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This paper proposes a single-stage three-phase modular flyback differential inverter (MFBDI) for medium/high power solar PV grid-integrated applications. The proposed inverter structure consists of parallel modules of flyback DC-DC converters based on the required power level. The MFBDI offers many features for renewable energy applications, such as reduced components, single-stage power processing, high-power density, voltage-boosting property, improved footprint, flexibility with modular extension capability, and galvanic isolation. The proposed inverter has been modelled, designed, and scaled up to the required application rating. A new mathematical model of the proposed MFBDI is presented and analyzed with a time-varying duty-cycle, wide-range of frequency variation, and power balancing in order to display its grid current harmonic orders for grid-tied applications. In addition, an LPF-based harmonic compensation strategy is used for second-order harmonic component (SOHC) compensation. With the help of the compensation technique, the grid current THD is reduced from 36% to 4.6% by diminishing the SOHC from 51% to 0.8%. Moreover, the SOHC compensation technique eliminates third-order harmonic components from the DC input current. In addition, a 15% parameters mismatch has been applied between the flyback parallel modules to confirm the modular operation of the proposed MFBDI under modules divergence. In addition, SiC MOSFETs are used for inverter switches implementation, which decrease the inverter switching losses at high-switching frequency. The proposed MFBDI is verified by using three flyback parallel modules/phase using PSIM/Simulink software, with a rating of 5 kW, 200 V, and 50 kHz switching frequency, as well as experimental environments.

This paper proposes a simple single-phase new pulse-width modulated seven-level inverter architecture for photovoltaic (PV) systems supporting home-grid with electric vehicle (EV) charging port. The proposed inverter includes a reduced number of power components and passive elements size, while showing less output-voltage total harmonic distortion (THD), and unity power factor operation. In addition, the proposed inverter requires simple control and switching strategies compared to recently published topologies. A comparative study was performed to compare the proposed inverter structure with the recent inverter topologies based on the number of components in the inverter circuit, number of components per output-voltage level, average number of active switches, THD, and operating efficiency as effective parameters for inverter performance evaluation. For design and validation purposes, numerical and analytical models for a grid-tied solar PV system driven by the proposed seven-level inverter were developed in MATLAB/Simulink environment. The inverter performance was evaluated considering grid-integration and stand-alone home with level-2 AC EV charger (3–6 kW). Compared with recently published topologies, the proposed inverter utilizes a reduced number of power components (7 switches) for seven-level terminal voltage synthesis. An experimental prototype for proposed inverter with the associated controller was built and tested for a stand-alone and grid-integrated system. Due to the lower number of ON-switches, the inverter operating efficiency was enhanced to 92.86% with load current THD of 3.43% that follows the IEEE standards for DER applications.

This paper proposes a three-phase isolated flyback inverter (IFBI) for single-stage grid-tied solar PV applications, considering a simple sinusoidal pulse-width modulation (SPWM) scheme. The proposed single-stage inverter employs a reduced passive elements count by considering three input-parallel output-differential (IPOD) flyback converter modules. Additionally, a single small size LC-input low-pass filter is utilized at the input paralleling point for ripple-free input current operation, which is essential in grid-connected renewable energy applications. In addition, a mathematical model of the IFBI is presented to confirm the existence of its low-order harmonic components. A simple PI controller-based control scheme, considering only two loops and five sensors, is used to control the proposed grid-tied IFBI. Continuous modulation scheme (CMS) combined with SPWM is used to diminish the low-frequency harmonic components. Moreover, a simple selective harmonic elimination (SHE) loop is used for second-order harmonic components (SOHC) elimination from grid-injected currents. The SHE has decreased the SOHC from 43% to 0.96%, which improves the grid current THD from 39% to 3.65%, to follow the IEEE harmonic standard limits. Additionally, the harmonic elimination technique decreases the circulating power between the inverter paralleled modules, which enhances the grid currents power factor. The proposed inverter is verified through a grid-connected 200 V, 1.6 kW, 60 Hz experimental prototype, and the switching frequency is 50 kHz. TMS-based DSP controller is used to control the grid-injected power to follow the reference power set-point.

