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Comprehensive pyrolysis models that are integral to computational fire codes have improved significantly over the past decade as the demand for improved predictive capabilities has increased. High fidelity pyrolysis models may improve the design of engineered materials for better fire response, the design of the built environment, and may be used in forensic investigations of fire events. A major limitation to widespread use of comprehensive pyrolysis models is the large number of parameters required to fully define a material and the lack of effective methodologies for measurement of these parameters, especially for complex materials. The work presented here details a methodology used to characterize the pyrolysis of a low-pile carpet tile, an engineered composite material that is common in commercial and institutional occupancies. The studied material includes three distinct layers of varying composition and physical structure. The methodology utilized a comprehensive pyrolysis model (ThermaKin) to conduct inverse analyses on data collected through several experimental techniques. Each layer of the composite was individually parameterized to identify its contribution to the overall response of the composite. The set of properties measured to define the carpet composite were validated against mass loss rate curves collected at conditions outside the range of calibration conditions to demonstrate the predictive capabilities of the model. The mean error between the predicted curve and the mean experimental mass loss rate curve was calculated as approximately 20% on average for heat fluxes ranging from 30 to 70 kW·m−2, which is within the mean experimental uncertainty.

This work details a methodology for parameterization of the kinetics and thermodynamics of the thermal decomposition of polymers blended with reactive additives. This methodology employs Thermogravimetric Analysis, Differential Scanning Calorimetry, Microscale Combustion Calorimetry, and inverse numerical modeling of these experiments. Blends of glass-fiber-reinforced polybutylene terephthalate (PBT) with aluminum diethyl phosphinate and melamine polyphosphate were used to demonstrate this methodology. These additives represent a potent solution for imparting flame retardancy to PBT. The resulting lumped-species reaction model consisted of a set of first- and second-order (two-component) reactions that defined the rate of gaseous pyrolyzate production. The heats of reaction, heat capacities of the condensed-phase reactants and products, and heats of combustion of the gaseous products were also determined. The model was shown to reproduce all aforementioned experiments with a high degree of detail. The model also captured changes in the material behavior with changes in the additive concentrations. Second-order reactions between the material constituents were found to be necessary to reproduce these changes successfully. The development of such models is an essential milestone toward the intelligent design of flame retardant materials and solid fuels.

The effectiveness of suppression of lithium ion battery, LIB, fires with water mist was investigated experimentally using a previously developed bench-scale wind tunnel. The experiments were conducted on lithium ion cell arrays constructed from twelve cylindrical (18,650 form factor), fully charged, lithium cobalt oxide cells, which were densely packed in a rectangular configuration without gaps. An electric heater was employed to initiate thermal runaway in one cell. Failure propagation was then tracked using thermocouples located at the bottom surfaces of the cells. Heat release due to flaming combustion was computed based on the oxygen consumption method. Experiments conducted at 640 l min−1 of air, 320 l min−1 of air, and 186 l min−1 of nitrogen tunnel purge flow were used as reference points. All reference point experiments underwent complete cascading failure. Addition of 1.0 and 1.6 g s−1 of water mist to 320 and 640 l min−1 of air produced agent concentrations of 14.1 and 11.1 wt%, respectively, which are slightly above the concentration of water mist recommended for suppression of traditional fires. Application of water mist at 1.0 and 1.6 g s−1 prevented cascading failure in 40% and 50% of the tests, respectively, and significantly reduced the rate of failure propagation in the other tests. At both water mist delivery rates, flaming combustion associated with burning of battery ejecta was inhibited, reducing the combustion efficiency below 50%. One of the key findings of this study is that suppression of flaming combustion is not sufficient to stop cascading failure. The array must be continually cooled with water mist until the temperature of the cells decreases below a certain threshold, which prevents chemical reactions between battery materials inside the cell casings.

