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170 result(s) for "Szewczyk, Piotr"
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Roughness and Fiber Fraction Dominated Wetting of Electrospun Fiber-Based Porous Meshes
Wettability of electrospun fibers is one of the key parameters in the biomedical and filtration industry. Within this comprehensive study of contact angles on three-dimensional (3D) meshes made of electrospun fibers and films, from seven types of polymers, we clearly indicated the importance of roughness analysis. Surface chemistry was analyzed with X-ray photoelectron microscopy (XPS) and it showed no significant difference between fibers and films, confirming that the hydrophobic properties of the surfaces can be enhanced by just roughness without any chemical treatment. The surface geometry was determining factor in wetting contact angle analysis on electrospun meshes. We noted that it was very important how the geometry of electrospun surfaces was validated. The commonly used fiber diameter was not necessarily a convincing parameter unless it was correlated with the surface roughness or fraction of fibers or pores. Importantly, this study provides the guidelines to verify the surface free energy decrease with the fiber fraction for the meshes, to validate the changes in wetting contact angles. Eventually, the analysis suggested that meshes could maintain the entrapped air between fibers, decreasing surface free energies for polymers, which increased the contact angle for liquids with surface tension above the critical Wenzel level to maintain the Cassie-Baxter regime for hydrophobic surfaces.
Oil‐Infused Polymer Fiber Membranes as Porous Patches for Long‐Term Skin Hydration and Moisturization
Skin allergies and diseases, including atopic dermatitis (AD), affect millions worldwide. Current treatments for AD are often expensive, leading to a need for cost‐effective solutions. Here, using fiber‐based patches to maintain and increase skin hydration is explored, which helps treat eczema and AD. Nanofiber membranes are manufactured via electrospinning of eight different polymers: nylon 6 (PA6), polyimide (PI), poly(3‐hydroxybuty‐rate‐co‐3‐hydroxyvalerate (PHBV), poly(l‐lactide) (PLLA), polycaprolactone (PCL), and polystyrene (PS), and two molecular weights poly(vinyl butyral‐co‐vinyl alcohol‐co‐vinyl acetate) (PVB). Further, their morphology is examined through scanning electron microscopy (SEM), fibers, and pores diameter, wettability, and membrane thickness. Additionally, water vapor transmission rates (WVTR) are measured, and notably, skin hydration tests are conducted before and after using evening primrose oil‐infused patches. The comparison and findings highlight the flexibility of electrospun patches, demonstrating their potential in maintaining skin hydration for 6 h and enhancing skin moisture, which are necessary in AD treatment. These insights, which focus on selecting the most effective performance patches, help improve skin moisture, leading to tailored treatments for AD, which can significantly impact the efforts to reduce healthcare costs and simplify skincare steps. Here the practical application of fiber‐based patches is explored for treating severe skin dryness. It compares eight different polymer nanofiber membranes to assess their ability to maintain skin hydration and moisture over a 6 h period. These findings offer promising solutions for treating atopic dermatitis and chronic dryness while streamlining skincare routines.
Humidity Controlled Mechanical Properties of Electrospun Polyvinylidene Fluoride (PVDF) Fibers
Processing parameters in electrospinning allow us to control the properties of fibers on a molecular level and are able to tailor them for specific applications. In this study, we investigate how relative humidity (RH) affects the mechanical properties of electrospun polyvinylidene fluoride (PVDF). The mechanical properties of single fibers were carried out using a specialized tensile stage. The results from tensile tests were additionally correlated with high-resolution imaging showing the behavior of individual fibers under tensile stress. The mechanical characteristic is strongly dependent on the crystallinity, chain orientation, and fiber diameter of electrospun PVDF fibers. Our results show the importance of controlling RH during electrospinning as the mechanical properties are significantly affected. At low RH = 30% PVDF fibers are 400% stiffer than their counterparts prepared at high RH = 60%. Moreover, the vast differences in the strain at failure were observed, namely 310% compared to 75% for 60% and 30% RH, respectively. Our results prove that humidity is a crucial parameter in electrospinning able to control the mechanical properties of polymer fibers.
