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Natural gas flaring, with its harmful environmental, health, and economic effects, is common in the Nigerian oil and gas industry because of a lower tax regime for flared gases. Based on the adverse effects of flared gas, the Nigerian government has renewed and improved its efforts to reduce or eliminate gas flaring through the application of natural gas utilisation techniques. However, because the conventional approach to flare gas utilisation is heavily reliant on achieving scale, fuel, and end-product prices, not all technologies are technically and economically viable for typically capturing large and small quantities of associated gas from various flare sites or gas fields (located offshore or onshore). For these reasons, this paper reviews and compares various flare gas utilisation options to guide their proper selection for appropriate implementation in the eradication of routine gas flaring in Nigeria and to promote the Zero Routine Flaring initiative, which aims to reduce flaring levels dramatically by 2030. A qualitative assessment is used in this study to contrast the various flare gas utilisation options against key decision drivers. In this analysis, three natural gas utilisation processes—liquefied natural gas (LNG), gas to wire (GTW), and gas to methanol (GTM)—are recommended as options for Nigeria because of their economic significance, technological viability (both onshore and offshore), and environmental benefits. All these gas utilisation options have the potential to significantly reduce and prevent routine gas flaring in Nigeria and can be used separately or in combination to create synergies that could lower project costs and product market risk. This article clearly identifies the environmental benefits and the technical and economic viability of infrastructure investments to recover and repurpose flare gasses along with recommendation steps to select and optimise economies of scale for an associated natural gas utilisation option.

This study examines the fireside corrosion of FeCrAl, NiCr, NiCrAlY and A625 coatings applied by ‘high velocity oxy fuel’(HVOF) and exposed to simulated biomass firing conditions (gas composition CO 2 , N 2 , SO 2 and HCl). The coatings and a typical base steel alloy (T92) were exposed to simulated conditions at 600 °C for 1000 h in a laboratory scale furnace. Samples were coated with a potassium chloride deposit. Samples were then cold mounted in a low-shrinkage epoxy resin and then cross-sectioned. Corrosion was assessed by dimensional metrology comparing the coating thickness change of the samples. The cross-sections of the ‘worst’ and ‘best’ coatings were examined. Results show that all but one coating (HVOF NiCr) outperformed the T92 alloy. No coating composition or method was conclusively better. Evidence of Cr depletion as well as the formation of a sulphidation layer have been found in the exposed samples with coatings. The formation of a K 2 SO 4 layer has also been observed on all coated specimens.

The use of hydrocarbon fuels increases with population growth and rising standards of living, and so does natural gas flaring. Natural gas flaring is both a waste of natural resources and a violation of Nigeria’s energy policy for sustainable development through natural gas conservation. However, it remains the most cost-efficient and effective associated natural gas (ANG) management option in developing countries such as Nigeria. The World Bank’s initiative to eliminate routine gas flaring by 2030 has increased the need to limit or eliminate routine gas flaring. Often, studies on natural gas utilisation techniques fail to consider the lack of practical tools that integrate economic, technical, and regulatory factors into a gas flaring management framework, and the intricacies of existing tools, which often come at the expense of simplicity to achieve real-time information output. This paper aims to establish a framework and ANG management tool to reduce regular gas flaring in Nigeria. This research established a management framework (using a flowchart decision tree) and models to provide a user-friendly ANG flaring tool (using a MATLAB graphical front end user interface with back-end ASPEN HYSYS thermodynamic models). This was combined with techno-economic models for liquefied natural gas, gas-to-methanol, and gas-to-wire ANG utilisation options. The tool was then tested with data obtained from Fields Y and X in the Niger Delta region of Nigeria. The results, considering both economic and technical factors, showed that the choice of liquefied natural gas for Field Y was best due to its proximity to the pipeline infrastructure and its cost-effectiveness, and the availability of a high-demand LNG market for that area. For Field X, gas-to-wire was best due to its proximity to the electrical grid and high electricity requirements for that area. Additional geographical profiles in West Africa and ANG utilisation alternatives were recommended for further investigation. This paper developed and validated a one-of-a-kind ANG flaring management tool that incorporates techno-economic analysis of selected ANG utilisation options to assist operators and investors in making more profitable investment decisions.