A methodology for parameterization of pyrolysis models for polymeric solids is proposed. This methodology is based on a series of experiments including thermogravimetric analysis, differential scanning calorimetry, infrared radiation absorption measurement and controlled atmosphere, radiation-driven gasification experiments involving simultaneous sample mass and temperature monitoring. These experiments are interpreted using a transient pyrolysis model run in an infinitely fast (0D) and one-dimensional (1D) transport modes to derive a complete property set. This property set is subsequently validated by comparing the mass loss rate histories obtained from the gasification experiments to the model predictions. For a range of previously studied materials, these predictions were found to be, on average, within 10 to 20% of the experimental values. This manuscript provides an overview of this methodology, accompanied by examples of its application, identifies its imitations and suggests paths for future development.

Polyisocyanurate (PIR) foam is a robust thermal insulation material utilized widely in the modern construction. In this work, the flammability of one representative example of this material was studied systematically using experiments and modeling. The thermal decomposition of this material was analyzed through thermogravimetric analysis, differential scanning calorimetry, and microscale combustion calorimetry. The thermal transport properties of the pyrolyzing foam were evaluated using Controlled Atmosphere Pyrolysis Apparatus II experiments. Cone calorimetry tests were also carried out on the foam samples to quantify the contribution of the blowing agent (contained within the foam) to its flammability, which was found to be significant. A complete pyrolysis property set was developed and was shown to accurately predict the results of all aforementioned measurements. The foam was also subjected to full-scale flame spread tests, similar to the Single Burning Item test. A previously developed modeling approach based on a coupling between detailed pyrolysis simulations and a spatially-resolved relationship between the total heat release rate and heat feedback from the flame, derived from the experiments on a different material in the same experimental setup, was found to successfully predict the evolution of the heat release rate measured in the full-scale tests on the PIR foam.

A previous study of poly(arylether-ether-ketone) showed that the ignitability of this high temperature engineering plastic is sensitive to the presence of absorbed moisture. The present research extends this work to include five other engineering plastics: polycarbonate, polyoxymethylene, polymethylmethacrylate, polyphenylsulfone and polyhexamethyleneadipamide (PC, POM, PMMA, PPSU and PA66 respectively). Separate batches of each polymer were equilibrated in hot (80°C) water, 50% relative humidity at 20°C, or vacuum dried at 100°C and tested in a cone calorimeter at heat fluxes between 10 kW/m 2 and 75 kW/m 2 . These hygrothermally-conditioned samples were also examined by microscale combustion calorimetry to determine the effect of moisture on the thermal, decomposition, and combustion properties. It was found that absorbed moisture did not change the thermal decomposition or ignition temperatures significantly, but was released as steam that formed microscopic surface bubbles at or above the softening (glass transition or melting) temperature of the polymer. The phase change from bound water to steam entrained in the polymer melt (foam) significantly reduced the ignition time compared to dry samples. Attempts were made to account for the moisture-sensitive ignition delay in terms of thermal properties, chemical processes governing ignition, and a numerical pyrolysis model.

The authors wish to make the following corrections to this manuscript [1]. During the publishing process, symbols that represented the absorption coefficient in Table 4 and thermal conductivity in Table 5 were changed such that they were inconsistent with the rest of the manuscript. [...]

Recent research has shown that acoustics can be used to suppress flames from a liquid fuel source. The results of these experiments indicated that acoustics alone are insufficient to control flames beyond the incipient stage. Recent research has also shown that variations in the delivery of water mist to a fire can enhance the mist’s efficiency. Therefore, the addition of acoustics to water mist may be an effective means of enhancing an established fire protection technology. For the first time, acoustics and water mist have been combined and studied as a flame suppression strategy. A series of experiments were conducted that explored the potential for coupling acoustics with water mist as means of flame suppression. Heptane fueled flames were created from two different sized ceramic fiber wicks: 30 mm × 50 mm with 5 mL of fuel, and 60 mm × 100 mm with 20 mL of fuel. The flames were then exposed to water mist delivered at a constant rate, which was found to be incapable of suppressing the flames. Next, low frequency sound waves at 62 Hz and 80 Hz were used to suppress flames from both wicks, with each frequency being generated by a different resonator. Finally, acoustics from both resonators were combined with water mist, and used to suppress flames from both wicks. The results showed that a combination of acoustic waves and water mist suppressed the flames more effectively than each individual technique on its own. This finding opens the possibility of developing more efficient ways to use water mist technology.