Triboelectric Performance of Electrospun PVDF Fibers for Energy Harvesting: A Comparative Study of Boron Nitride (BN) and Reduced Graphene Oxide (rGO) Fillers
The growing demand for smart electronic devices in daily life requires sustainable, renewable energy sources that reliably power portable and wearable systems. Triboelectric nanogenerators (TENGs) have emerged as a promising platform for smart textile-based energy harvesting due to their material versatility and mechanical compliance. In this work, electrospun poly (vinylidene fluoride) (PVDF) fiber mats incorporating boron nitride (BN) nanoparticles and reduced graphene oxide (rGO) were investigated to elucidate the roles of insulating and conductive nanofillers in governing the structural and electroactive properties of PVDF-based triboelectric materials. Electrospun PVDF mats containing 5 wt.% BN exhibited enhanced β-phase content (82%), attributed to the nucleating effect of BN and strong interfacial interactions between the nanofiller and the PVDF matrix. In contrast, 7 wt.% rGO demonstrated a high electroactive β-phase fraction (81%), arising from filler-induced dipole alignment and enhanced charge transport within the fibrous network. A comparative analysis of BN and rGO highlights filler-driven mechanisms influencing the electroactive phase formation and triboelectric charge generation in PVDF mats. The corresponding triboelectric power density reached 231 μWcm−2 for the 7 wt.% rGO/PVDF and 281 μWcm−2 for the 5 wt.% BN/PVDF-based TENGs, providing valuable insights for the rational design of high-performance, flexible triboelectric materials for wearable energy-harvesting applications.
Studies on Energy Consumption of Electric Light Commercial Vehicle Powered by In-Wheel Drive Modules
This article presents the results of energy consumption research for an electric light commercial vehicle (eLCV) powered by a centrally located motor (4 × 2 drive system) or motors placed in the vehicle’s wheels (4 × 4 drive system). For the considered constructions of electric drive systems, mathematical models of 4 × 2 and 4 × 4 drive systems were developed in the Modelica simulation environment, based on real data. Additionally, the influence of changes in the vehicle loading condition on the operation of the motor mounted in the wheel and the energy consumption of the drive module was investigated. On the basis of the conducted research, a comparative analysis of energy consumption by electric drive systems in 4 × 2 and 4 × 4 configurations was carried out for selected test cycles. The tests carried out with the Worldwide harmonized Light vehicles Test Cycles (WLTC) test cycle showed a roughly 6% lower energy consumption by the 4 × 4 drive system compared to the 4 × 2 configuration.
Comparative Studies on Batteries for the Electrochemical Energy Storage in the Delivery Vehicle
The publication presents a proposal of methodology for the evaluation of electric vehicle energy storage, based on examples of three types of batteries. Energy stores are evaluated in different categories such as cost, reliability, total range, energy density, battery life, weight, dependency on ambient temperature, and requirements of battery conditioning system. The performance of the battery systems were analyzed on exemplary 4 × 4 vehicle with 4 independent drives systems composed of inverters and synchronous in-wheel motors. The studies showed that the best results were obtained for energy storage built on LFP prismatic batteries, and the lowest ranking was given to energy storage built on cylindrical NMC batteries. The studies present the method of aggregation of optimization criteria as a valuable methodology for assessing design requirements and the risk of traction batteries in electric vehicles.
Effectiveness of Selected Strain and Displacement Measurement Techniques in Civil Engineering
The aim of this study was to assess how useful certain selected measurement techniques are in civil engineering. In this work, the focus was placed on the measurement of displacement and strain. Classical methods with an established position in the industry, such as electrical resistance strain gauge measurements and linear variable differential transducers (LVDT), were compared with modern techniques that do not require direct contact with the measured object, such as laser scanning and digital image correlation. A simply supported beam was bent in two types of tests. In the first test, a small load was applied on the beam, causing a slight deflection of the structure of approximately 0.5 mm. This enabled us to assess how effective the tested methods were, given the very precise measurement of the structure. In the second test, a much higher load was introduced, which caused displacement that can realistically be found in actual civil engineering structures. Ultimately, the model went through the plastic phase and was damaged. This enabled the measurement of displacement and strain that were much higher than those of the safe operating range of the structure. Based on conducted examinations, practical conclusions were drawn relative to the analyzed measurement methods.
