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10,195 result(s) for "Silva, Francisco"
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Nanocellulose Bio-Based Composites for Food Packaging
The food industry is increasingly demanding advanced and eco-friendly sustainable packaging materials with improved physical, mechanical and barrier properties. The currently used materials are synthetic and non-degradable, therefore raising environmental concerns. Consequently, research efforts have been made in recent years towards the development of bio-based sustainable packaging materials. In this review, the potential of nanocelluloses as nanofillers or as coatings for the development of bio-based nanocomposites is discussed, namely: (i) the physico-chemical interaction of nanocellulose with the adjacent polymeric phase, (ii) the effect of nanocellulose modification/functionalization on the final properties of the composites, (iii) the production methods for such composites, and (iv) the effect of nanocellulose on the overall migration, toxicity, and the potential risk to human health. Lastly, the technology readiness level of nanocellulose and nanocellulose based composites for the market of food packaging is discussed.
Synthesis of Benzyl Acetate Catalyzed by Lipase Immobilized in Nontoxic Chitosan-Polyphosphate Beads
Enzymes serve as biocatalysts for innumerable important reactions, however, their application has limitations, which can in many cases be overcome by using appropriate immobilization strategies. Here, a new support for immobilizing enzymes is proposed. This hybrid organic-inorganic support is composed of chitosan—a natural, nontoxic, biodegradable, and edible biopolymer—and sodium polyphosphate as the inorganic component. Lipase B from Candida antarctica (CALB) was immobilized on microspheres by encapsulation using these polymers. The characterization of the composites (by infrared spectroscopy, thermogravimetric analysis, and confocal Raman microscopy) confirmed the hybrid nature of the support, whose external part consisted of polyphosphate and core was composed of chitosan. The immobilized enzyme had the following advantages: possibility of enzyme reuse, easy biocatalyst recovery, increased resistance to variations in temperature (activity declined from 60 °C and the enzyme was inactivated at 80 °C), and increased catalytic activity in the transesterification reactions. The encapsulated enzymes were utilized as biocatalysts for transesterification reactions to produce the compound responsible for the aroma of jasmine.
Residual stresses and heat treatments of Inconel 718 parts manufactured via metal laser beam powder bed fusion: an overview
Additive manufacturing (AM) is a unique manufacturing process that disrupted completely the way which components are made, since this process is capable of producing complex parts layer after layer. As a matter of fact, one of its distinct technologies is metal laser beam powder bed fusion (mLB-PBF), also known as selective laser melting (SLM) or direct metal laser sintering (DMLS), which creates metallic parts with the aid of a high-energy laser beam. One of the most employed superalloys in this technology is the Inconel 718 (IN718), a precipitation-hardened alloy that is used in the marine, nuclear power plants, gas turbines, and aerospace field due to its capacity of retaining good mechanical properties at high temperatures. The research novelty of this review manuscript is the compilation of all kinds of information from the last 15 years of investigation about IN718 parts produced via mLB-PBF, namely, information related to distinct heat treatments and the influence they have in increasing mechanical properties of the manufactured components, as well as reducing residual stresses (RS) and part porosity. Throughout the review, it can be seen that the expected microstructure in the as-built state is characterized by fine columnar grains and a saturated γ matrix with the presence of the Laves phase and carbides. However, distinct heat treatments can be employed which lead to the dissolution of the undesired phases (Laves and carbides), the precipitation of the strengthening phases (γ’ and γ”), and the porosity decrease. Furthermore, it was also shown that heat treatments as well as optimized process parameters can be held accountable for lowering the RS of the IN718 manufactured parts. Nevertheless, there are still some problems to overcome, namely, the mechanical properties variability when subjecting IN718 powder to different process parameters. Moreover, the RS evolution under different heat treatments needs to be further investigated.