Polyoxymethylene dimethyl ether (PODEn, n ≥ 1) is a promising alternative fuel to diesel with higher reactivity and low soot formation tendency. In this study, PODE3-4 is used as a pilot ignition fuel for methane (CH4) and the combustion characteristics of PODE3-4/CH4 mixtures are investigated numerically using an updated PODE3-4 mechanism. The ignition delay time (IDT) and laminar burning velocity (LBV) of PODE3-4/CH4 blends were calculated at high temperature and high pressure relevant to engine conditions. It is discovered that addition of a small amount of PODE3-4 has a dramatic promotive effect on IDT and LBV of CH4, whereas such a promoting effect decays at higher PODE3-4 addition. Kinetic analysis was performed to gain more insight into the reaction process of PODE3-4/CH4 mixtures at different conditions. In general, the promoting effect originates from the high reactivity of PODE3-4 at low temperatures and it is further confirmed in simulations using a perfectly stirred reactor (PSR) model. The addition of PODE3-4 significantly extends the extinction limit of CH4 from a residence time of ~0.5 ms to that of ~0.08 ms, indicating that the flame stability is enhanced as well by PODE3-4 addition. It is also found that NO formation is reduced in lean or rich flames; moreover, NO formation is inhibited by too short a residence time.

Ammonia has attracted considerable attention as a zero-carbon fuel for decarbonizing energy-intensive industries. However, its low reactivity and narrow flammability limit efficient ignition and efficient combustion. By using CONVERGR software, this study numerically investigates the ignition and combustion characteristics of liquid ammonia spray ignited by dimethyl ether spray in a constant-volume chamber at an ambient temperature of 900 K. Critical parameters, including injection angles (90°–150°), liquid ammonia injection pressures (60–90 MPa), and ambient pressures (2.8–5.8 MPa), were systematically analyzed to evaluate their effects on ignition conditions and emissions. Results indicate that increasing the injection angle improves mixing between liquid ammonia and dimethyl ether sprays, enhancing combustion efficiency and achieving a maximum efficiency of 92.47% at 120°. Excessively large angles cause incomplete combustion or misfire. Higher liquid ammonia injection pressures improve atomization and promote earlier interactions between the sprays but reduce combustion efficiency, decreasing by approximately 2% as injection pressure increases from 60 MPa to 90 MPa. Higher ambient pressures improve combustion stability but decrease ammonia combustion efficiency. Post-combustion NO emissions at 5.8 MPa are reduced by 60.48% compared to 3.8 MPa. The formation of NO is strongly correlated with the combustion efficiency of liquid ammonia. A higher combustion rate of liquid ammonia tends to result in elevated NO. Based on these findings, an injection angle of 120°, an NH3 injection pressure of 75 MPa, and an ambient pressure of 3.8 MPa are recommended to optimize combustion efficiency.

BackgroundBiomass and municipal solid waste offer sustainable sources of energy; for example to meet heat and electricity demand in the form of combined cooling, heat and power. Combustion of biomass has a lesser impact than solid fossil fuels (e.g. coal) upon gas pollutant emissions, whilst energy recovery from municipal solid waste is a beneficial component of an integrated, sustainable waste management programme. Concurrent combustion of these fuels using a fluidised bed combustor may be a successful method of overcoming some of the disadvantages of biomass (high fuel supply and distribution costs, combustion characteristics) and characteristics of municipal solid waste (heterogeneous content, conflict with materials recycling). It should be considered that combustion of municipal solid waste may be a financially attractive disposal route if a 'gate fee' value exists for accepting waste for combustion, which will reduce the net cost of utilising relatively more expensive biomass fuels.ResultsEmissions of nitrogen monoxide and sulphur dioxide for combustion of biomass are suppressed after substitution of biomass for municipal solid waste materials as the input fuel mixture. Interactions between these and other pollutants such as hydrogen chloride, nitrous oxide and carbon monoxide indicate complex, competing reactions occur between intermediates of these compounds to determine final resultant emissions.ConclusionsFluidised bed concurrent combustion is an appropriate technique to exploit biomass and municipal solid waste resources, without the use of fossil fuels. The addition of municipal solid waste to biomass combustion has the effect of reducing emissions of some gaseous pollutants.

