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107 result(s) for "Timar, Cristina"
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Nanodelivery of essential oils as efficient tools against antimicrobial resistance: a review of the type and physical-chemical properties of the delivery systems and applications
This review provides a synthesis of the last ten years of research on nanodelivery systems used for the delivery of essential oils (EOs), as well as their potential as a viable alternative to antibiotics in human and veterinary therapy. The use of essential oils alone in therapy is not always possible due to several limitations but nanodelivery systems seem to be able to overcome these issues. The choice of the essential oil, as well as the choice of the nanodelivery system influences the therapeutic efficacy obtained. While several studies on the characterization of EOs exist, this review assesses the characteristics of the nanomaterials used for the delivery of essential oils, as well as impact on the functionality of nanodelivered essential oils, and successful applications. Two classes of delivery systems stand out: polymeric nanoparticles (NPs) including chitosan, cellulose, zein, sodium alginate, and poly(lactic-co-glycolic) acid (PLGA), and lipidic NPs including nanostructured lipid carriers, solid lipid NPs, nanoemulsions, liposomes, and niosomes. While the advantages and disadvantages of these delivery systems and information on stability, release, and efficacy of the nanodelivered EOs are covered in the literature as presented in this review, essential information, such as the speed of emergence of a potential bacteria resistance to these new systems, or dosages for each type of infection and for each animal species or humans is still missing today. Therefore, more quantitative and in vivo studies should be conducted before the adoption of EOs loaded NPs as an alternative to antibiotics, where appropriate.
Sustainable thermal and acoustic insulating panels from recycled cardboard
The objective of this study was to determine both the physical and mechanical properties of experimental panels made from recycled corrugated cardboard. Two types of composite samples, derived from two different raw materials — namely, unprinted and printed cardboard — were manufactured. The physical characteristics of the specimens, including density, water absorption, dimensional stability, thermal conductivity, and sound absorption, were tested. Additionally, the mechanical properties, such as the modulus of elasticity, modulus of rupture, and internal bond strength, were evaluated. Based on the findings of this research, the samples made from unprinted cardboard exhibited higher density, lower thickness swelling, and slightly better thermal insulation properties than those made from printed raw material. In contrast, the samples containing printed material demonstrated superior mechanical properties, suggesting they may be more suitable to be used where structural properties are desired. Overall, the properties of both types of samples indicate that such panels have an important potential to be used as sustainable products, serving as a green alternative material for indoor applications.
Comparative research on the structure, chemistry, and physical properties of Turkey oak and sessile oak wood
The objective of this research was to establish comparatively some relevant features of Turkey oak and sessile oak wood, in order to better understand the drying behavior of these species. The analyzed samples were obtained from freshly harvested trees of the same age, originating from the Southern Sub-Carpathians. The microscopic analysis revealed that Turkey oak has larger earlywood pores than sessile oak. In heartwood, they are partly filled with tyloses for both species. The macroscopic analysis showed that Turkey oak wood has a much lower proportion of heartwood (only 50%) compared to sessile oak (90%). The comparative FTIR analysis of the two species showed similar qualitative chemical composition, but also some differences between sapwood and heartwood regarding the relative proportion of the main constituents, and very likely in the structure of lignin. High amounts of extractives were found in Turkey oak sapwood (5.34% in cold water, 7.77% in hot water, and 21.60% in NaOH 1%), close to the values obtained in sessile oak heartwood. The research also revealed that the Turkey oak sapwood and heartwood have statistically similar values of oven-dry density, shrinkage coefficient, fiber saturation point, while in sessile oak, the values are clearly higher in the heartwood.
Light-Induced Colour Changes in Wood Surfaces in Indoor Conditions Determined by an Artificial Accelerated Test: Influence of Wood Species and Coating Materials
Stabilising the natural colour of wood species exposed to light in indoor conditions is a challenge that could be better addressed based on a deeper understanding of the occurring phenomena and influencing factors. This paper investigates comparatively the light-induced colour changes for three hardwood species, namely, European maple (Acer pseudoplatanus L.), European ash (Fraxinus excelsior L.) and European walnut (Juglans regia L.), as well as the influence of finishing with three types of clear, colourless waterborne lacquers: acrylic-polyurethane (F1), acrylic (F2) and polyurethane (F3) on their colour stability. Colour measurements in the CIELab system in conjunction with an artificial accelerated ageing test under the action of UV-VIS radiation, simulating natural light passing through window glass, and two types of test samples were employed to highlight the influence and contributions of the wood substrate and of the coating films to the global colour modifications. Coating films applied on 1 mm clear glass slides were employed as a sort of “detachable” finish for this purpose. Direct exposure to UV-VIS light caused visible colour changes for both uncoated and coated wood surfaces, the values of the calculated colour differences (ΔE) after a 72 h exposure being dependant on both the wood species and the coating material. Excepting two situations for walnut, statistically significantly higher colour differences were obtained for the uncoated samples: maple (9.36 units), ash (8.39 units), walnut (6.20 units), compared to the coated ones: maple (4.92–5.71 units), ash (2.25–3.94 units), walnut (4.74–7.70 units). The wood substrates underlying the coating films were found to bring the maximum contribution to the overall colour changes in the clear coated surfaces, while the coating films employed in this research demonstrated a fairly good colour stability to UV-VIS light exposure, with maximum colour changes (∆E) up to only 1.30 units. Overall, the wood species and the type of coating were found as influencing factors in interaction with the light-induced colour changes in wood surfaces in indoor conditions.
