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result(s) for
"Socha, Robert P."
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Development of a Multi-Bed Catalytic Heat Generator Utilizing a Palladium-Based Hydrogen Combustion System
by
Mordarski, Grzegorz
,
Skowron, Konrad
,
Socha, Robert P.
in
Analysis
,
catalytic reactor
,
Ceramic fibers
2025
The growing demand for sustainable energy solutions requires the development of safe and efficient systems for hydrogen utilization. Hydrogen, with its high energy density and clean combustion characteristics, has become a promising alternative for heating applications. However, conventional combustion technologies often suffer from inefficiencies and safety concerns, such as NOx emissions and explosion risks. To address these challenges, this study aimed to design and evaluate a catalytic heat generator utilizing hydrogen–air mixtures under controlled conditions to eliminate the need for pure oxygen and mitigate associated risks. A single-bed catalytic system was developed using palladium-based catalysts supported on ceramic fibers, followed by its heating, activation, and further characterization using the SEM-EDS technique. A multi-bed generator was later constructed to enhance scalability and performance. Thermal imaging and temperature monitoring were employed to optimize activation processes and assess system performance under varying hydrogen flow rates. The experimental results demonstrated efficient heat transfer and operational stability.
Journal Article
Adsorption of Au(III), Pt(IV), Pd(II), and Rh(III) ions on activated carbon in a batch reactor supported by microwave radiation
by
Hessel, Volker
,
Kowalik, Remigiusz
,
Wojtaszek, Konrad
in
Activated carbon
,
Adsorbents
,
Adsorption
2025
This study investigates the simultaneous recovery of noble metal ions using commercially available activated carbon (AC). Adsorption was carried out in a closed batch reactor enhanced by microwave radiation, creating high-pressure and high-temperature conditions. The effects of AC mass, process time, temperature, pH, and ionic strength of the solution were examined. High-temperature, high-pressure, and microwave radiation proved to be effective means of chemical activation, resulting in nearly 100% adsorption efficiency. It is proposed that microwave radiation significantly increases the local temperature at the surface of activated carbon, altering the adsorption mechanism. This enhancement led to higher recovery yields compared to traditional batch reactors without microwave support. The results demonstrate the significant potential of this method for efficient metal recovery.
Journal Article
The Impacts of Crystalline Structure and Different Surface Functional Groups on Drug Release and the Osseointegration Process of Nanostructured TiO2
by
Sulka, Grzegorz D.
,
Socha, Robert P.
,
Jarosz, Magdalena
in
cell response
,
heat treatment
,
silane derivatives
2021
In implantable materials, surface topography and chemistry are the most important in the effective osseointegration and interaction with drug molecules. Therefore, structural and surface modifications of nanostructured titanium dioxide (TiO2) layers are reported in the present work. In particular, the modification of annealed TiO2 samples with —OH groups and silane derivatives, confirmed by X-ray photoelectron spectroscopy, is shown. Moreover, the ibuprofen release process was studied regarding the desorption-desorption-diffusion (DDD) kinetic model. The results proved that the most significant impact on the release profile is annealing, and further surface modifications did not change its kinetics. Additionally, the cell adhesion and proliferation were examined based on the MTS test and immunofluorescent staining. The obtained data showed that the proposed changes in the surface chemistry enhance the samples’ hydrophilicity. Moreover, improvements in the adhesion and proliferation of the MG-63 cells were observed.
Journal Article
The influence of dielectric permittivity of water on the shape of PtNPs synthesized in high-pressure high-temperature microwave reactor
by
Luty-Błocho, Magdalena
,
Hessel, Volker
,
Socha, Robert P.
in
639/925
,
639/925/357
,
639/925/357/354
2021
In this paper, a novel method for the synthesis of Pt nanoparticles (PtNPs) using a microwave autoclave reactor is proposed. For benchmarking, the obtained results are compared with the traditional, batch method. A novel process window is proposed, which is the application of high-temperature and high-pressure. The main finding is that this only brings advantage, when the ionic strength of the system is enough low. It is explained, that at high pressure and high temperature, water behaves like only a slightly polar solvent, approaching a subcritical state. This reduces the electrostatic stabilization of the particles. Moreover, a change in the Pt particle shape is observed under high pressure and temperature conditions, suggesting that additional physical–chemical processes are involved.