Laser Powder Bed Fusion of Inconel 718: Residual Stress Analysis Before and After Heat Treatment
Residual stresses (RS) of great magnitude are usually present in parts produced by Laser Powder Bed Fusion (PBF-LB), mainly owing to the extreme temperature gradients and high cooling rates involved in the process. Those “hidden” stresses can be detrimental to a part’s mechanical properties and fatigue life; therefore, it is crucial to know their magnitude and orientation. The hole-drilling strain-gage method was used to determine the RS magnitude and direction-depth profiles. Cuboid specimens in the as-built state, and after standard solution annealing and ageing heat treatment conditions, were prepared to study the RS evolution throughout the heat treatment stages. Measurements were performed on the top and lateral surfaces. In the as-built specimens, tensile stresses of ~400 MPa on the top and above 600 MPa on the lateral surface were obtained. On the lateral surface, RS anisotropy was noticed, with the horizontally aligned stresses being three times lower than the vertically aligned. RS decreased markedly after the first heat treatment. On heat-treated specimens, magnitude oscillations were observed. By microstructure analysis, the presence of carbides was verified, which is a probable root for the oscillations. Furthermore, compressive stresses immediate to the surface were obtained in heat-treated specimens, which is not in agreement with the typical characteristics of parts fabricated by PBF-LB, i.e., tensile stresses at the surface and compressive stresses in the part’s core.
Hybrid Manufacturing Processes Used in the Production of Complex Parts: A Comprehensive Review
Additive manufacturing is defined as a process based on the superposition of layers of materials in order to obtain 3D parts; however, the process does not allow achieve the adequate and necessary surface finishing. In addition, with the development of new materials with superior properties, some of them acquire high hardness and strength, consequently decreasing their ability to be machined. To overcome this shortcoming, a new technology assembling additive and subtractive processes, was developed and implemented. In this process, the additive methods are integrated into a single machine with subtractive processes, often called hybrid manufacturing. The additive manufacturing process is used to produce the part with high efficiency and flexibility, whilst machining is then triggered to give a good surface finishing and dimensional accuracy. With this, and without the need to transport the part from one machine to another, the manufacturing time of the part is reduced, as well as the production costs, since the waste of material is minimized, with the additive–subtractive integration. This work aimed to carry out an extensive literature review regarding additive manufacturing methods, such as binder blasting, directed energy deposition, material extrusion, material jetting, powder bed fusion, sheet laminating and vat polymerization, as well as machining processes, studying the additive-subtractive integration, in order to analyze recent developments in this area, the techniques used, and the results obtained. To perform this review, ScienceDirect, Web of Knowledge and Google Scholar were used as the main source of information because they are powerful search engines in science information. Specialized books have been also used, as well as several websites. The main keywords used in searching information were: “CNC machining”, “hybrid machining”, “hybrid manufacturing”, “additive manufacturing”, “high-speed machining” and “post-processing”. The conjunction of these keywords was crucial to filter the huge information currently available about additive manufacturing. The search was mainly focused on publications of the current century. The work intends to provide structured information on the research carried out about each one of the two considered processes (additive manufacturing and machining), and on how these developments can be taken into consideration in studies about hybrid machining, helping researchers to increase their knowledge in this field in a faster way. An outlook about the integration of these processes is also performed. Additionally, a SWOT analysis is also provided for additive manufacturing, machining and hybrid manufacturing processes, observing the aspects inherent to these technologies.
Recent Advances on Coated Milling Tool Technology—A Comprehensive Review
The milling process is one of the most used processes in the manufacturing industry. Milling, as a process, as evolved, with new machines and methods being employed, in order to obtain the best results consistently. Milling tools have also seen quite an evolution, from the uncoated high-speed steel tool, to the now vastly used, coated tools. Information on the use of these coated tools in recent scientific researches was collected. The coatings that are currently being researched are going to be presented, highlighting some novel advances in the nanocomposite and diamond coatings area, as these coatings are seeing a growing use in the industry, with very satisfactory results, with performance and tool-life increase. Wear mechanism of various types of coatings are also a popular topic on recent research, as the cutting behavior of these coated tools provides valuable information on the tool’s-life. Furthermore, analysis of these mechanisms enables for the selection of the best coating type for the correct application. Recently, the employment of coated tools paired with sustainable lubrication methods as seen some use. As this presents the opportunity to enhance the coated tool’s and the process’s performance, obtaining better results, in terms of better tool-life and better surface finish quality, in a more sustainable fashion.
