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In search of affordable, flexible, lightweight, efficient and stable supercapacitors, metal oxides have been shown to provide high charge storage capacity but with poor cyclic stability due to structural damage occurring during the redox process. Here, we develop an efficient flexible supercapacitor obtained by carbonizing abundantly available and recyclable jute. The active material was synthesized from jute by a facile hydrothermal method and its electrochemical performance was further enhanced by chemical activation. Specific capacitance of 408 F/g at 1 mV/s using CV and 185 F/g at 500 mA/g using charge-discharge measurements with excellent flexibility (~100% retention in charge storage capacity on bending) were observed. The cyclic stability test confirmed no loss in the charge storage capacity of the electrode even after 5,000 charge-discharge measurements. In addition, a supercapacitor device fabricated using this carbonized jute showed promising specific capacitance of about 51 F/g, and improvement of over 60% in the charge storage capacity on increasing temperature from 5 to 75 °C. Based on these results, we propose that recycled jute should be considered for fabrication of high-performance flexible energy storage devices at extremely low cost.

In this study, \"Real-Time Information Access in Urban Environments: A User Interaction Study Using the Real-Time Information Test,\" participant data revealed a diverse group with an average age of 31, a balanced gender distribution, varying education levels (40% Bachelor's, 20% Master's, 40% PhD), and an average of 6 years of experience with urban navigation. The findings of the Real-Time Information Test (RTIT) showed an average job completion time of 140 seconds and a low average error count of 1.2, demonstrating competency in interacting with real-time information systems. Furthermore, the User Satisfaction Survey found an average of 8.4 overall satisfaction ratings, 8.4 user-friendliness ratings, and 7.8 information accuracy ratings, indicating excellent user experiences. These results highlight user variety, increases in job efficiency and accuracy, and high user satisfaction, all of which contribute to a comprehensive knowledge of real-time information access in urban contexts, with implications for system advancements and urban planning.

Ki67 is a commonly used marker of cancer cell proliferation, and has significant prognostic value in breast cancer. In spite of its clinical importance, assessment of Ki67 remains a challenge, as current manual scoring methods have high inter- and intra-user variability. A major reason for this variability is selection bias, in that different observers will score different regions of the same tumor. Here, we developed an automated Ki67 scoring method that eliminates selection bias, by using whole-slide analysis to identify and score the tumor regions with the highest proliferative rates. The Ki67 indices calculated using this method were highly concordant with manual scoring by a pathologist (Pearson's r = 0.909) and between users (Pearson's r = 0.984). We assessed the clinical validity of this method by scoring Ki67 from 328 whole-slide sections of resected early-stage, hormone receptor-positive, human epidermal growth factor receptor 2-negative breast cancer. All patients had Oncotype DX testing performed (Genomic Health) and available Recurrence Scores. High Ki67 indices correlated significantly with several clinico-pathological correlates, including higher tumor grade (1 versus 3, P<0.001), higher mitotic score (1 versus 3, P<0.001), and lower Allred scores for estrogen and progesterone receptors (P = 0.002, 0.008). High Ki67 indices were also significantly correlated with higher Oncotype DX risk-of-recurrence group (low versus high, P<0.001). Ki67 index was the major contributor to a machine learning model which, when trained solely on clinico-pathological data and Ki67 scores, identified Oncotype DX high- and low-risk patients with 97% accuracy, 98% sensitivity and 80% specificity. Automated scoring of Ki67 can thus successfully address issues of consistency, reproducibility and accuracy, in a manner that integrates readily into the workflow of a pathology laboratory. Furthermore, automated Ki67 scores contribute significantly to models that predict risk of recurrence in breast cancer.