Enhancing waste resource efficiency: circular economy for sustainability and energy conversion
This study explores optimizing waste resource efficiency through the Circular Economy (CE) framework. Motivated by the imperative to enhance resource efficiency and mitigate waste's environmental impact, we examine the CE concept's extension of product life cycles, while minimizing waste. We conduct a comprehensive review to explore the core CE principles across all stages of the product lifecycle and provide an in-depth analysis of waste treatment practices in Poland, emphasizing potential energy conversion methods like biogas production and incineration. Our findings underscore the importance of prioritizing waste incineration plant design for quicker payback, aligning with circular rational economic practices. Strategies such as improving biogas production, establishing solid bio-waste fermentation facilities, promoting sortable packaging, and incentivizing sustainable sorting emerge to optimize waste management. These findings highlight the pivotal role of economic, environmental, and energy considerations in shaping sustainable waste management strategies.
Balance and Energy Use of Biogas in Poland: Prospects and Directions of Development for the Circular Economy
The production of biogas from biodegradable waste generated in all sectors of the economy in Poland is a key issue for the diversification of energy sources and climate neutrality. The biogas balances presented in the literature based on bio-waste often contain overly optimistic data, which in reality only represent the theoretical potential of biogas in Poland. The pragmatic approach presented in this study fills a gap in research by presenting a technical balance of biogas (real potential) that can be realistically achieved. The objective of the work was to perform a biogas balance in the context of electricity and heat generation in cogeneration units. The tests made it possible to estimate the technical potential of biogas, depending on the source of its generation, the possibility of its conversion to biomethane and biohydrogen and the methods of its use. The research results showed a 30% increase in biogas potential on an annual basis compared to the current state, resulting in a 29% increase in electricity production and a 28% increase in heat production. The technical potential of biogas was estimated at 2186.62 million m3, which would allow for the production of 4627.06 GWh of electricity and 1869.64 TG of heat. The technical balance of biogas and the potential energy production can serve as input material for developing plans and strategies for the development of renewable energy sources in Poland. The work is consistent with the issues of balancing the renewable energy resources from biogas and the methods of conversion into other energy carriers using sustainable energy transformations in order to optimise energy production processes.
Enhanced Electroactive Phases of Poly(vinylidene Fluoride) Fibers for Tissue Engineering Applications
Nanofibrous materials generated through electrospinning have gained significant attention in tissue regeneration, particularly in the domain of bone reconstruction. There is high interest in designing a material resembling bone tissue, and many scientists are trying to create materials applicable to bone tissue engineering with piezoelectricity similar to bone. One of the prospective candidates is highly piezoelectric poly(vinylidene fluoride) (PVDF), which was used for fibrous scaffold formation by electrospinning. In this study, we focused on the effect of PVDF molecular weight (180,000 g/mol and 530,000 g/mol) and process parameters, such as the rotational speed of the collector, applied voltage, and solution flow rate on the properties of the final scaffold. Fourier Transform Infrared Spectroscopy allows for determining the effect of molecular weight and processing parameters on the content of the electroactive phases. It can be concluded that the higher molecular weight of the PVDF and higher collector rotational speed increase nanofibers’ diameter, electroactive phase content, and piezoelectric coefficient. Various electrospinning parameters showed changes in electroactive phase content with the maximum at the applied voltage of 22 kV and flow rate of 0.8 mL/h. Moreover, the cytocompatibility of the scaffolds was confirmed in the culture of human adipose-derived stromal cells with known potential for osteogenic differentiation. Based on the results obtained, it can be concluded that PVDF scaffolds may be taken into account as a tool in bone tissue engineering and are worth further investigation.