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Neutral sodium was the first atom detected in an exoplanetary atmosphere via transmission spectroscopy and remains the most frequently detected species due to its strong doublet in the optical. However, the center-to-limb variation (CLV) of these lines in the host star can bias the Na detection.When combined with the Rossiter-McLaughlin (RM) effect, the CLV can mimic or obscure planetary absorption features. This work investigates the impact of 3D radiation hydrodynamic stellar atmospheres and non-local thermodynamic equilibrium (NLTE) radiative transfer on the modeling of the CLV+RM effect in single-line transmission spectroscopy, to improve the characterization of exoplanet atmospheres. We produced a grid of 3D NLTE synthetic spectra for Na I for FGK stars within the following parameter space: Teff=4500-6500 K, log g=4.0-5.0 and [Fe/H]=-0.5, 0, 0.5.This grid was then interpolated to match the stellar parameters of four stars hosting giant exoplanets, to correct for the CLV+RM effect in their transmission spectra. We used ESPRESSO archival observations. Our work confirms the Na detections in three systems, namely WASP-52b, WASP-76b, and WASP-127b, improving the accuracy of the measured absorption depth. Furthermore, we find that 3D NLTE stellar models can explain the spectral features in HD 209458b without the need for any planetary absorption. In the grid of synthetic spectra, we observe that the CLV effect is stronger for stars with low Teff and high log g. However, the combined effect of CLV and RM is highly dependent on the orbital geometry of the planet-star system. With the continuous improvement of instrumentation, it is crucial to use the most accurate stellar models to correct for the CLV+RM effect in high-resolution transmission spectra, to achieve the best possible characterization of exoplanet atmospheres. We make our grid of 3D NLTE spectra for Na publicly available.

With a mass, radius, and mean density similar to Earth's, the rocky planet GJ 1132 b is the first truly small planet for which an atmosphere detection was proposed. If confirmed, ultra-reduced magma outgassing is the only mechanism capable of producing HCN and H\\(_2\\)O in large enough quantities to match the HST observations. The proposed atmosphere detection, however was challenged by reanalysis of the same HST data by different teams. Recent JWST observations returned ambiguous results due to the unaccounted for variability seen between two different visits. Here we report the analysis of three CRIRES+ transit observations of GJ 1132 b in order to determine the presence or absence of He I, HCN, CH\\(_4\\), and H\\(_2\\)O in its atmosphere. We are unable to detect the presence of any of these species in the atmosphere of GJ 1132 b assuming a clear, H\\(_2\\)-dominated atmosphere, although we can place upper limits for the volume mixing ratios of CH\\(_4\\), HCN, and H\\(_2\\)O using injections tests and atmospheric retrievals. These retrieved upper limits show the capability of CRIRES+ to detecting chemical species in rocky exoplanets, if the atmosphere is H\\(_2\\) dominated. The detection of the atmospheres of small planets with high mean molecular weight, and the capability to distinguish between the variability introduced by stellar activity and/or the planetary atmosphere will require high-resolution spectrographs in the upcoming extremely large telescopes.

Ultra-hot Jupiters (UHJs) are gas giant planets orbiting close to their host star, with equilibrium temperatures exceeding 2000 K, and among the most studied planets in terms of their atmospheric composition. Thanks to a new generation of ultra-stable high-resolution spectrographs, it is possible to detect the signal from the individual lines of the species in the exoplanetary atmospheres. We employed two techniques in this study. First, we used transmission spectroscopy, which involved examining the spectra around single lines of FeII. Then we carried out a set of cross-correlation studies for two UHJs: KELT-9b and KELT-20b. Both planets orbit fast-rotating stars, which resulted in the detection of the strong Rossiter-McLaughlin (RM) effect and center-to-limb variations in the transmission spectrum. These effects had to be corrected to ensure a precise analysis. Using the transmission spectroscopy method, we detected 21 single lines of FeII in the atmosphere of KELT-9b. All of the detected lines are blue-shifted, suggesting strong day-to-night side atmospheric winds. The cross-correlation method leads to the detection of the blue-shifted signal with a signal-to-noise ratio (S/N) of 13.46. Our results are in agreement with models based on non-local thermodynamical equilibrium (NLTE) effects, with a mean micro-turbulence of nu_mic = 2.73 +/- 1.5 km/s and macro-turbulence of nu_mac = 8.22 +/- 3.85 km/s. In the atmosphere of KELT-20b, we detected 17 single lines of FeII. Considering different measurements of the systemic velocity of the system, we conclude that the existence of winds in the atmosphere of KELT-20b cannot be determined conclusively. The detected signal with the cross-correlation method presents a S/N of 11.51. The results are consistent with NLTE effects, including means of nu_mic = 3.04 +/- 0.35 km/s and nu_mac = 6.76 +/- 1.17 km/s.

