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Chondrules are spherical or subspherical particles of crystallized or partially crystallized liquid silicates that constitute large-volume fractions of most chondritic meteorites. Chondrules typically range 0.1 - 2 mm in size and solidified with cooling rates of 10 - 1000 K h - 1 , yet these characteristics prove difficult to reconcile with proposed formation models. We numerically show that collisions among planetesimals containing volatile materials naturally explain both the sizes and cooling rates of chondrules. We show that the high-velocity collisions with volatile-rich planetesimals first induced in the solar nebula by Jupiter’s formation produced increasing amounts of silicate melt for increasing impact velocities above 2 km s - 1 . We propose that the expanding gas formed from volatile materials by collisional heating dispersed and cooled the silicate melt, resulting in droplet sizes and cooling rates consistent with the observed sizes and inferred cooling rates. We further show that the peak melt production is linked to the onset of Jupiter’s runaway gas accretion, and argue that the peak age of chondrules points to Jupiter’s birth dating 1.8 Myr after CAIs.

Analysis of silicon-rich, nanometre-sized dust particles near Saturn shows them to consist of silica, which was initially embedded in icy grains emitted from Enceladus’ subsurface waters and released by sputter erosion in Saturn’s E ring; their properties indicate their ongoing formation and transport by high-temperature hydrothermal reactions from the ocean floor and up into the plume of Enceladus. Evidence of hydrothermal activity on Enceladus Hsiang-Wen Hsu et al . have analysed the silicon-rich, nanometre-sized dust stream particles in the Saturnian system using the Cosmic Dust Analyser (CDA) onboard the Cassini spacecraft. With the help of experiments and modelling, the particles are interpreted as silica grains that were initially embedded in the icy plume emitted from subsurface waters on Enceladus and released by sputter erosion in Saturn's E ring. Their properties indicate their formation and transport by high-temperature hydrothermal reactions from the ocean floor and up into the plume of Enceladus. Detection of sodium-salt-rich ice grains emitted from the plume of the Saturnian moon Enceladus suggests that the grains formed as frozen droplets from a liquid water reservoir that is, or has been, in contact with rock 1 , 2 . Gravitational field measurements suggest a regional south polar subsurface ocean of about 10 kilometres thickness located beneath an ice crust 30 to 40 kilometres thick 3 . These findings imply rock–water interactions in regions surrounding the core of Enceladus. The resulting chemical ‘footprints’ are expected to be preserved in the liquid and subsequently transported upwards to the near-surface plume sources, where they eventually would be ejected and could be measured by a spacecraft 4 . Here we report an analysis of silicon-rich, nanometre-sized dust particles 5 , 6 , 7 , 8 (so-called stream particles) that stand out from the water-ice-dominated objects characteristic of Saturn. We interpret these grains as nanometre-sized SiO 2 (silica) particles, initially embedded in icy grains emitted from Enceladus’ subsurface waters and released by sputter erosion in Saturn’s E ring. The composition and the limited size range (2 to 8 nanometres in radius) of stream particles indicate ongoing high-temperature (>90 °C) hydrothermal reactions associated with global-scale geothermal activity that quickly transports hydrothermal products from the ocean floor at a depth of at least 40 kilometres up to the plume of Enceladus.

It has been suggested that Saturn’s moon Enceladus possesses a subsurface ocean. The recent discovery of silica nanoparticles derived from Enceladus shows the presence of ongoing hydrothermal reactions in the interior. Here, we report results from detailed laboratory experiments to constrain the reaction conditions. To sustain the formation of silica nanoparticles, the composition of Enceladus’ core needs to be similar to that of carbonaceous chondrites. We show that the presence of hydrothermal reactions would be consistent with NH 3 - and CO 2 -rich plume compositions. We suggest that high reaction temperatures (>50 °C) are required to form silica nanoparticles whether Enceladus’ ocean is chemically open or closed to the icy crust. Such high temperatures imply either that Enceladus formed shortly after the formation of the solar system or that the current activity was triggered by a recent heating event. Under the required conditions, hydrogen production would proceed efficiently, which could provide chemical energy for chemoautotrophic life. Observations indicate that the southern hemisphere of Enceladus is geologically active, with spray containing Si nanoparticles being ejected from an underground ocean. Here, the authors report that experiments to constrain reaction conditions suggest the core is similar to that of carbonaceous chondrites.

Isolated silica concretions in calcareous sediments have unique shapes and distinct sharp boundaries and are considered to form by diagenesis of biogenic siliceous grains. However, the details and rates of syngenetic formation of these spherical concretions are still not fully clear. Here we present a model for concretion growth by diffusion, with chemical buffering involving decomposition of organic matter leading to a pH change in the pore-water and preservation of residual bitumen cores in the concretions. The model is compatible with some pervasive silica precipitation. Based on the observed elemental distributions, C, N, S, bulk carbon isotope and carbon preference index (CPI) measurements of the silica-enriched concretions, bitumen cores and surrounding calcareous rocks, the rate of diffusive concretion growth during early diagenesis is shown using a diffusion-growth diagram. This approach reveals that ellipsoidal SiO 2 concretions with a diameter of a few cm formed rapidly and the precipitated silica preserved the bitumen cores. Our work provides a generalized chemical buffering model involving organic matter that can explain the rapid syngenetic growth of other types of silica accumulation in calcareous sediments.

