates are used in the production of cosmetics, pharmaceuticals, building materials, animal feed, sorbents, and water filters, as well as in the field of modern energy storage and conversion, such as supercapacitors. The key importance of this material is attributed to its ability to sequestrate carbon and reduce greenhouse gas emissions. The relentless growth of the global economy and the high demand for energy generate large amounts of CO2 in the atmosphere. Solving the carbon balance problem and the low-carbon energy transition toward carbon neutrality is very challenging. Biochar therefore appears to be an excellent tool for creating systems that can play an important role in mitigating climate change. The purpose of this review is to consolidate the existing knowledge and assess the potential of biochar in carbon neutrality based on the application sector.

This review analyzes in detail the topic of supercapacitors based on biochar technologies, including their advantages, disadvantages, and development potential. The main topic is the formation of precursors in the process of pyrolysis and activation, and the possibility of the application of biochar itself in various fields is brought closer. The structure, division, and principle of operation of supercondensates are discussed, where their good and bad sides are pointed out. The current state of the scientific and legal knowledge on the topic of biocarbon and its applications is verified, and the results of many authors are compared to examine the current level of the research on supercapacitors based on biochar electrodes created from lignocellulosic biomass. Current application sites for supercapacitors in transportation, electronics, and power generation (conventional and unconventional) are also examined, as is the potential for further development of the technology under discussion.

The purpose of this paper is to review the scientific results and summarise the emerging topic of the effects of statistic magnetic field on the structure, biochemical activity, and gene expression of plants. The literature on the subject reports a wide range of possibilities regarding the use of the magnetic field to modify the properties of plant cells. MFs have a significant impact on the photosynthesis efficiency of the biomass and vigour accumulation indexes. Treating plants with SMFs accelerates the formation and accumulation of reactive oxygen species. At the same time, the influence of MFs causes the high activity of antioxidant enzymes, which reduces oxidative stress. SMFs have a strong influence on the shape of the cell and the structure of the cell membrane, thus increasing their permeability and influencing the various activities of the metabolic pathways. The use of magnetic treatments on plants causes a higher content of proteins, carbohydrates, soluble and reducing sugars, and in some cases, lipids and fatty acid composition and influences the uptake of macro- and microelements and different levels of gene expression. In this study, the effect of MFs was considered as a combination of MF intensity and time exposure, for different varieties and plant species. The following article shows the wide-ranging possibilities of applying magnetic fields to the dynamics of changes in the life processes and structures of plants. Thus far, the magnetic field is not widely used in agricultural practice. The current knowledge about the influence of MFs on plant cells is still insufficient. It is, therefore, necessary to carry out detailed research for a more in-depth understanding of the possibilities of modifying the properties of plant cells and achieving the desired effects by means of a magnetic field.

Biochar from forest biomass and its remains has become an essential material for environmental engineering, and is used in the environment to restore or improve soil function and its fertility, where it changes the chemical, physical and biological processes. The article presents the research results on the opportunity to use the pyrolysis process to receive multifunctional biochar materials from oak biomass. It was found that biochars obtained from oak biomass at 450 and 500 °C for 10 min were rich in macronutrients. The greatest variety of the examined elements was characterized by oak-leaf pyrolysate, and high levels of Ca, Fe, K, Mg, P, S, Na were noticed. Pyrolysates from acorns were high in Fe, K, P and S. Oak bark biochars were rich in Ca, Fe, S and contained nitrogen. In addition, biomass pyrolysis has been found to improve energy parameters and does not increase the dust explosion hazard class. The oak biomass pyrolytic at 450 and 500 °C after 10 min increases its caloric content for all samples tested by at least 50%. The highest caloric value among the raw biomass tested was observed in oak bark: 19.93 MJ kg−1 and oak branches: 19.23 MJ kg−1. The mean and highest recorded Kstmax were 94.75 and 94.85 bar s−1, respectively. It can be concluded that pyrolysis has the potential to add value to regionally available oak biomass. The results described in this work provide a basis for subsequent, detailed research to obtain desired knowledge about the selection of the composition, purpose, and safety rules of production, storage, transport and use of biochar materials.