Ultra-hot jupiters (UHJs) are giant planets on short orbital periods with high equilibrium temperature (T_eq) values. Their hot, extended atmospheres are perfect laboratories for transmission spectroscopy studies based on high-resolution spectrographs. In recent years, a variety of atoms and molecules were found in their atmospheres, using different methods such as cross-correlation or transmission and emission spectroscopy. Here, we present the studies of six ultra-hot Jupiters: HAT-P-57b, KELT-7b, KELT-17b, KELT-21b, MASCARA-1b, and WASP-189b, based on high-resolution observations obtained with HARPS-N and HARPS spectrographs. By applying line and cross-correlation transmission spectroscopy methods, we searched for the absorption features of a broad range of atomic and molecular species. We did not detect any absorption features in our sample of UHJs, with the exception of WASP-189b, for which we detected FeI, FeII, and TiI using cross-correlation. The transmission spectroscopy of single lines for WASP-189b revealed several absorption features (including Halpha, Hbeta and Ca H&K), but they remain tentative pending a better modelling of the gravity darkening deformation of the Rossiter-McLaughlin effect. The non-detections with regard to the rest of the planets can be explained via a combination of stellar pulsations and the Rossiter-McLaughlin effect, which mask possible planetary signals for most of the planets, and by the low signal-to-noise ratios (S/N) of the observations for KELT-21b. Here, we compare our results with the known population of planets for which atmospheric detections have been reported in the literature. We find that the empirical frontier between hot and ultra-hot planets, based on the detection of atomic and ionized species in their atmospheres, can be established as Teq = 2150 K.

Atmospheric characterization is key to understanding exoplanetary systems, offering insights into the planets current and past conditions. By analyzing key lines like H alpha and the He I triplet, we can trace the evolution of planets through atmospheric photo-evaporation. While ultra-hot Jupiters have been the focus for years, attention is shifting toward smaller, colder planets, which are more challenging to study due to weaker signals, requiring more precise techniques. This study aims to characterize the atmosphere of TOI-5398 b, a warm Saturn with a 10.59-day orbit around a young (650 Myr) G-type star. The system also hosts a smaller inner planet, TOI-5398 c, with a 4.77-day orbit. Both planets are ideal for atmospheric studies due to their proximity to the host star, which drives strong photo-evaporation, especially in planet b, whose high transmission spectroscopy metric (288) makes it a prime target. We analyzed data from a transit observed with the HARPS-N and GIANO-B high-resolution spectrographs, using cross-correlation and single-line analysis to search for atomic species. During this observation, planet c was also transiting, so we investigated the source of the signals. Based on photo-evaporation models, we attribute the signal mainly to planet b, which is expected to lose more mass. We detected H alpha and He I triplets, key markers of photo-evaporation, corresponding to atmospheric heights of 2.33 Rp and 1.65 Rp, respectively. The ATES models supported our observations, predicting a similar He I absorption for planet b and suggesting an He/H ratio of 1/99. Additionally, we detected an Na I doublet via single-line analysis, though cross-correlation did not reveal other atomic species.

