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The Baltic Sea is an intra-continental marginal sea that is vertically stratified with a strong halocline isolating the saline bottom layer from the brackish surface layer. The surface layer is eutrophic, and abiotic zones lacking oxygen are common in the deeper regions. While freshwater is constantly flowing into the North Sea, oxygen-rich bottom waters can only occasionally enter the Baltic Sea following a special sequence of transient weather conditions. These so-called Major Baltic Inflow events can be monitored via the sea level gradients between the Kattegat and the Western Baltic Sea. Innovative interferometric altimetry from the Surface Water and Ocean Topography (SWOT) mission gave us the first opportunity to directly observe the sea level signal associated with the inflow event in December 2023. Recent high-rate multi-mission nadir altimetry observations support the SWOT findings for scales larger than 50 km. The SWOT observations are compared to the simulations with the regional 3D HBMnoku ocean circulation model operated by the German Federal Maritime and Hydrographic Agency (BSH). The model explains more than 80% of the variance observed by SWOT and up to 90% of the variance observed by the nadir altimeters. However, the north–south gradients of the two datasets differ by about 10% of the overall gradient. Comparisons with tide gauges suggest possible model deficiencies on daily to sub-daily time scales. In addition, the SWOT data have many fine scale structures, such as eddies and fronts, which cannot be adequately modeled.

Time-variable gravity field models derived from observations of the Gravity Recovery and Climate Experiment (GRACE) mission, whose science operations phase ended in June 2017 after more than 15 years, enabled a multitude of studies of Earth’s surface mass transport processes and climate change. The German Research Centre for Geosciences (GFZ), routinely processing such monthly gravity fields as part of the GRACE Science Data System, has reprocessed the complete GRACE mission and released an improved GFZ GRACE RL06 monthly gravity field time series. This study provides an insight into the processing strategy of GFZ RL06 which has been considerably changed with respect to previous GFZ GRACE releases, and modifications relative to the precursor GFZ RL05a are described. The quality of the RL06 gravity field models is analyzed and discussed both in the spectral and spatial domain in comparison to the RL05a time series. All results indicate significant improvements of about 40% in terms of reduced noise. It is also shown that the GFZ RL06 time series is a step forward in terms of consistency, and that errors of the gravity field coefficients are more realistic. These findings are confirmed as well by independent validation of the monthly GRACE models, as done in this work by means of ocean bottom pressure in situ observations and orbit tests with the GOCE satellite. Thus, the GFZ GRACE RL06 time series allows for a better quantification of mass changes in the Earth system.

To mitigate temporal aliasing effects in monthly mean global gravity fields from the GRACE and GRACE‐FO satellite tandem missions, both tidal and non‐tidal background models describing high‐frequency mass variability in atmosphere and oceans are needed. To quantify tides in the atmosphere, we exploit the higher spatial (31 km) and temporal (1 hr) resolution provided by the latest atmospheric ECMWF reanalysis, ERA5. The oceanic response to atmospheric tides is subsequently modeled with the general ocean circulation model MPIOM (in a recently revised TP10L40 configuration that includes the feedback of self‐attraction and loading to the momentum equations and has an improved bathymetry around Antarctica) as well as the shallow water model TiME (employing a much higher spatial resolution and more elaborate tidal dissipation than MPIOM). Both ocean models consider jointly the effects of atmospheric pressure variations and surface wind stress. We present the characteristics of 16 waves beating at frequencies in the 1–6 cpd band and find that TiME typically outperforms the corresponding results from MPIOM and also FES2014b as measured from comparisons with tide gauge data. Moreover, we note improvements in GRACE‐FO laser ranging interferometer range‐acceleration pre‐fit residuals when employing the ocean tide solutions from TiME, in particular, for the S1 spectral line with most notable improvements around Australia, India, and the northern part of South America. Plain Language Summary In addition to many rather slow processes such as the melting of glaciers, rapid mass redistribution related to the weather also measurably affect the Earth's gravity field. The ability of monitoring liquid freshwater changes within the Earth system from the satellite gravity missions GRACE (2002–2017) and GRACE‐FO (since 2018) relies on accurate background models of mass variability in atmosphere and oceans for both tidal and non‐tidal processes. Atmospheric tides are primarily excited in the middle atmosphere by solar energy absorption at periods of 24 hr and its overtones. We find additional tidal signatures in the atmosphere excited by periodic deformations of both crust and sea‐surface of the Earth. We thus introduce here a new data set for the atmospheric tides and their corresponding oceanic response that features both more waves and higher accuracy than other background models previously used for the processing of GRACE and GRACE‐FO satellite gravimetry data. Key Points Sixteen relevant tidal lines identified in hourly data from ERA5 atmospheric reanalysis Dedicated simulations with a high‐resolution global hydrodynamic model to simulate ocean tides with atmospheric influence New tidal models reduce pre‐fit residuals in GRACE‐FO Laser Ranging Interferometer data