We assess the possibility of using biochar and ash from plant biomass to fertilise giant miscanthus (Miscanthus x giganteus). The paper concerns the optimisation of the combination of fertiliser applications of the aforementioned materials in the context of the plant yield obtained. There was an increase in yield of 8–68% over the two years of research when compared with the control plots. It was found that the application of biochar, ash from biomass and a combination of the two at appropriate rates as a soil additive can substitute for classic mineral fertilisers and strengthen the ecological aspects of energy crop cultivation. The interpretation of the results obtained enabled the selection of optimum fertiliser applications, resulting in a significant increase in the yield of plants and an improvement in soil chemical properties. It was found that the highest yield of dry matter of giant miscanthus plants, after both the first and second year of cultivation, was obtained by applying the fertiliser containing ash at a rate of 1.5 t ha−1, together with biocarbon and the combination of biochar and ash at a rate of 1.5 t ha−1.

The growing demand for electricity, caused by dynamic economic growth, leads to a decrease in the available non-renewable energy resources constituting the foundation of global power generation. A search for alternative sources of energy that can support conventional energy technologies utilizing fossil fuels is not only of key significance for the power industry but is also important from the point of view of environmental conservation and sustainable development. Plant biomass, with its specific chemical structure and high calorific value, is a promising renewable source of energy which can be utilized in numerous conversion processes, enabling the production of solid, liquid, and gaseous fuels. Methods of thermal biomass conversion include pyrolysis, i.e., a process allowing one to obtain a multifunctional product known as biochar. The article presents a review of information related to the broad uses of carbonization products. It also discusses the legal aspects and quality standards applicable to these materials. The paper draws attention to the lack of uniform legal and quality conditions, which would allow for a much better use of biochar. The review also aims to highlight the high potential for a use of biochar in different environments. The presented text attempts to emphasize the importance of biochar as an alternative to classic products used for energy, environmental and agricultural purposes.

Biomass is one of the most important sources of renewable energy. It is expected that in the coming decades, biomass will play a major role in replacing fossil fuels. The most commonly used biofuels include wood pellet, which is a cost-effective, uniform and easy-to-use material. In view of the growing interest in this type of resource, novel methods are being investigated to improve the quality of pellet. This article presents the results of a laboratory study focusing on wood pellets refined with waste sunflower cooking oil applied by spraying. In this work, authors attempted to modify the energy parameters of wood pellets with the use of waste cooking oil. Addition of waste cooking oil, applied at the rates of 2%, 4%, 6%, 8%, 10% and 12% relative to the weight of pellets, increased the calorific value of the pellets without decreasing their durability. The highest dose of the modifier (12%) on average led to a 12–16% increase in calorific value. In each case, the addition of sunflower oil resulted in decreased contents of ash in the pellets; on average a decrease of 16–38% was observed in the samples treated with the highest dose of the modifier. The treatment led to a higher content of elements affecting the heating value, i.e., carbon and hydrogen, which on average increased by 7.5–12%, and 7.0–10.0%, respectively. The presented method seems to be a promising way of increasing the calorific value of pellets. Further research on refining the method and the possibility of using it in industry is necessary.

The article discusses the findings related to the calorific value as well as the explosion and combustion parameters of dust from the raw biomass of fruit trees, i.e., apple, cherry, and pear branches, and from biochars produced using this type of biomass during pyrolysis processes conducted under various conditions. The plant biomass was thermally processed at 400, 450, or 500 °C for a duration of 5, 10, or 15 min. The study aimed to identify the calorific value of the biomass obtained from waste produced in orchards and to estimate the explosion hazard during the processing of such materials and during the storage of the resulting solid fuels. Tests were conducted to assess the total contents of carbon, ash, nitrogen, hydrogen, and volatile substances as well as the calorific value. The findings show a significant effect of the thermal transformation of fruit tree branches on the calorific value of the biochars that were produced. It was found that the mean calorific value of all of the biochars was increased by 62.24% compared to the non-processed biomass. More specifically, the mean calorific values of the biochars produced from apple, cherry, and pear branches amounted to 27.90, 28.75, and 26.84 MJ kg−1, respectively. The maximum explosion pressure Pmax measured for the dust from the biomass and for the biochars was in the range 7.56–7.8 and 7.95–11.72 bar, respectively. The maximum rate of pressure rose over time (dp/dt)max in the case of the dust from the biomass, which was in the range of 274.77–284.97 bar s−1, and the dust from biochar amounted to 282.05–353.41 bar s−1. The explosion index Kst max measured for non-processed biomass and biochars was found to range from 74.46 to 77.23 and from 76.447 to 95.77 bar s−1, respectively. It was also shown that a change in the temperature and duration of the pyrolysis process affected the quality of the biochars that were obtained. The findings show that pyrolysis, as a method of plant biomass processing, positively affects the calorific value of the products and does not lead to an increased risk of explosion during the treatment and storage of such materials. It is necessary, however, to continue research on biomass processing in order to develop practices that adequately ensure safety during the production of novel fuels.