We analysed six primary transits of the ultra-hot Jupiter KELT-9,b obtained with the HARPS-N high-resolution spectrograph in the context of the Global Architecture of Planetary Systems (GAPS2) project, to characterise the atmosphere via single-line analysis. We extracted the transmission spectrum of each individual line by comparing the master out-of-transit spectrum with the in-transit spectra and computing the weighted average of the tomography in the planet reference frame. We corrected for the centre-to-limb variation and the Rossiter-McLaughlin effect by modelling the region of the star disc obscured by the planet during the transit and subtracting it from the master-out spectrum. We detected all six observable lines of the Balmer series within the HARPS-N wavelength range, from H\\(\\alpha\\) to H\\(\\zeta\\), with a significance exceeding 5\\(\\sigma\\). We focussed on metal species, detecting Na I, Ca I, Ca II, Fe I, Fe II, Mg I, Ti II, Sc II, and Cr II lines. This is the first detection in the atmosphere of an exoplanet of H\\(\\epsilon\\) and H\\(\\zeta\\) lines, as well as of individual lines of Sc II and Cr II. Our detections are supported by a comparison with published synthetic transmission spectra of KELT-9b obtained accounting for non-local thermodynamic equilibrium effects. The results underline the presence of a systematic blueshift due to night-side to day-side winds. The single-line analysis allowed us not only to assess the presence of atomic species in the atmosphere of KELT-9 b, but also to further characterise the local stratification of the atmosphere. Coupling the height distribution of the detected species with the velocity shift retrieved, we acknowledged the height distribution of night-side to day-side winds. Moreover, the study of the rotational broadening of different species supports the prediction of a tidally locked planet rotating as a rigid body.

HAT-P-67 b is one of the lowest-density gas giants known to date, making it an excellent target for atmospheric characterization through the transmission spectroscopy technique. In the framework of the GAPS large programme, we collected four transit events, with the aim of studying the exoplanet atmosphere and deriving the orbital projected obliquity. We exploited the high-precision GIARPS observing mode of the TNG, along with additional archival TESS photometry, to explore the activity level of the host star. We performed transmission spectroscopy, both in the VIS and in the nIR wavelength range, and analysed the RML effect both fitting the RVs and the Doppler shadow. Based on the TESS photometry, we redetermined the transit parameters of HAT-P-67 b. By modelling the RML effect, we derived a sky-projected obliquity of (\\(2.20.4\\)) indicating an aligned planetary orbit. The chromospheric activity index \\(\\,R^_ HK\\), the CCF profile, and the variability in the transmission spectrum of the H\\(\\) line suggest that the host star shows signatures of stellar activity and/or pulsations. We found no evidence of atomic or molecular species in the VIS transmission spectra, with the exception of pseudo-signals corresponding to Cr I, Fe I, H\\(\\), Na I, and Ti I. In the nIR range, we found an absorption signal of the He I triplet of 5.56\\(^+0.29_-0.30\\)%(19.0\\(\\)), corresponding to an effective planetary radius of \\(\\)3\\(R_p\\) (where \\(R_p\\)2\\(R_J\\)) which extends beyond the planet's Roche Lobe radius. Owing to the stellar variability, together with the high uncertainty of the model, we could not confirm the planetary origin of the signals found in the optical transmission spectrum. On the other hand, we confirmed previous detections of the infrared He I triplet, providing a 19.0\\(\\) detection. Our finding indicates that the planet's atmosphere is evaporating.

Ultra-hot Jupiters (UHJs) are expected to possess temperature inversion layers in their dayside atmospheres. Recent thermal emission observations have discovered several atomic and molecular species along with temperature inversions in UHJs. We observed the thermal emission spectra of two UHJs (WASP-33b and WASP-189b) with the GIANO-B high-resolution near-infrared spectrograph. Using the cross-correlation technique, we detected carbon monoxide (CO) in the dayside atmospheres of both planets. The detected CO lines are in emission, which agrees with previous discoveries of iron emission lines and temperature inversions in the two planets. This is the first detection of CO lines in emission with high-resolution spectroscopy. Further retrieval work combining the CO lines with other spectral features will enable a comprehensive understanding of the atmospheric properties such as temperature structures and C/O ratios. The detected CO and iron emission lines of WASP-189b have redshifted radial velocities of several km/s, which likely originate from a dayside to nightside wind in its atmosphere. Such a redshifted velocity has not been detected for the emission lines of WASP-33b, suggesting that the atmospheric circulation patterns of the two UHJs may be different.

