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Understanding battery characteristic behaviors is indispensable in designing and managing large-scale battery-based energy storage systems in high-power applications. This paper presents a practical-based characterization method to model the ohmic series resistance of lithium-ion batteries under life-cycle consideration. Aging cells were prepared in a controlled environment, and the testing information was automatically characterized using a developed computer-based battery test system. An experimental methodology based on the cycling of pulse tests is applied for modeling the ohmic series resistance. Several aspects of the testing parameters during the cycling operations, such as the characteristic changes of the ohmic series resistance, amplitudes of the periodic test current, cell capacity, state of charge, and the rate of change of the resistance increment, are also investigated and analyzed so as to fulfill the resistance model. The accuracy of the proposed model is verified by comparing the testing information, showing a satisfactory result.

Open circuit voltage (OCV) of lithium batteries has been of interest since the battery management system (BMS) requires an accurate knowledge of the voltage characteristics of any Li-ion batteries. This article presents an OCV characteristic for lithium manganese oxide (LMO) batteries under several experimental operating conditions, and discusses factors for accurate OCV determination. A test system is developed for OCV characterization based on the OCV pulse test method. Various factors for the OCV behavior, such as resting period, step-size of the pulse test, testing current amplitude, hysteresis phenomena, and terminal voltage relationship, are investigated and evaluated. To this end, a general OCV model based on state of charge (SOC) tracking is developed and validated with satisfactory results.