Steam oxidation of heat exchanger tubes and pipe work is of growing interest as research into the improvement of power plant efficiencies shows the need for much higher steam temperatures and pressures. This paper reports on the characterisation of the oxide scales grown during the steam oxidation of four alloys (T23, T92, TP347HFG and Inconel 740) in atmospheric pressure steam at four temperatures (600, 650, 700 and 750°C) for periods of 250, 500 and 1000 h. Three methods have been employed in analysing these scales: reflected light optical microscopy, scanning electron microscopy with energy dispersive X-ray analysis and X-ray diffraction. The thickness, composition, morphology and spalling behaviour of the oxides differed with alloy composition, exposure times/temperatures and sample shapes. The ferritic steels exhibited the most severe oxidation, with the scales formed on these typically being triple-layered: an inner layer of Fe - Cr spinel, central layer of magnetite and outermost layer of haematite. However, the amount of haematite formed changed with the exposure time/temperature, alloy and sample orientation. In comparison TP347HFG and Inconel 740 showed significantly slower oxidation, with generally thin oxide scales (<5 µm) developing even at the highest exposure temperatures, though TP347HFG started to form some nodular growths after 1000 h exposure at the two higher temperatures.

The current pressures for increased worldwide electricity supplies coupled with reduced environmental emissions, are leading to a revolution in the operating conditions within pulverised fuel fired boilers to improve their generating efficiencies. This paper reports results from a series of 1000 hour 'deposit recoat' laboratory tests that are assessing the effects of increasing heat exchanger surface temperatures (600, 650 and 700°C) on the fireside corrosion resulting from the combustion of a biomass/coal mix using oxy-firing (with hot flue gas recycle before desulfurisation). The results presented focus on two materials: a ferritic steel (T92) and an austenitic stainless steel (TP347HFG), to illustrate the effects of alloy Cr content. After exposure, the samples were examined using scanning electron microscopy/energy dispersive X-ray analysis to evaluate: surface morphological changes (formation of nodules and whiskers) on bare samples; microstructures of scale/deposit/metal in crosssections; and, elemental distributions. The performances of the samples were determined using dimensional metrology: pre-exposure contact metrology and post-exposure optical microscopy image analysis measurements. The metal loss data generated is being used to develop statistical models to predict the lifetimes of candidate materials for use in superheaters/reheaters in advanced power plants.

To meet environmental, legislative and commercial targets, gas turbines must operate with increasingly high gas temperatures and fuels with increased contaminant levels. A series of three burner rig tests have been used to evaluate the effects of fly ash, gas moisture and gas temperatures on alkali metal induced hot corrosion in the metal temperature range of 700 - 960°C on three uncoated materials (Haynes 230, IN939, and IN738LC) and one coated system (IN738LC/HVOF SV21). It has been found that the specific burner rig test conditions impact upon the severity of samples' corrosion and oxidation, with samples exposed to impacting fly ash demonstrating reduced hot corrosion. However, type II hot corrosion (pitting) and type I hot corrosion (internal damage and sulfidation) have been observed under all test conditions. Generally IN939 was more resistant to hot corrosion over both high and low temperatures than IN738LC or Haynes 230. SV21-coatings on IN738LC provided improved resistance to both type I and II hot corrosion.

The effect of aerofoil geometry on the oxidative degradation mechanisms experienced by thermal barrier coatings (TBCs) used on industrial turbine blades has been investigated. Modified aerofoil-shaped samples (CMSX4 coated with high-velocity oxy-fuel sprayed AMDRY 995 and air plasma sprayed TBC) were oxidised at five temperatures in furnaces from 900 to 1000°C. Scanning electron microscopy and energy dispersive X-ray analysis were used to characterise details of the microstructural evolution of the thermally grown oxide and to monitor inter-diffusion between the bond coating and substrate. Additionally, a novel non-destructive examination technique (flash thermography) was used to detect and track the spread of cracks beneath the TBCs. Multiple samples cracking in identical locations suggested an effect of geometry in the failure of coatings. Furthermore, it was observed that coating curvature influenced spinel formation.