The focus on the bioactive effects of plants concerns mainly ruminal microflora for the modulation of rumen fermentation with very little emphasis placed on their consequences on health parameters, including antioxidative and immune stimulating effects. The aim of the present study was to examine the effects of supplementing phytogenic feed additives composed of a mixture of eucalyptus (Eucalyptus citriodora) and poplar (Populus deltoides) leaf-meal (EPLM) on immune response, antioxidant status, metabolic profile, enteric methane production, growth performance, and nutrient utilization in buffalo (Bubalus bubalis) calves. In vitro studies with graded doses of EPLM extract revealed a reduction in total gas and methane production with an increased proportion of propionate without affecting feed degradability. In the in vivo experimentation, eighteen female buffalo calves (10–14 months old, avg. body weight 131.68 ± 7.50 kg) were divided into three groups (CONT, EPLM-1, and EPLM-2) of six each in a completely randomized design. Treatment groups were supplemented with a blend (1:1) of dry grounded eucalyptus (Eucalyptus citriodora) and poplar (Populus deltoids) leaves (50 g, EPLM-1; 150 g, EPLM-2). Feed intake and growth rate of buffalo calves fed on different feeding regimens did not differ (p > 0.05). Haemato-biochemical parameters reveal no variations (p > 0.05) among groups, irrespective of period of collection, except the concentration of blood urea, which was decreased (p < 0.05) in both treatment groups as compared to the control. The levels of reduced glutathione (GSH), catalase (CAT), and superoxide dismutase (SOD) increased (p < 0.05) in EPLM supplemented animals as compared to CONT. The extent of lipid peroxidation (LPO) was reduced (p < 0.05) with increased level of EPLM in the diet. The total thiol group (T-SH) was also increased with the supplementation of leaves in the diet. The mean absolute values for skin thickness following the intra-dermal injection of PHA-P were increased (p < 0.05) in all the supplemented animals relative to CONT. However, there was no significant difference among the calves fed graded levels of these feed additives in the diet. The Ab titer against Pasteurella multocida vaccine was higher (p < 0.05) on both day 45 and 90 in both treatments, irrespective of the level of additive supplemented. The enteric methane production was reduced in EPLM supplemented buffaloes; however, digestibility of all the nutrients remained comparable (p > 0.05) among the animals. It may be concluded that blends of eucalyptus (Eucalyptus citriodora) and poplar (Populus deltoides) leaf-meal (50 g/h/d) containing 3.19 g, 2.30 g, and 0.71 g of total phenolics, tannin phenolics, and condensed tannins, respectively, can be used as the phytogenic feed additive for improving antioxidant status and immunity of buffalo calves, and mitigating enteric methane production without affecting performance and nutrient utilization.

A laboratory experiment was conducted to study the degradation dynamics of halosulfuron-methyl residues in sandy loam and clay loam soil. The herbicide formulation was applied at 0.034 and 0.068 mg kg− 1 equivalent to field application dose of 67.5 and 135 g a.i. ha− 1 as single and double dose respectively. Soil samples were collected on 0 (1 h), 1, 3, 7, 10, 15, 30 and 45 days after treatments. Extraction was done using modified QuEChERS method. Residues were estimated by UPLC coupled with quadrupole Dalton mass detector. Average recoveries ranged from 85.5% to 94.5% for both soils at different fortification levels of 0.005 to 0.1 mg kg− 1 with limit of detection (LOD) and limit of quantification (LOQ) as 0.001 and 0.005 mg kg− 1, respectively. Dissipation followed first order kinetics with half-life of 8.4 to 10.7 days in both soil at two doses. The residues reached below LOQ of 0.005 mg kg− 1 after 45 days of herbicide application.

Large-eddy simulations (LES) using explicit filtering are performed to obtain grid-independent solutions of turbulent wake flow behind a circular cylinder at Re D = 3900 on non-Cartesian type grids. A differential elliptic equation where the filter kernel is implicitly defined is discretized in an unstructured-grid solver to enable explicit filtering on non-Cartesian grids. The separation of filtering procedure from discretization is known to produce an LES solution of which error is mainly attributed to the capability of a sub-filter scale (SFS) model. Equipped with the differential filter and the Vreman SFS model, explicitly filtered LES on unstructured grids is shown to produce nearly grid-independent solutions for flow over a circular cylinder at a critical Reynolds number.

