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This study investigates the efficacy of adsorbents from locally sourced olive waste—encompassing olive skins, leaves, and pits, recovered from the initial centrifugation of olives (OWP)—and a composite with sodium alginate (OWPSA) for the removal of Cu2+ ions from synthetic wastewater. Experimental analyses conducted at room temperature, with an initial Cu2+ concentration of 50 mg/L and a solid/liquid ratio of 1 g/L, showed that the removal efficiencies were approximately 79.54% and 94.54% for OWP and OWPSA, respectively, highlighting the positive impact of alginate on adsorption capacity. Utilizing statistical physics isotherm models, particularly the single-layer model coupled to real gas (SLMRG), allowed us to robustly fit the experimental data, providing insights into the adsorption mechanisms. Thermodynamic parameters affirmed the spontaneity and endothermic nature of the processes. Adsorption kinetics were interpreted effectively using the pseudo-second-order (PSO) model. Molecular modeling investigations, including the conductor-like screening model for real solvents (COSMO-RS), density functional theory (DFT), and atom-in-molecule (AIM) analysis, unveiled intricate molecular interactions among the adsorbent components—cellulose, hemicellulose, lignin, and alginate—and the pollutant Cu2+, confirming their physically interactive nature. These findings emphasize the synergistic application of experimental and theoretical approaches, providing a comprehensive understanding of copper adsorption dynamics at the molecular level. This methodology holds promise for unraveling intricate processes across various adsorbent materials in wastewater treatment applications.

Water conservation is a critical issue, particularly in arid countries and countries that suffer a lack of natural water resources. Jordan is one of the most water-scarce countries in the world; this fact has forced the search for alternative sustainable solutions. With the support of several regional and international organizations, tens of projects were implemented across the country over the past 30 years that aimed to reuse greywater in rural communities. The current review provides a wide overview of Jordan's experience in greywater treatment and its reuse for non-potable purposes in rural areas. To the best knowledge of the authors, the present review is the first to assess the Jordanian experience in this field. Many governmental authorities and non-governmental organizations have been involved in Jordan's experience. The greywater reuse systems were established to achieve advantageous environmental and socio-economic consequences on the rural communities. The strategy of greywater treatment was based on a local on-site greywater treatment system in households or the so-called ‘autonomous water management’. The applied greywater treatment technologies in households were found efficient in rendering greywater adequate for agricultural uses. However, further improvements and territorial expansion of the experiment are needed.

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Developing efficient and durable oxygen evolution reaction (OER) catalysts holds great promise for green hydrogen production via seawater electrolysis, but remains a challenge. Herein, we report a Co-doped Ni 3 S 2 nanosheet array on Ni foam (Co-Ni 3 S 2 /NF) as a high-efficiency OER electrocatalyst for seawater. In alkaline conditions, Co-Ni 3 S 2 /NF requires an overpotential of only 368 mV to drive 100 mA·cm −2 , superior to Ni 3 S 2 /NF (385 mV). Besides, it exhibits at least 50-h continuous electrolysis.

In this study, a new eco-friendly kaolinite–cellulose (Kaol/Cel) composite was prepared from waste red bean peels (Phaseolus vulgaris) as a source of cellulose to serve as a promising and effective adsorbent for the removal of crystal violet (CV) dye from aqueous solutions. Its characteristics were investigated through the use of X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and zero-point of charge (pHpzc). The Box–Behnken design was used to improve CV adsorption on the composite by testing its primary affecting factors: loading Cel into the composite matrix of Kaol (A: 0–50%), adsorbent dosage (B: 0.02–0.05 g), pH (C: 4–10), temperature (D: 30–60 °C), and duration (E: 5–60 min). The significant interactions with the greatest CV elimination efficiency (99.86%) are as follows: BC (adsorbent dose vs. pH) and BD (adsorbent dose vs. temperature) at optimum parameters (A: 25%, B: 0.05 g, C: 10, D: 45 °C, and E: 17.5 min) for which the CV’s best adsorption capacity (294.12 mg/g) was recorded. The Freundlich and pseudo-second-order kinetic models were the best isotherm and kinetic models fitting our results. Furthermore, the study investigated the mechanisms responsible for eliminating CV by utilizing Kaol/Cel–25. It detected multiple types of associations, including electrostatic, n-π, dipole–dipole, hydrogen bonding interactions, and Yoshida hydrogen bonding. These findings suggest that Kaol/Cel could be a promising starting material for developing a highly efficient adsorbent that can remove cationic dyes from aqueous environments.

This study investigates the efficacy of adsorbents from locally sourced olive waste—encompassing olive skins, leaves, and pits, recovered from the initial centrifugation of olives (OWP)—and a composite with sodium alginate (OWPSA) for the removal of Cu[sup.2+] ions from synthetic wastewater. Experimental analyses conducted at room temperature, with an initial Cu[sup.2+] concentration of 50 mg/L and a solid/liquid ratio of 1 g/L, showed that the removal efficiencies were approximately 79.54% and 94.54% for OWP and OWPSA, respectively, highlighting the positive impact of alginate on adsorption capacity. Utilizing statistical physics isotherm models, particularly the single-layer model coupled to real gas (SLMRG), allowed us to robustly fit the experimental data, providing insights into the adsorption mechanisms. Thermodynamic parameters affirmed the spontaneity and endothermic nature of the processes. Adsorption kinetics were interpreted effectively using the pseudo-second-order (PSO) model. Molecular modeling investigations, including the conductor-like screening model for real solvents (COSMO-RS), density functional theory (DFT), and atom-in-molecule (AIM) analysis, unveiled intricate molecular interactions among the adsorbent components—cellulose, hemicellulose, lignin, and alginate—and the pollutant Cu[sup.2+], confirming their physically interactive nature. These findings emphasize the synergistic application of experimental and theoretical approaches, providing a comprehensive understanding of copper adsorption dynamics at the molecular level. This methodology holds promise for unraveling intricate processes across various adsorbent materials in wastewater treatment applications.

In the original publication [...].

This study investigates the efficacy of adsorbents from locally sourced olive waste-encompassing olive skins, leaves, and pits, recovered from the initial centrifugation of olives (OWP)-and a composite with sodium alginate (OWPSA) for the removal of Cu ions from synthetic wastewater. Experimental analyses conducted at room temperature, with an initial Cu concentration of 50 mg/L and a solid/liquid ratio of 1 g/L, showed that the removal efficiencies were approximately 79.54% and 94.54% for OWP and OWPSA, respectively, highlighting the positive impact of alginate on adsorption capacity. Utilizing statistical physics isotherm models, particularly the single-layer model coupled to real gas (SLMRG), allowed us to robustly fit the experimental data, providing insights into the adsorption mechanisms. Thermodynamic parameters affirmed the spontaneity and endothermic nature of the processes. Adsorption kinetics were interpreted effectively using the pseudo-second-order (PSO) model. Molecular modeling investigations, including the conductor-like screening model for real solvents (COSMO-RS), density functional theory (DFT), and atom-in-molecule (AIM) analysis, unveiled intricate molecular interactions among the adsorbent components-cellulose, hemicellulose, lignin, and alginate-and the pollutant Cu , confirming their physically interactive nature. These findings emphasize the synergistic application of experimental and theoretical approaches, providing a comprehensive understanding of copper adsorption dynamics at the molecular level. This methodology holds promise for unraveling intricate processes across various adsorbent materials in wastewater treatment applications.