Mesoporous α–Fe 2 O 3 has been synthesized via a simple sol-gel procedure in the presence of Pluronic (F-127) triblock copolymer as structure directing agent. Silver (Ag) nanoparticles were deposited onto α–Fe 2 O 3 matrix by the photochemical reduction approach. Morphological analysis revealed the formation of Ag nanoparticles with small sizes < 20 nm onto the mesoporous structure of α–Fe 2 O 3 possessing < 50 nm semi-spherical shape. The XRD, FTIR, Raman, UV-vis, PL, and N 2 sorption isotherm studies confirmed the high crystallinity, mesoporosity, and optical characteristics of the synthesized product. The electrochemical sensing toward liquid ethanol has been performed using the current devolved Ag/α–Fe 2 O 3 -modified glassy carbon electrode (GCE) by cyclic voltammetry ( CV ) and current potential ( I-V ) techniques, and the obtained results were compared with bare GCE or pure α–Fe 2 O 3 . Mesoporous Ag/α–Fe 2 O 3 was found to largely enhance the sensor sensitivity and it exhibited excellent sensing characteristics during the precision detection of low concentrations of ethanol. High and reproducible sensitivity of 41.27 μAmM − 1  cm − 2 at lower ethanol concentration region (0.05 to 0.8 mM) and 2.93 μAmM − 1  cm − 2 at higher concentration zone (0.8 to 15 mM), with a limit of detection (LOD) of 15.4 μM have been achieved. Investigation on reaction kinetics revealed a characteristic behavior of mixed surface and diffusion-controlled processes. Detailed sensing studies revealed also that the sensitivity toward ethanol was higher than that of methanol or isopropanol. With further effort in developing the synthesis and fabrication approaches, a proper utility for the current proposed protocol for fabricating a better sensor device performance is possible.

The design of open irrigation channels typically includes a bed slope to achieve the desired hydraulic performance, governing key parameters such as velocity, water depth, and discharge. Diversion head structures, often constructed across these channels, raise upstream water levels, generating potential energy that converts into high-velocity kinetic energy downstream Previous research has studied the type and configuration of water energy dissipaters, considering most hydraulic parameters affecting their performance, except for canal bed slope. The current work aims to explore the extent to which canal bed slope affects the performance efficiency of water energy dissipaters behind head structures, ensuring their safety. The experiments utilized a tilting flume under controlled conditions at six different bed slopes (0.05% to 0.30%) in addition to a zero bed slope, with five discharge values ranging from 9.76 to 17.14 L/s. Through 150 experimental runs, all hydraulic parameters affecting the performance efficiency of the water energy dissipater (relative energy loss, hydraulic jump, sequent depth ratio, and jump length) are measured and recorded. The results clearly show that increasing the canal bed slope to 0.20% enhances the water energy dissipater’s performance efficiency by 31.9%, reduces the jump length by 20% and lowers the sequent depth ratio ( y 2 y 1 ) by 20%. The recommended relative dissipater location ( L b b ) of 5.83 is accurate for canals with slopes up to 0.20% but for steeper slopes, this ratio must be checked.