The authors would like to make the following correction to the published paper [...]

Herbicide resistance in weeds is a global threat to sustaining food security. In India, herbicide-resistant Phalaris minor was the major problem in wheat for more than two decades, but the continuous use of metsulfuron-methyl (an ALS inhibitor) to control broadleaf weeds has resulted in the evolution of ALS inhibitor-resistant Rumex dentatus L. This review summarizes the current scenario of herbicide resistance in R. dentatus, along with its ecology and management perspectives. Studies have provided valuable insights on the emergence pattern of R. dentatus under different environments in relation to tillage, cropping systems, nutrients, and irrigation. Moreover, R. dentatus has exhibited higher emergence under zero tillage, with high infestation levels in rice-wheat compared to other wheat-based cropping systems (sorghum-wheat). Alternative herbicides for the management of resistant R. dentatus include pendimethalin, 2,4-D, carfentrazone, isoproturon, and metribuzin. Although the pre-emergence application of pendimethalin is highly successful in suppressing R. dentatus, but its efficiency is questionable under lower field soil moisture and heavy residue load conditions. Nevertheless, the biological data may be utilized to control R. dentatus. Therefore, herbicide rotation with suitable spray techniques, collecting weed seeds at differential heights from wheat, crop rotation, alternate tillage practices, and straw retention are recommended for addressing the resistance issue in R. dentatus in North India conditions. Overall, we discuss the current state of herbicide resistance in R. dentatus, the agronomic factors affecting its population, its proliferation in specific cropping systems (rice-wheat), and management strategies for containing an infestation of a resistant population.

We report the exotic photoluminescence (PL) behaviour of 3D topological insulator Bi 2 Te 3 single crystals grown by customized self-flux method and mechanically exfoliated few layers (18 ± 2 nm)/thin flakes obtained by standard scotch tape method from as grown Bi 2 Te 3 crystals. The experimental PL studies on bulk single crystal and mechanically exfoliated few layers of Bi 2 Te 3 evidenced a broad red emission in the visible region from 600–690 nm upon 375 nm excitation wavelength corresponding to optical band gap of 2 eV. These findings are in good agreement with our theoretical results obtained using the ab initio density functional theory framework. Interestingly, the observed optical band gap is several times larger than the known electronic band gap of ~0.15 eV. The experimentally observed 2 eV optical band gap in the visible region for bulk as well as for mechanically exfoliated few layers Bi 2 Te 3 single crystals clearly rules out the quantum confinement effects in the investigated samples which are well known in the 2D systems like MoS 2 ,WS 2 , WSe 2 , and MoSe 2 for 1–3 layers.

Purpose This paper aims to depict the erosion performance of two HVOF-coated micron layers (Colmonoy-88 and Stellite-6) on pump impeller steel (SS-410) by using Taguchi's method. Taguchi's array (L16) was used to optimize the erosion wear (in terms of weight loss) by using four influencing parameters such as rotational speed, solid concentration, average particle size and time which were varied at four different levels. Design/methodology/approach The experiments were carried out by using a Ducom slurry tester with rotational speed in the range of 750-1,500 rpm, solid concentration of 35-65 per cent by weight, time period of 75-210 min and average particle sizes in the range of < 53 to 250 µm. Bottom Ash with a nominal size range of < 53 to 250 µm was used as erodent. The process parameters were optimized by using Taguchi's method. The ANOVA method was used to validate the results given by Taguchi's method. Findings The results revealed that the presence of both carbides and borides and the additional presence of Cr in Colmonoy-88 coating enhancing the slurry erosion resistance of Colmonoy-88 coating. Moreover, the chromium and tungsten carbide particles help in increasing the bond strength between the coating and the substrate material. Further, it was also found that the time was the most dominant factor as compared to other factors. Originality/value The very less work has been reported on optimization of erosion wear response of Colmonoy-88 and Stellite-6 coatings by using different design of experiment techniques. Further, the erosion wear mechanism of both coatings has been studied by using image j analysis software.