Satellite altimetry observations have provided a significant contribution to the understanding of global sea surface processes, particularly allowing for advances in the accuracy of ocean tide estimations. Currently, almost three decades of satellite altimetry are available which can be used to improve the understanding of ocean tides by allowing for the estimation of an increased number of minor tidal constituents. As ocean tide models continue to improve, especially in the coastal region, these minor tides become increasingly important. Generally, admittance theory is used by most global ocean tide models to infer several minor tides from the major tides when creating the tidal correction for satellite altimetry. In this paper, regional studies are conducted to compare the use of admittance theory to direct estimations of minor tides from the EOT20 model to identify which minor tides should be directly estimated and which should be inferred. The results of these two approaches are compared to two global tide models (TiME and FES2014) and in situ tide gauge observations. The analysis showed that of the eight tidal constituents studied, half should be inferred (2N2, ϵ2, MSF and T2), while the remaining four tides (J1, L2, μ2 and ν2) should be directly estimated to optimise the ocean tidal correction. Furthermore, for certain minor tides, the other two tide models produced better results than the EOT model, suggesting that improvements can be made to the tidal correction made by EOT when incorporating tides from the two other tide models. Following on from this, a new approach of merging tidal constituents from different tide models to produce the ocean tidal correction for satellite altimetry that benefits from the strengths of the respective models is presented. This analysis showed that the tidal correction created based on the recommendations of the tide gauge analysis provided the highest reduction of sea-level variance. Additionally, the combination of the EOT20 model with the minor tides of the TiME and FES2014 model did not significantly increase the sea-level variance. As several additional minor tidal constituents are available from the TiME model, this opens the door for further investigations into including these minor tides and optimising the tidal correction for improved studies of the sea surface from satellite altimetry and in other applications, such as gravity field modelling.

Monthly gravity field recovery using data from the GRACE and GRACE Follow‐On missions includes errors limiting the spatial and temporal resolution of the estimated gravity fields. The major error contributions, besides the noise of the accelerometer instruments, arise from temporal aliasing errors due to imperfections in the non‐tidal atmospheric and oceanic de‐aliasing models and ocean tide models. We derive uncertainty information for the eight major tidal constituents from five different ocean tide models and introduce it into the gravity field recovery process in terms of a constrained normal equation system while expanding the parameter space by additional tidal parameters to be adjusted. We prove the effectiveness of the ocean tide variance‐covariance information through realistic simulations and we assess its potential based on microwave and laser interferometer observations from the GRACE Follow‐On mission. We show that errors are reduced by more than 20% ocean wRMS for a Gaussian filter radius of 300 km if uncertainty information for ocean tides is considered and stochastic modeling of instrument errors is applied, compared to the latest GFZ release 6.1. Our results also show the limited visibility of the effectiveness of the ocean tide variance‐covariance information due to the dominating error contribution of non‐tidal atmospheric and oceanic mass variations. Additionally, we investigate the option of estimating ocean tide parameters over a 1‐year period while including ocean tide uncertainty information in order to improve ocean tide background modeling. Key Points Application of variance‐covariance information from ocean tide models in Level‐2 satellite gravity field processing Reduction of temporal aliasing errors due to ocean tides in time‐varying gravity field solutions Estimation of ocean tide parameters for an improved ocean tide background modeling

We study optical pulse propagation through a hollow-core fiber filled with a radially inhomogeneous cloud of cold atoms. A co-propagating control field establishes electromagnetically induced transparency. In analogy to a graded index fiber, the pulse experiences micro-lensing and the transmission spectrum becomes distorted. Based on a two-layer model of the complex index of refraction, we can analytically understand the cause of the aberration, which is corroborated by numerical simulations for a radial Gaussian-shaped function. With these insights, we show that the spectral distortions can be rectified by choosing an optimal detuning from one-photon resonance.

The selective introduction of amine groups within deconstruction products of lignin could provide an avenue for valorizing waste biomass while achieving a green synthesis of industrially relevant building blocks from sustainable sources. Here, we built and characterized enzyme cascades that create aldehydes and subsequently primary amines from diverse lignin-derived carboxylic acids using a carboxylic acid reductase (CAR) and an ω-transaminase (TA). Unlike previous studies that have paired CAR and TA enzymes, here we examine multiple homologs of each of these enzymes and a broader set of candidate substrates. In addition, we compare the performance of these systems in cell-free and resting whole-cell biocatalysis formats using the conversion of vanillate to vanillyl amine as model chemistry. We also demonstrate that resting whole cells can be recycled for multiple batch reactions. We used the knowledge gained from this study to produce several amines from carboxylic acid precursors using one-pot biocatalytic reactions, several of which we report for the first time. These results expand our knowledge of these industrially relevant enzyme families to new substrates and contexts for environmentally friendly and potentially low-cost synthesis of diverse aryl aldehydes and amines.