The Wadi Ranga sulfidic jasperoids in the Southern Eastern Desert (SED) of Egypt are hosted within the Neoproterozoic Shadli metavolcanics as an important juvenile crustal section of the Arabian Nubian Shield (ANS). This study deals with remote sensing and geochemical data to understand the mechanism and source of pyritization, silicification, and hematization in the host metavolcanics and to shed light on the genesis of their jasperoids. The host rocks are mainly dacitic to rhyolitic metatuffs, which are proximal to volcanic vents. They show peraluminous calc-alkaline affinity. These felsic metatuffs also exhibit a nearly flat REE pattern with slight LREE enrichment (La/Yb = 1.19–1.25) that has a nearly negative Eu anomaly (Eu/Eu* = 0.708–0.776), while their spider patterns display enrichment in Ba, K, and Pb and depletion in Nb, Ta, P, and Ti, reflecting the role of slab-derived fluid metasomatism during their formation in the island arc setting. The ratios of La/Yb (1.19–1.25) and La/Gd (1.0–1.17) of the studied felsic metatuffs are similar to those of the primitive mantle, suggesting their generation from fractionated melts that were derived from a depleted mantle source. Their Nb and Ti negative anomalies, along with the positive anomalies at Pb, K, Rb, and Ba, are attributed to the influence of fluids/melt derived from the subducted slab. The Wadi Ranga jasperoids are mainly composed of SiO2 (89.73–90.35 wt.%) and show wide ranges of Fe2O3t (2.73–6.63 wt.%) attributed to the significant amount of pyrite (up to 10 vol.%), hematite, goethite, and magnetite. They are also rich in some base metals (Cu + Pb + Zn = 58.32–240.68 ppm), leading to sulfidic jasperoids. Pyrite crystals with a minor concentration of Ag (up to 0.32 wt.%) are partially to completely converted to secondary hematite and goethite, giving the red ochre and forming hematization. Euhedral cubic pyrite is of magmatic origin and was formed in the early stages and accumulated in jasperoid by epigenetic Si-rich magmatic-derived hydrothermal fluids; pyritization is considered a magmatic–hydrothermal stage, followed by silicification and then hematization as post-magmatic stages. The euhedral apatite crystals in jasperoid are used to estimate the saturation temperature of their crystallization from the melt at about 850 °C. The chondrite (C1)-normalized REE pattern of the jasperoids shows slightly U–shaped patterns with a slightly negative Eu anomaly (Eu/Eu* = 0.43–0.98) due to slab-derived fluid metasomatism during their origin; these jasperoids are also rich in LILEs (e.g., K, Pb, and Sr) and depleted in HFSEs (e.g., Nb and Ta), reflecting their hydrothermal origin in the island arc tectonic setting. The source of silica in the studied jasperoids is likely derived from the felsic dyke and a nearby volcanic vent, where the resultant Si-rich fluids may circulate along the NW–SE, NE–SW, and E–W major faults and shear zones in the surrounding metavolcanics to leach Fe, S, and Si to form hydrothermal jasperoid lenses and veins.

Keratomycosis, a sight-threatening fungal infection of the cornea, can be more effectively treated with a novel combination of Natamycin (NAT, 5%) and Fluconazole (FLC, 0.2%) than with NAT alone. To support the development of this therapy, new sustainable, eco-friendly, and sensitive analytical methods were developed for the simultaneous quantification of both drugs in pharmaceutical formulations. Two techniques were successfully employed. The first was a Reversed-Phase High-Performance Liquid Chromatography (RP-HPLC) method using an isocratic mobile phase of methanol and water (70:30%v/v) at a 1 mL/min flow rate. Detection was accomplished with both diode array (DAD) and fluorescence (FLD) detectors. The second technique was a Capillary Zone Electrophoresis (CZE) method utilizing a capillary (56 cm effective length, 50 μm internal diameter) at ambient temperature. Samples were injected hydrodynamically at 50 mbar pressure. The environmental sustainability and practical applicability of these methods were rigorously evaluated using modern assessment tools: the Greenness, Whiteness, and Blueness approaches. Furthermore, their innovative character was formally quantified using a novel metric, the Violet Innovation Grade Index (VIGI).