A Review of Heat Treatments on Improving the Quality and Residual Stresses of the Ti–6Al–4V Parts Produced by Additive Manufacturing
Additive manufacturing (AM) can be seen as a disruptive process that builds complex components layer upon layer. Two of its distinct technologies are Selective Laser Melting (SLM) and Electron Beam Melting (EBM), which are powder bed fusion processes that create metallic parts with the aid of a beam source. One of the most studied and manufactured superalloys in metal AM is the Ti–6Al–4V, which can be applied in the aerospace field due to its low density and high melting point, and in the biomedical area owing to its high corrosion resistance and excellent biocompatibility when in contact with tissues or bones of the human body. The research novelty of this work is the aggregation of all kinds of data from the last 20 years of investigation about Ti–6Al–4V parts manufactured via SLM and EBM, namely information related to residual stresses (RS), as well as the influence played by different heat treatments in reducing porosity and increasing mechanical properties. Throughout the report, it can be seen that the expected microstructure of the Ti–6Al–4V alloy is different in both manufacturing processes, mainly due to the distinct cooling rates. However, heat treatments can modify the microstructure, reduce RS, and increase the ductility, fatigue life, and hardness of the components. Furthermore, distinct post-treatments can induce compressive RS on the part’s surface, consequently enhancing the fatigue life.
Dempster–Shafer Theory for Modeling and Treating Uncertainty in IoT Applications Based on Complex Event Processing
The Internet of Things (IoT) has emerged from the proliferation of mobile devices and objects connected, resulting in the acquisition of periodic event flows from different devices and sensors. However, such sensors and devices can be faulty or affected by failures, have poor calibration, and produce inaccurate data and uncertain event flows in IoT applications. A prominent technique for analyzing event flows is Complex Event Processing (CEP). Uncertainty in CEP is usually observed in primitive events (i.e., sensor readings) and rules that derive complex events (i.e., high-level situations). In this paper, we investigate the identification and treatment of uncertainty in CEP-based IoT applications. We propose the DST-CEP, an approach that uses the Dempster–Shafer Theory to treat uncertainties. By using this theory, our solution can combine unreliable sensor data in conflicting situations and detect correct results. DST-CEP has an architectural model for treating uncertainty in events and its propagation to processing rules. We describe a case study using the proposed approach in a multi-sensor fire outbreak detection system. We submit our solution to experiments with a real sensor dataset, and evaluate it using well-known performance metrics. The solution achieves promising results regarding Accuracy, Precision, Recall, F-measure, and ROC Curve, even when combining conflicting sensor readings. DST-CEP demonstrated to be suitable and flexible to deal with uncertainty.
Recent Advances in Turning Processes Using Coated Tools—A Comprehensive Review
Turning continues to be the largest segment of the machining industry, which highlights the continued demand for turned parts and the overall improvement of the process. The turning process has seen quite an evolution, from basic lathes using solid tools, to complex CNC (Computer Numerical Control) multi-process machines, using, for the most part, coated inserts and coated tools. These coatings have proven to be a significant step in the production of high-quality parts and a higher tool life that have captivated the industry. Continuous improvement to turning coated tools has been made, with many researches focusing on the optimization of turning processes that use coated tools. In the present paper, a presentation of various recently published papers on this subject is going to be made, mentioning the various types of coatings that have recently been used in the turning process, the turning of hard to machine materials, such as titanium alloys and Inconel, as well as the interaction of these coatings with the turned surfaces, the wear patterns that these coatings suffer during the turning of materials and relating these wear mechanisms to the coated tool’s life expectancy. Some lubrication conditions present a more sustainable alternative to current methods used in the turning process; the employment of coated tool inserts under these conditions is a current popular research topic, as there is a focus on opting for more eco-friendly machining options.