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A detailed description of alkali water springs (pH > 10) found within the ultrabasic massif of Mount Soldatskaya in the Kamchatsky Mys Peninsula in Kamchatka is presented for the first time. The chemical composition of the springs and the dependence of the ratios and concentrations of some components on pH are indicative of the fact that these waters were involved in the present-day serpentinization of ultrabasic rocks. The springs with the highest alkali levels (pH 12.3) contain dissolved hydrogen at a concentration of about 0.6 mmol/l. The isotopic composition behavior of carbonate travertines deposited from these springs (δ 13 C and δ 18 O) differs from the known trend of “meteogenic” travertines related to serpentinization of ultrabasic rocks in Oman and California. The age of travertines determined by the radiocarbon method is close to modern.

Abstract—2720 cosmic spherules extracted from ferromanganese crusts sampled at two guyots of the Magellan Seamounts were studied using a scanning electron microscope. In comparison with collections of modern cosmic spherules, our samples are significantly richer in I-type spherules (consisting of Fe oxides, often with a Fe–Ni metal core). The compositions of 406 metal cores were analyzed. Six spherules with cores significantly enriched in Co (>5 wt %) were found; these were the first spherules of this composition ever found worldwide. Such a high Co content in the cores cannot be explained by the evolution of a micrometeorite of chondrite composition at its melting. Some groups of the spherules have either elevated or lower Co concentrations than those expected according to the evolutionary trend of spherules at oxidation during the atmosphere entry. These groups apparently reflect the composition of the initial micrometeorites. It is proposed to use the composition of the cores of cosmic spherules to reveal the time variation in the composition of cosmic dust entering the Earth. Several spherules were found with small cores compared to the oxide shell; these cores are characterized by the presence of a significant amount of platinum group elements (PGE) (up to 2.4 wt % PGE). The averaged composition of PGE in the high-Ni core, which is the richest in PGE, shows a pattern close to that of chondrite. The collection contains 23 spherules that host PGE nuggets. In three spherules, micrometer-sized nuggets with various PGE were found (one nugget is Os + Ir + Ru, and two others contain all PGE). In 20 spherules, nanometer-sized nuggets of rhodium platinum were found. The largest nugget (3 μm) has PGE ratios close to chondritic, with the exception of a significant depletion in Pd.

AbstractMore than 250 magnetic spherules 40–200 µm in size were mechanically separated from a ferromanganese crust sample of Fedorov Guyot in the Magellan Seamounts. The composition of the spherules corresponds to stony-iron and iron (with a nickel admixture) meteorites oxidized to varying degrees. The surface morphology and the internal texture of these spherules are similar to modern micrometeorites. Some spherules have a zonal structure with a core consisting of unoxidized nickel iron, with a nickel content of 7.5%–53% and a cobalt admixture up to 3.7%. Microinclusions (up to 0.5 μm) of rhodium platinum were found for the first time in a spherule consisting of wüstite and magnetite in the ferromanganese crust. The presence of cosmogenic spherules in the sample studied indicates the accumulation of a certain fraction of platinoids in the ferromanganese crusts due to the burial of cosmic dust in them.

Abstract—New U‒Pb (LA-ICP-MS) geochronological data have been obtained on accessory zircons from granodiorites and on detrital zircons from stream-sediment samples from the Shipunsky massif in the Eastern Kamchatka region. The age of accessory zircons from amphibole–biotite granodiorites has been estimated at 49–44 Ma. Detrital zircons have the Late Paleocene–Early Eocene age from ~57 to ~49 Ma. Based on the geological and geochronological data, the massif was formed in two stages: a gabbroid intrusion (56‒51 Ma) and the quartz diorite-granodiorite intrusion (49‒44 Ma). In terms of the petrographic and geochemical characteristics of the Upper Cretaceous–Eocene volcanic rocks in the Shipunsky Peninsula and granitoids in the Shipunsky massif, they were formed in the suprasubduction setting. The Shipunsky granitoids belong to the I-type granites. The Shipunsky massif was formed as a part of the Kronotsky intraoceanic paleoarc during the Paleocene–Eocene in two stages. The southern segment of the Kronotsky paleoarc collided with the Kamchatka continental margin and the deformed rocks of this massif were brought to the surface.

An Erratum to this paper has been published:

An Erratum to this paper has been published: https://doi.org/10.1134/S1028334X23070097

A detailed description of alkali water springs (pH > 10) found within the ultrabasic massif of Mount Soldatskaya in the Kamchatsky Mys Peninsula in Kamchatka is presented for the first time. The chemical composition of the springs and the dependence of the ratios and concentrations of some components on pH are indicative of the fact that these waters were involved in the present-day serpentinization of ultrabasic rocks. The springs with the highest alkali levels (pH 12.3) contain dissolved hydrogen at a concentration of about 0.6 mmol/l. The isotopic composition behavior of carbonate travertines deposited from these springs ([delta].sup.13C and [delta].sup.18O) differs from the known trend of \"meteogenic\" travertines related to serpentinization of ultrabasic rocks in Oman and California. The age of travertines determined by the radiocarbon method is close to modern.

The zone of serpentinite melange in the Kamchatsky Mys Peninsula was found to contain high-magnesium ultramafic volcanic rocks, viz., plagioclase picrite (oceanite) with a MgO concentration of 22.5–25.8%. We evaluated the petrochemical and geochemical characteristics of these rocks, as well as their mineral compositions. The olivine phenocrysts make up 50–60% of the rock volume; their composition (mostly 87–89 mol % Fo) and the composition of melt inclusions in them indicate their origin from a picritic melt with an additional cumulative enrichment in olivine. The geochemical parameters (Zr/Y = 3.1, Th/Yb = 0.14–0.18, Nb/Yb = 2.39–2.66, La (N) /Sm (N) = 1.0–1.1, La (N) /Yb (N) = 1.24–1.42) indicate an oceanic genesis of these rocks affected by a mantle plume.

The eastern peninsulas of Kamchatka are mostly composed of tectonostratigraphic complexes, which were formed within the Late Cretaceous-Eocene Kronotskii-Kamchatka arc. The accretion of this paleoarc to the Kamchatka margin of northeastern Asia in the terminal Cenozoic represented the last collisional event in the formation of the present-day structure of Kamchatka. The article presents new data on the age, composition, and structure of the tectonostratigraphic complexes constituting the southern segment of the Kronotskii-Kamchatka paleoarc. It is shown that the oldest rocks of these complexes are the Campanian in age and represented by volcano-sedimentary rocks that were formed in different geodynamic environments. The investigated igneous rocks are attributed to two types: (1) the tholeiite series of a mid-oceanic ridge (MOR) (Vetlovaya Complex); (2) tholeiite and calc-alkaline series of island arcs (Shipunskii Sequence of the Kronotskii Group).

An Erratum to this paper has been published: https://doi.org/10.1134/S1028334X23070097