Journal Article
Gallium Nitride for Space Photovoltaics: Properties, Synthesis Methods, Device Architectures and Emerging Market Perspectives
by
Uss, Paweł
,
Kasza, Patryk
,
Putynkowski, Grzegorz
in
Atomic layer epitaxy
,
Atomic oxygen
,
Defects
2025
Gallium nitride (GaN) has emerged as one of the most promising wide-bandgap semiconductors for next-generation space photovoltaics. In contrast to conventional III–V compounds such as GaAs and InP, which are highly efficient under terrestrial conditions but suffer from radiation-induced degradation and thermal instability, GaN offers an exceptional combination of intrinsic material properties ideally suited for harsh orbital environments. Its wide bandgap, high thermal conductivity, and strong chemical stability contribute to superior resistance against high-energy protons, electrons, and atomic oxygen, while minimizing thermal fatigue under repeated cycling between extreme temperatures. Recent progress in epitaxial growth—spanning metal–organic chemical vapor deposition, molecular beam epitaxy, hydride vapor phase epitaxy, and atomic layer deposition—has enabled unprecedented control over film quality, defect densities, and heterointerface sharpness. At the device level, InGaN/GaN heterostructures, multiple quantum wells, and tandem architectures demonstrate outstanding potential for spectrum-tailored solar energy conversion, with modeling studies predicting efficiencies exceeding 40% under AM0 illumination. In this review article, the current state of knowledge on GaN materials and device architectures for space photovoltaics has been summarized, with emphasis placed on recent progress and persisting challenges. Particular focus has been given to defect management, doping strategies, and bandgap engineering approaches, which define the roadmap toward scalable and radiation-hardened GaN-based solar cells. With sustained interdisciplinary advances, GaN is anticipated to complement or even supersede traditional III–V photovoltaics in space, enabling lighter, more durable, and radiation-hard power systems for long-duration missions beyond Earth’s magnetosphere.
Journal Article
Analysis of Stability and Functionality of Coil and Piezoelectric Braille Modules Under Varying Temperature Conditions
2025
In this study, the performance and reliability of two different types of Braille modules, i.e., coil and piezoelectric, under varying temperature conditions were compared. The coil module works on the principle of electromagnetic forces generated by coils, while the piezoelectric module is based on the deformation of piezoelectric materials under electric voltage to move needles. The main purpose of this research was to discuss the stability and functionality of both modules within the temperature range from −30 °C to +50 °C. One thousand cycles of operation were conducted for each temperature step in 5 °C increments, focusing on the correctness of needle movement and system reliability. The results demonstrated that the piezoelectric module exhibited stable operation over the entire temperature range, while the coil module showed instabilities, such as self-jamming and overheating, above 20 °C. These problems were probably due to thermal expansion and reduced lubrication efficiency. These results underscore the piezoelectric module’s improved adaptation to high-temperature operation, making it a promising solution for applications requiring reliable operation under varying conditions.
