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8 result(s) for "Szewczenko, Wiktor"
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Designing a Universal Glass Composite for Plaster Mortars
Currently, construction uses a vast array of materials that, while serving the same purpose, differ only slightly in their properties. This complicates the substitution of one material for another, significantly expanding the product range when considering operating conditions, necessitating expanded warehouse space. Therefore, preference should be given to universal materials that, while maintaining the same chemical composition, can change their properties by altering the ratio of their components. This study addresses this issue by evaluating the potential of glass composites containing powdered waste glass as alternatives to selected conventional construction materials. The results demonstrated that the rheological properties of the composites can be effectively controlled by adjusting the ratio of water glass to waste glass powder, enabling the achievement of viscosity values suitable for both plastering and installation mortars. In addition, the composites exhibited markedly higher adhesion strength than conventional gypsum mortars under high-humidity conditions, confirming their applicability as adaptable, substrate-specific materials with geopolymer-like characteristics.
Effect of Glass-Composite Additives on the Properties of Cement-Based Products
In recent decades, replacing clinker in cement with mineral additives has become increasingly common, and the range of such additives continues to expand. An example is the growing number of cement types defined in European standards. Some of these standards allow the use of fine recycled concrete waste as an active additive in amounts up to 35%.. Finely ground waste glass, whose quantity steadily increases worldwide, can also be classified as an active additive. Due to its relatively high silica content, finely ground waste glass is a potential supplementary cementitious material. However, the high alkali content in glass limits its use in cementitious products to 5–10% of the binder mass. Considering that silicate binders (water glass) with high alkali activity are also used in construction and influence the hydration process of cement, it can be assumed that waste glass likewise has a significant impact on the properties of cement composites, particularly on hardening parameters and the development of mechanical strength. However, scientific literature lacks data on the synergistic effect of alkaline components of finely ground waste glass and water glass on the cement hydration process, its hardening, and the strength of cement products. Therefore, this study aimed to analyze the mechanism of the influence of a glass-based composite, consisting of waste glass additives and water glass, on the physicochemical and mechanical properties of cement composites.
Extraction of Alkalis from Silicate Materials Part 1—Amorphous Silicate Materials
The main building materials widely used worldwide are those based on cement, glass, and ceramics. Taking into account the fact that the raw material base for the production of these materials is narrowing, and the quality of raw materials is declining, methods are being used to modify the structure of silicate materials in order to improve their properties when using cheaper raw materials and industrial waste, which should help reduce the energy intensity of their production. One of the ways to reduce energy consumption is the use of alkaline components in the chemical composition of silicate materials, which makes it possible to reduce the temperature of their synthesis. However, the presence of alkalis in the material at the stage of the operation is undesirable since it contributes, for example, to a decrease in the chemical resistance of silicate glasses or leads to the phenomenon of alkaline corrosion in cement products. In this regard, in order to reduce the negative impact of alkalis, it is necessary to extract them from the surface layers of the silicate material. There are various methods for extracting alkalis from silicate materials, some of which are presented in this article.
Properties of Adhesive Mortars Using Waste Glass
This study investigates the use of waste glass as an active aggregate in glass polymers based on water glass, aiming to enhance the sustainability of construction materials by utilizing recyclable waste. Methodologically, the research employs a combination of water glass as a binder with waste glass, analyzing their chemical interaction and the resulting mechanical properties. The primary findings reveal that the inclusion of finely ground waste glass not only promotes the polycondensation and hardening processes of water glass but also significantly influences the adhesive and cohesive strengths of the developed glass polymers. After 7 days of hardening, the tensile strength of these materials exceeds that of standard concrete with values reaching up to 4.11 MPa, indicating strong adhesion capabilities that could pull out fragments of the concrete substrate. Conclusively, the study underscores the potential of waste glass in improving the structural and economic efficiencies of building materials, contributing to a reduction in landfill waste and offering a promising avenue for the innovative use of recyclable materials in construction.
Alkaline Activity of Portland Cement with Additives of Waste Glass
The concept of the alkaline activity of powdered materials introduced into cement compositions has been proposed, along with methods for its determination. The possibility of using waste glass as an active additive to Portland cement was evaluated from the standpoint of alkaline activity. Replacing the Portland cement component with glass waste in the form of glass powder at amounts from 1 to 35% made it possible to maintain the cement composition’s alkaline activity at a level that met the standard requirements. The previously unknown effects of mixed alkali in Portland cement in the presence of glass waste are described. Portland cement has a high potassium alkaline activity; however, container glass has a high sodium alkaline activity and a fairly low potassium alkaline activity. When glass waste is introduced into the structure of cement compositions, potassium alkaline activity is reduced.
Influence of Water Glass Introduction Methods on Selected Properties of Portland Cement
This article presents a study of the effect of water glass and its introduction on the hydration of Portland cement and its properties in plastic and solid states. The introduction of sodium water glass into the mixing water extends the setting time of Portland cement by 35%, while introduction into the cement paste reduces it by 24.4%; for potassium water glass, the respective values are 10.8% and 10.8%. The introduction of sodium water glass into the mixing water decreases its consistency by 17.6%; its introduction into the cement paste reduces its consistency by 97%. Based on microcalorimetric studies and using the modelling method, mechanisms of the processes occurring in the cement paste, for various methods of introducing water glass admixtures, and their influence on the properties of cement are proposed. The important implications of the obtained results are that, using various methods for introducing admixtures of water glass, it is possible to regulate the setting of cement slurries within significant limits that are important during their transportation.
Extraction of Alkalis from Silicate Materials PART 2—Crystalline Silicate Materials
A feature of silicate materials is that they can exist in two antagonistic states—amorphous and crystalline. In both cases, alkalis, which are always present in chemical compositions, play an important role. A feature of alkalis in the composition of silicate materials is that at certain stages of the synthesis of products, they play a positive role, reducing the temperature of synthesis, but worsening the properties of these products at the stage of their operation. Synthesis products should be understood as important building materials such as building glass and cement. It is known that the performance properties of glass and cement can be improved by the extraction of alkalis. In the first part of the article, the issues of extraction of alkalis in amorphous silicate materials-inorganic glasses were considered. This article presents the results of studies on the extraction process of alkalis in crystalline silicate materials-cement.
Physical and Chemical Properties of The Implant Used for Double Pelvic Osteotomy/Triple Pelvic Osteotomy Procedure in Dogs
This study aimed to determine the physical and chemical properties of a titanium alloy implant used to treat hip dysplasia in dogs. The scope of the study included examination of: surface morphology using light microscopy, optical profilometry, scanning electron microscopy, structure, hardness and hardness profile of the surface layer, adhesion of the surface layer, pitting corrosion resistance, wettability, chemical composition of the surface and passive layer using EDS and XPS. On the basis of the conducted tests, the quality of the implant was found to be satisfactory. The implant is made of biphasic Ti6Al4V alloy, it is characterized by a homogeneous surface topography, the hydrophilic surface layer is characterized by good adhesion to the substrate, the passive layer, formed on the substrate strengthened by vibratory treatment, consists mainly of titanium oxides and protects the implant from pitting corrosion. The specified set of physical and chemical properties of the implant indicates that it should be characterized by biocompatibility in the environment of the dog's body.