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82 result(s) for "Thundat, Thomas"
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Experimental Realization of Zenneck Type Wave-based Non-Radiative, Non-Coupled Wireless Power Transmission
A decade ago, non-radiative wireless power transmission re-emerged as a promising alternative to deliver electrical power to devices where a physical wiring proved impracticable. However, conventional “coupling-based” approaches face performance issues when multiple devices are involved, as they are restricted by factors like coupling and external environments. Zenneck waves are excited at interfaces, like surface plasmons and have the potential to deliver electrical power to devices placed on a conducting surface. Here, we demonstrate, efficient and long range delivery of electrical power by exciting non-radiative waves over metal surfaces to multiple loads. Our modeling and simulation using Maxwell’s equation with proper boundary conditions shows Zenneck type behavior for the excited waves and are in excellent agreement with experimental results. In conclusion, we physically realize a radically different class of power transfer system, based on a wave, whose existence has been fiercely debated for over a century.
Microfluidic cantilever detects bacteria and measures their susceptibility to antibiotics in small confined volumes
In the fight against drug-resistant bacteria, accurate and high-throughput detection is essential. Here, a bimaterial microcantilever with an embedded microfluidic channel with internal surfaces chemically or physically functionalized with receptors selectively captures the bacteria passing through the channel. Bacterial adsorption inside the cantilever results in changes in the resonance frequency (mass) and cantilever deflection (adsorption stress). The excitation of trapped bacteria using infrared radiation (IR) causes the cantilever to deflect in proportion to the infrared absorption of the bacteria, providing a nanomechanical infrared spectrum for selective identification. We demonstrate the in situ detection and discrimination of Listeria monocytogenes at a concentration of single cell per μl. Trapped Escherichia coli in the microchannel shows a distinct nanomechanical response when exposed to antibiotics. This approach, which combines enrichment with three different modes of detection, can serve as a platform for the development of a portable, high-throughput device for use in the real-time detection of bacteria and their response to antibiotics. Analysis of bacteria and their response to antibiotics in real time is challenging. Here the authors report a microcantilever based system that can detect and discriminate between bacteria species and, due to the ability to discriminate between alive and dead samples, measure response to antibiotics.
Carbon fiber doped thermosetting elastomer for flexible sensors: physical properties and microfabrication
We have developed conductive microstructures using micropatternable and conductive hybrid nanocomposite polymer. In this method carbon fibers (CFs) were blended into polydimethylsiloxane (PDMS). Electrical conductivities of different compositions were investigated with various fiber lengths (50–250 μm), and weight percentages (wt%) (10–60 wt%). Sample composites of 2 cm × 1 cm × 500 μm were fabricated for 4-point probe conductivity measurements. The measured percolation thresholds varied with length of the fibers: 50 wt% (307.7 S/m) for 50 µm, 40 wt% (851.1 S/m) for 150 µm, and 30 wt% (769.23 S/m) for 250 μm fibers. The conductive composites showed higher elastic modulus when compared to that of PDMS.
Investigating fouling at the pore-scale using a microfluidic membrane mimic filtration system
The work investigates fouling in a microfluidic membrane mimic (MMM) filtration system for foulants such as polystyrene particles and large polymeric molecules. Our MMM device consists of a staggered arrangement of pillars which enables real-time visualization and analysis of pore-scale phenomena. Different fouling scenarios are investigated by conducting constant-pressure experiments. Fouling experiments are performed with three different types of foulants: polystyrene particle solution (colloidal fouling), polyacrylamide polymer solution (organic fouling) and a mixture of these two solutions (combined fouling). Four major categories of microscopic fouling are observed: cake filtration (upstream), pore blocking (inside the pores), colloidal aggregation (downstream) and colloidal streamer fouling (downstream). Our microfluidic experiments show that downstream colloidal aggregation and streamer fouling have a significant effect on overall membrane fouling which were not studied before.
Freestanding hierarchical porous carbon film derived from hybrid nanocellulose for high-power supercapacitors
Nanocellulose is a sustainable and eco-friendly nanomaterial derived from renewable biomass. In this study, we utilized the structural advantages of two types of nanocellulose and fabricated freestanding carbonized hybrid nanocellulose films as electrode materials for supercapacitors. The long cellulose nanofibrils (CNFs) formed a macroporous framework, and the short cellulose nanocrystals were assembled around the CNF framework and generated micro/mesopores. This two-level hierarchical porous structure was successfully preserved during carbonization because of a thin atomic layer deposited (ALD) A1203 conformal coating, which effectively prevented the aggregation of nanocellulose. These carbonized, partially graphitized nanocellulose fibers were interconnected, forming an integrated and highly conductive network with a large specific surface area of 1,244 m2·g-1. The two-level hierarchical porous structure facilitated fast ion transport in the film. When tested as an electrode material with a high mass loading of 4 mg·cm-2 for supercapacitors, the hierarchical porous carbon film derived from hybrid nanocellulose exhibited a specific capacitance of 170 F·g-1 and extraordinary performance at high current densities. Even at a very high current of 50 A-g-l, it retained 65% of its original specific capacitance, which makes it a promising electrode material for high-power applications.