The atmospheric characterisation of hot and warm Neptune-size exoplanets is challenging due to their small radius and atmospheric scale height. The warm-Neptune HAT-P-11b is a remarkable target for such characterisation due to the large brightness of its host star (V=9.46 mag; H=7.13 mag). The aims of this work are to review the main physical and architectural properties of the HAT-P-11 planetary system, and to probe the presence of 8 molecular species in the atmosphere of HAT-P-11b at high spectral resolution in the near-infrared. The planetary system was reviewed by analysing transits and occultations of HAT-P-11b from the Kepler data set as well as HIRES at Keck archival radial-velocity (RV) data. We modelled the latter with Gaussian-process regression and a combined quasi-periodic and squared-exponential kernel to account for stellar variations on both (short-term) rotation and (long-term) activity-cycle timescales. In order to probe the atmospheric composition of HAT-P-11b, we observed 4 transits of this target with GIANO-B at TNG. We find that the long-period (\\(P\\sim9.3\\) years) RV signal previously attributed to planet HAT-P-11c is more likely due to the stellar magnetic activity cycle. Nonetheless, the Hipparcos-Gaia difference in the proper-motion anomaly suggests that an outer-bound companion might still exist. For HAT-P-11b, we measure a radius \\(R_{\\rm p}=0.4466\\pm0.0059\\,R_{\\rm J}\\), a mass \\(M_{\\rm p}=0.0787\\pm0.0048\\,M_{\\rm J}\\), and an eccentricity \\(e=0.2577^{+0.0033}_{-0.0025}\\), in accordance with values in the literature. Probing its atmosphere, we detect \\(NH_3\\) (S/N\\(=5.3\\), significance\\(=5.0\\sigma\\)) and confirm the presence of \\(H_2O\\) (S/N\\(=5.1\\), significance\\(=3.4\\sigma\\)). We also tentatively detect the signal of \\(CO_2\\) (S/N\\(=3.0\\), significance\\(=3.2\\sigma\\)) and \\(CH_4\\) (S/N\\(=4.8\\), significance\\(=2.6\\sigma\\)), whose presence need to be confirmed by further observations.

We search for atmospheric constituents for the UHJ WASP-178 b with two ESPRESSO transits using the narrow-band and cross-correlation techniques, focusing on the detections of NaI, H\\(\\alpha\\), H\\(\\beta\\), H\\(\\gamma\\), MgI, FeI and FeII. Additionally, we show parallel photometry used to obtain updated and precise stellar, planetary and orbital parameters. We report the resolved line detections of NaI (5.5 and 5.4 \\(\\sigma\\)), H\\(\\alpha\\) (13 \\(\\sigma\\)), H\\(\\beta\\) (7.1 \\(\\sigma\\)), and tentatively MgI (4.6 \\(\\sigma\\)). In cross-correlation, we confirm the MgI detection (7.8 and 5.8 \\(\\sigma\\)) and additionally report the detections of FeI (12 and 10 \\(\\sigma\\)) and FeII (11 and 8.4 \\(\\sigma\\)), on both nights separately. The detection of MgI remains tentative, however, due to the differing results between both nights, as well as compared with the narrow-band derived properties. None of our resolved spectral lines probing the mid- to upper atmosphere show significant shifts relative to the planetary rest frame, however H\\(\\alpha\\) and H\\(\\beta\\) exhibit line broadenings of 39.6 \\(\\pm\\) 2.1 km/s and 27.6 \\(\\pm\\) 4.6 km/s, respectively, indicating the onset of possible escape. WASP-178 b differs from similar UHJ with its lack of strong atmospheric dynamics in the upper atmosphere, however the broadening seen for FeI (15.66 \\(\\pm\\) 0.58 km/s) and FeII (11.32 \\(\\pm\\) 0.52 km/s) could indicate the presence of winds in the mid-atmosphere. Future studies on the impact of the flux variability caused by the host star activity might shed more light on the subject. Previous work indicated the presence of SiO cloud-precursors in the atmosphere of WASP-178 b and a lack of MgI and FeII. However, our results suggest that a scenario where the planetary atmosphere is dominated by MgI and FeII is more likely. In light of our results, we encourage future observations to further elucidate these atmospheric properties.