Journal Article
The Mechanism of Phase Transfer Synthesis of Silver Nanoparticles Using a Fatty Amine as Extractant/Phase Transfer Agent
by
Hessel, Volker
,
Escribà i Gelonch, Marc
,
Wojtaszek, Konrad
in
Acetates
,
Aqueous solutions
,
Carbon
2023
The paper presents the research results on synthesizing silver nanoparticles in aqueous solutions and their extraction into the organic phase. Studies have shown that it is best to perform the extraction process using n-hexane > cyclohexane > toluene > chloroform > ethyl acetate. The results show a correlation between the dielectric constant of the organic phase and its ability to extract nanoparticles. The lower the dielectric constant is, the higher the extractability. The hydrodynamic radius of the silver nanoparticles changes after transfer to the organic phase, depending greatly on the organic phase used. The extraction mechanism is complex and multi-step. As the first step, the Ag nanoparticles are transferred to the phase boundary. As the second step, the octadecylamine (ODA) molecules adsorb on the silver nanoparticles (AgNPs) surface. The change in particle shape was also noted. This suggests that the interfacial processes are more complex than previously reported. Below the initial concentration of ODA 2 × 10−4 M, the formation of a third phase has been observed. In a one-stage experiment, the concentration of silver nanoparticles after transferring to the organic phase was increased 500 times in about 10 s. The role of the concentration of ODA, therefore, is not only a measure of the extraction efficiency and productivity but functions as an enabler to maintain favorable biphasic processing, which underlines the role of the solvent again.
Journal Article
Carbon Quantum Dots as Phosphors in LEDs: Perspectives and Limitations—A Critical Review of the Literature
2024
The enduring interest in carbon quantum dots (CQDs) as photoluminescent material arises from their significant advantages over inorganic quantum dots (QDs), such as low toxicity and biocompatibility, which enables their application in bioimaging and drug delivery. This review is focused on the use of CQDs for light emitting devices (LED) technology and provides a guide on how to synthesize CQDs that emit blue, green, and red light, which is necessary to produce RGB LEDs. Consideration was given to the precursors, solvents, methods, and conditions of the processes, the excitation wavelength, the emission wavelength, and the photoluminescence quantum yield (QY). These unique, organic nanoparticles have the potential to revolutionize lighting and, above all, the electronics market due to their low cost and eco-friendliness, as well as the possibility of using various precursors, including waste.
Journal Article
Nanoporous Anodic Aluminum-Iron Oxide with a Tunable Band Gap Formed on the FeAl3 Intermetallic Phase
2020
Nanostructured anodic oxide layers on an FeAl3 intermetallic alloy was prepared by two-step anodization in 20 wt.% H2SO4 at 0 °C. The obtained anodic oxide coating was subjected to phase and chemical composition analysis using XPS and XRD techniques. An analysis of the band gap of individual coatings was also performed. The applied parameters of the anodization process were determined, enabling the formation of a nanostructured coating on the FeAl3 intermetallic alloy. Tests were carried out on samples produced at a voltage between 10 V and 22.5 V in 2.5 V steps. The produced coatings were subjected to an annealing process at 900 °C for 2 h in an argon protective atmosphere. Moreover, the influence of the substrate chemical composition on the chemical and phase composition of the anodic oxide are discussed. Band gaps of 2.37 eV at 22.5 V and 2.64 eV at 10 V were obtained directly after the anodizing process. After applying the heat treatment, band gap values of 2.10 eV at 22.5 Vand 2.48 eV for the coating produced at 10 V were obtained.
Journal Article
Ambient Stability of Sodium-Doped Copper Oxide Obtained through Thermal Oxidation
2024
The ambient stability of copper oxide layers produced through thermal oxidation is a critical factor for their application in advanced photovoltaic devices. This study investigates the long-term stability of thermally grown sodium-doped copper oxides fabricated at 300 °C, 500 °C, and 700 °C. The structural, optical, and electronic properties of these oxide layers were examined after a 30-day period to understand how thermal oxidation temperature and sodium doping influence the durability and properties of copper oxide films. The results indicate that the stability of thermal copper oxide increases with oxidation temperature. The film produced at 700 °C maintained consistent optical properties, work function value, and structural integrity over time, demonstrating their robustness against environmental degradation. In contrast, the layers produced at lower temperatures (300 °C and 500 °C) showed more significant changes due to continued oxidation and adsorption from ambient.
Journal Article