Flexible Supercapacitor Device Based on Laser‐Synthesized Nanographene for Low‐Power Applications
Laser‐induced graphene (LIG) and laser‐induced reduced graphene oxide (LIrGO) are two relatively recent graphene‐based nanoscale materials suitable for miniaturized flexible supercapacitors. This study employs direct laser engraving techniques to generate patterns on flexible substrates, such as paper and polyamide (PI). This methodology allows fine control over the formed nanographene structures to fabricated LIG and LIrGO supercapacitors. The LIG on PI exhibits a distinctive porous structure and high surface area, adsorption, and transportation of ions. Furthermore, paper‐based LIrGO electrodes are recyclable and are formed in a single step. The morphological study is done using scanning electron microscopy, Raman spectroscopy, X‐ray photoelectron spectroscopy, and X‐ray diffraction. Galvanostatic charge–discharge studies at 0.05 mA cm−2 current density show an areal capacitance of 3.69 mF cm−2 for LIG and 1.61 mF cm−2 for LIrGO. The comparable energy densities for LIG and LIrGO are 0.32 and 0.16 μWh cm−2, respectively. From the calculative analysis of both types, the variation in specific areal capacitance enabling effective is 56.3% from GCD, indicating that the LIG device performs better. Finally, a portable potentiostat is employed to investigate the viability of utilizing supercapacitors to operate self‐powered sensors in a portable and integrable fashion. This study presents the rapid fabrication of flexible miniaturized supercapacitors using laser‐induced graphene (LIG) on polyimide and laser‐induced reduced graphene oxide (LIrGO) on paper. LIG exhibits superior performance with higher areal capacitance and energy density compared to LIrGO, making it a promising candidate for integration into portable and low‐power electronic devices.
Piezotransistive transduction of femtoscale displacement for photoacoustic spectroscopy
Measurement of femtoscale displacements in the ultrasonic frequency range is attractive for advanced material characterization and sensing, yet major challenges remain in their reliable transduction using non-optical modalities, which can dramatically reduce the size and complexity of the transducer assembly. Here we demonstrate femtoscale displacement transduction using an AlGaN/GaN heterojunction field effect transistor-integrated GaN microcantilever that utilizes piezoelectric polarization-induced changes in two-dimensional electron gas to transduce displacement with very high sensitivity. The piezotransistor demonstrated an ultra-high gauge factor of 8,700 while consuming an extremely low power of 1.36 nW, and transduced external excitation with a superior noise-limited resolution of 12.43 fm Hz −1/2 and an outstanding responsivity of 170 nV fm −1 , which is comparable to the optical transduction limits. These extraordinary characteristics, which enabled unique detection of nanogram quantity of analytes using photoacoustic spectroscopy, can be readily exploited in realizing a multitude of novel sensing paradigms. Microelectromechanical systems—micrometre-sized devices with movable parts—make highly sensitive transducers. Here, the authors fabricate an integrated gallium nitride microcantilever and heterojunction field effect transistor that uses piezoelectric effects to measure displacement at the femtoscale level.
Determining the percentage of recycled plastic content in a plastic product
As global plastic waste continues to rise, accurately identifying and quantifying recycled content in plastic products is critical for developing a circular economy. At present, there is no method that can accurately determine the percentage of recycled plastic content in a plastic product. Here, we demonstrate a multi-modal, non-destructive sensing technique to determine the percentage of recycled plastic in plastic products. We have developed a multi-modal, multi-physics approach that integrates triboelectric properties, dielectric/impedance spectroscopy, capacitance measurements, mid-infrared spectroscopy, combined with machine learning and artificial intelligence to quantify the recycled content in plastics. Experimental results reveal that increasing recycled content leads to enhanced charge retention, reduced permittivity, and increased dielectric loss, consistent with polymer chain scission and defect-induced polarization. The machine learning model trained on the multi-modal dataset achieves we achieved over 97% classification accuracy across PET samples ranging from 0% to 50% recycled content, which is the expected regime of required recycled content in plastic products. This method offers a solution for control and regulatory compliance for recycled plastics. Yaoli Zhao and colleagues have developed a non-destructive method to determine the percentage of recycled plastic content in a plastic product. By combining multi-modal sensing with machine learning, this approach enables reliable verification of recycled content, supporting regulatory compliance, quality control, and circular plastics manufacturing.
Effect of interface on mid-infrared photothermal response of MoS2 thin film grown by pulsed laser deposition
This study reports on the mid-infrared (mid-IR) photothermal response of multilayer MoS2 thin films grown on crystalline (p-type silicon and c-axis- oriented single crystal sapphire) and amorphous (Si/SiO2 and Si/SiN) substrates by pulsed laser deposition (PLD). The photothermal response of the MoS2 films is measured as the changes in the resistance of the MoS2 films when irradiated with a mid-IR (7 to 8.2 μm) source. We show that enhancing the temperature coefficient of resistance (TCR) of the MoS2 thin films is possible by controlling the film-substrate interface through a proper choice of substrate and growth conditions. The thin films grown by PLD are characterized using X-ray diffraction, Raman, atomic force microscopy, X-ray photoelectron microscopy, and transmission electron microscopy. The high-resolution transmission electron microscopy (HRTEM) images show that the MoS2 films grow on sapphire substrates in a layer-by-layer manner with misfit dislocations. The layer growth morphology is disrupted when the films are grown on substrates with a diamond cubic structure (e.g., silicon) because of twin growth formation. The growth morphology on amorphous substrates, such as Si/SiO2 or Si/SiN, is very different. The PLD-grown MoS2 films on silicon show higher TCR (-2.9% K^-1 at 296 K), higher mid-IR sensitivity (△R/R = 5.2%), and higher responsivity (8.7 V·W^-1) compared to both the PLD-grown films on other substrates and the mechanically exfoliated MoS2 flakes transferred to different substrates.
Materials science: The abilities of instabilities
A method has been developed for preparing a variety of potentially useful spherical particles, ranging from several nanometres to millimetres in diameter. It relies on the same fluid instability that causes taps to drip.