Carbonate concretions occur in sedimentary rocks of widely varying geological ages throughout the world. Many of these concretions are isolated spheres, centered on fossils. The formation of such concretions has been variously explained by diffusion of inorganic carbon and organic matter in buried marine sediments. However, details of the syn-depositional chemical processes by which the isolated spherical shape developed and the associated carbon sources are little known. Here we present evidence that spherical carbonate concretions (diameters φ : 14 ~ 37 mm) around tusk-shells ( Fissidentalium spp.) were formed within weeks or months following death of the organism by the seepage of fatty acid from decaying soft body tissues. Characteristic concentrations of carbonate around the mouth of a tusk-shell reveal very rapid formation during the decay of organic matter from the tusk-shell. Available observations and geochemical evidence have enabled us to construct a ‘Diffusion-growth rate cross-plot’ that can be used to estimate the growth rate of all kinds of isolated spherical carbonate concretions identified in marine formations. Results shown here suggest that isolated spherical concretions that are not associated with fossils might also be formed from carbon sourced in the decaying soft body tissues of non-skeletal organisms with otherwise low preservation potential.

One of the probable scenarios of differentiation between silicate-ice in an icy object is the settling of a silicate particle in water after the melting of the object. In order for settling to proceed or occur, the size of the particle should be sufficiently large such that the settling velocity of the particle exceeds the background flow velocity induced by thermal convection. The sizes of the particles change because of dissolution and precipitation. This process is called ripening. In this study, the critical particle sizes required for settling, and the timescales for the growth of the particles to these sizes through ripening, are analytically derived. It is observed that settling is possible if the silicate particles coagulate with each other to form a network in water. If the particles do not coagulate, the probability of the occurrence of settling is low, because the time duration required for the particle growth to the critical size is large. The coagulation of silicate particles strongly depends on the pH of the water.

Collisions between sintered icy dust aggregates are numerically simulated. If the temperature of an icy aggregate is sufficiently high, sintering promotes molecular transport and a neck between adjacent grains grows. This growth changes the mechanical responses of the neck. We included this effect to a simulation code, and conducted collisional simulations. For porous aggregates, the critical velocity for growth, below which the mass of an aggregate increases, decreased from 50\\,m\\,s\\(^{-1}\\) for the non-sintered case to 20\\,m\\,s\\(^{-1}\\). For compacted aggregates, the main collisional outcome is bouncing. These results come from the fact that the strength of the neck is increased by sintering. The numerical results suggest that the collisional growth of icy grain aggregates is strongly affected by sintering.

It has been implicitly assumed that ices on grains in molecular clouds and proto planetary disks are formed by homogeneous layers regardless of their composition or crystallinity. To verify this assumption, we observed the H2O deposition onto refractory substrates and the crystallization of amorphous ices (H2O, CO2, and CO) using an ultra-high-vacuum transmission electron microscope. In the H2O-deposition experiments, we found that three-dimensional islands of crystalline ice (Ic) were formed at temperatures above 130 K. The crystallization experiments showed that uniform thin films of amorphous CO and H2O became three-dimensional islands of polyhedral crystals; amorphous CO2, on the other hand, became a thin film of nano crystalline CO2 covering the amorphous H2O. Our observations show that crystal morphologies strongly depend not only on the ice composition, but also on the substrate. Using experimental data concerning the crystallinity of deposited ices and the crystallization timescale of amorphous ices, we illustrated the criteria for ice crystallinity in space and outlined the macroscopic morphology of icy grains in molecular clouds as follows: amorphous H2O covered the refractory grain uniformly, CO2 nano-crystals were embedded in the amorphous H2O, and a polyhedral CO crystal was attached to the amorphous H2O. Furthermore, a change in the grain morphology in a proto-planetary disk is shown. These results have important implications for the chemical evolution of molecules, non-thermal desorption, collision of icy grains, and sintering.

The latest observation of HL Tau by ALMA revealed spectacular concentric dust rings in its circumstellar disk. We attempt to explain the multiple ring structure as a consequence of aggregate sintering. Sintering is known to reduce the sticking efficiency of dust aggregates and occurs at temperatures slightly below the sublimation point of their constituent material. We here present a dust growth model incorporating sintering and use it to simulate global dust evolution due to sintering, coagulation, fragmentation, and radial inward drift in a modeled HL Tau disk. We show that aggregates consisting of multiple species of volatile ices experience sintering, collisionally disrupt, and pile up at multiple locations slightly outside the snow lines of the volatiles. At wavelengths of 0.87--1.3 mm, these sintering zones appear as bright, optically thick rings with a spectral slope of \\(\\approx 2\\), whereas the non-sintering zones as darker, optically thinner rings of a spectral slope of \\(\\approx\\) 2.3--2.5. The observational features of the sintering and non-sintering zones are consistent with those of the major bright and dark rings found in the HL Tau disk, respectively. Radial pileup and vertical settling occur simultaneously if disk turbulence is weak and if monomers constituting the aggregates are \\(\\sim 1~{\\rm \\mu m}\\) in radius. For the radial gas temperature profile of \\(T = 310(r/1~{\\rm AU})^{-0.57}~{\\rm K}\\), our model perfectly reproduces the brightness temperatures of the optically thick bright rings, and reproduces their orbital distances to an accuracy of \\(\\lesssim\\) 30%.

I have proposed a measure for the cage effect in glass forming systems. A binary mixture of hard disks is numerically studied as a model glass former. A network is constructed on the basis of the colliding pairs of disks. A rigidity matrix is formed from the isostatic (rigid) sub--network, corresponding to a cage. The determinant of the matrix changes its sign when an uncaging event occurs. Time evolution of the number of the uncaging events is determined numerically. I have found that there is a gap in the uncaging timescales between the cages involving different numbers of disks. Caging of one disk by two neighboring disks sustains for a longer time as compared with other cages involving more than one disk. This gap causes two--step relaxation of this system.