Background Tigecycline (TIG), an antimicrobial agent indicated for complex bacterial infections, is now approved by FDA as an orphan chemotherapeutic agent for the treatment of acute myeloid leukemia due to its inhibitory effects on pathways of activating, signaling and abnormal mitochondrial function in cancer cells. TIG is mainly administered as intravenous infusion through centralized unit of oncology centers. This necessitates the continuous analytical quality control of the prepared solution in order to identify and quantify TIG for safe intravenous administration to patients. Moreover, the clinical staff exposure risk to toxic drugs during daily handling must be considered. Such concerns require a fast, cost-effective and green analytical procedure for sensitive determination of TIG directly in infusion bags. In this work, we propose a simple, rapid and green capillary zone electrophoretic (CZE) method for the sensitive assay of TIG directly in infusion bags, in addition to three simple and green spectrophotometric methods. Results TIG solutions corresponding to clinical ranges were detected in 5%glucose. Validation of all the proposed methods was according to ICH guidelines. Greenness assessment was performed depending on Green Analytical Procedure Index (GAPI) and the Eco-scale approach which showed that the proposed methods are better eco-friendly methods than reported ones. It also revealed the superiority of our proposed methods in terms of simplicity and sensitivity for TIG determination in infusion bags. Quantification limits obtained were significantly lower than the administered range of TIG in infusion bags and lower than its maximum serum concentration ( C max ). This promotes the application of the proposed methods for the pharmacokinetics and bioavailability studies of TIG in various biological fluids. Conclusions This work reports, for the first time, CZE method for the direct and rapid determination of TIG and its separation from other components in intravenous infusion solution. The developed CZE method has several advantages over current chromatographic methods such as higher efficiency of separation within short analysis time, consumption of fewer quantities of chemicals and offering better resolution than HPLC. Moreover, three green spectrophotometric methods are also proposed for TIG determination that offer many advantages such as accuracy, precision, simplicity, specificity and facility of quantification and separation of the selected drug in infusion bags and pharmaceutical preparations without any techniques for extraction.

Hybrid polymer films of polyvinyl pyrrolidone (PVP)/polyvinyl alcohol (PVA) embedded with gradient levels of Bi-powder were prepared using a conventional solution casting process. XRD, FTIR, and SEM techniques have been used to examine the micro/molecular structure and morphology of the synthesized flexible films. The intensities of the diffraction peaks and transmission spectrum of the PVP/PVA gradually declined with the introduction of Bi-metal. In addition, filler changes the microstructure surface of the pure film. The modification in the microstructure leads to an enhancement in the optical absorption characteristic of the blend films. The indirect allowed transition energy was calculated via Tauc’s and ASF (Absorption Spectra Fitting) models. The decrease in the hybrid film’s bandgap returns to the localized states in the forbidden region, which led the present films to be suitable for photo-electric, solar cell, etc., applications. The relation between the transition energy and the refractive index was studied. The enhancement in the refractive index with Bi-metal concentrations led to use the as-prepared films in optical sensors. The rise of Bi-metal concentrations leads also to the improvement of the nonlinear susceptibility and refractive parameters. The optical limiting characteristics revealed that the higher concentration dopant films reduce the light transmission intensity which is appropriate for laser attenuation and optical limiting in photonic devices. The results suggest that hybrid films are promising materials in a wide range of opto-electronic applications.

Rice is the world’s largest food crop, and its production needs to be doubled by 2050 to cope with population growth and associated demand. In addition to the value of improving yields, quality is also important for breeders and consumers, but it pays less attention in arid regions. During two successive summer growing seasons, the experimental material focused on 34 genotypes developed from different crosses on Fn generation after fixation as well as six of the most recent commercial cultivars used for comparisons. The results showed that a high yield of grain followed by high milling and grain quality characteristics were observed among the 34 genotypes used in this analysis. Highly important and positive correlations between the percentage of hulling and the percentage of milling (0.424) and the yield ability could be accomplished by choosing the number of panicles per plant and the weight of the panicles. Selection criteria for good quality should be met by the percentage of head rice and many mineral elements, particularly zinc and iron. As a consequence, the genotypes M.J 5460S/SK105-1, M.J 5460S/GZ7768-1, M.J 5460S/G177-1, M.J 5460S/SK105-3 and M.J 5460S/SK106-4 had desirable high yield and quality characteristics and could be used as promising accessions to the rice breeding program in arid regions. In addition to commercial genotypes, improved Japonica rice genotypes could be produced in arid conditions for higher yield and quality, leading to an increase in total production, supporting food security and nutrition.