Selected Physical and Mechanical Properties of Subfossil Oak (Quercus spp.) Compared to Aged Oak and Recent Oak
Subfossil oak (SO) wood material, originating from three different buried trunks discovered in recent years by excavations in riverbanks on Romanian territory, was analysed in this research. Aged oak recovered from constructions (AO_C) and recent/new oak wood material (NO) were also investigated to provide comparative data for the SO. The oven-dry density and the basic density, the total volumetric and linear swelling and shrinkage coefficients and the compression strength parallel to the grain were the selected physical and mechanical properties considered. The experimental results showed a lower density of SO compared to NO and AO_C tested by up to about 19–20%, alongside a trend of increased dimensional instability, with variability among the tested assortments. The compression strength parallel to the grain was reduced by 19–31% compared to NO. The properties of AO-C were closer to those of NO, but differences between wood materials from different sources and of different ages were registered. A positive linear correlation was found between compression strength parallel to grain and the basic density for all types of material and assortments tested. These comparative results have to be considered by designers and engineers in the valorisation of SO in furniture design and other applications.
Properties of Green Foam-Type Composites Made from Recycled Paper and Cardboard
This study developed sustainable foam-type composites from recycled paper (P), corrugated cardboard (C), and their 1:1 mixture (PC) for use in thermal and acoustic insulation. The materials were produced by water-assisted defibration, gas foaming with sodium bicarbonate and yeast, and oven curing, resulting in lightweight porous panels without synthetic binders. The composites exhibited distinct density and porosity profiles that influenced moisture behavior and stability. Cardboard-based panels absorbed the most water and swelled the most, while paper-based panels were more resistant. Despite these differences, all materials showed uniformly low thermal conductivity, confirming their strong insulation capability. Acoustic performance was enhanced by perforation and multilayer assembly. Cardboard panels with a triple-layer perforated design achieved the highest sound absorption, while mixed paper–cardboard composites provided balanced broadband performance. Microscopy revealed that fiber morphology—coarse in cardboard, fine in paper, and interlaced in mixtures—shaped the porous structure and bonding. Mechanical tests indicated comparable stiffness and strength across all types, with cardboard showing the strongest internal bonding. Overall, the results demonstrate that fiber structure and porosity govern material performance. These foam composites combine effective thermal insulation, competitive sound absorption, and sufficient mechanical strength, positioning them as biodegradable, low-cost alternatives for sustainable construction and acoustic applications.
Tunable Acoustic Properties Using Different Coating Systems on Resonance Spruce Wood
The study investigates the effect of the type of varnish and the number of layers on some acoustic properties of the resonance spruce in combination with the changes produced in some physical, morphological, and chemical properties of wood. In addition to color changes and surface chemistry, the surface roughness and morphology are modified by the thickness of the varnish film, 10 layers being optimal from this point of view, as well as the oil‐based finish. The sound absorption coefficient increases with the number of varnish layers and varies with the sound frequency range, varnish type, and wood quality, all contributing to the acoustic tunability. For example, for a sound frequency of 1.5 kHz, it is observed that the oil‐based varnish with 5 and 10 layers contributes to a full sound, while the alcohol varnish, due to a lower absorption coefficient for this frequency, can lead to some nasal sounds. Applying more than 10 layers of varnish does not improve the sound performance as it will soften the sound in an oil‐based finish and make the sound too sharp in the case of alcohol–varnished wood. The novelty of the article consists of a comprehensive approach, in which the effect of the varnishing systems (varnish type, number of layers applied) on the selected acoustic parameters is analyzed in combination with the effect they produce on the physical, morphological, and the chemical properties of resonance spruce wood, all contributing to the acoustic tunability.
Mechanical Properties and Formaldehyde Release of Particleboard Made with Lignin-Based Adhesives
The aim of this research was to evaluate the potential of magnesium lignosulfonate as adhesive in particleboard manufacturing. Diphenylmethane diisocyanate (PMDI) between 1% and 3% and glucose (1% of the lignosulfonate content) were added as potential cross-linkers in the adhesive formulations. Mixed beech and spruce wood, 30% beech wood and 70% spruce wood, were employed for the configuration of the panel structure. The density, mechanical properties and formaldehyde emission of single-layer particleboard were investigated. Spectroscopic analysis (FTIR) revealed structural changes brought by oxidation that may indicate depolymerization by the splitting of C-O-C bonds and formation of carbonyl groups. Mechanical properties were improved, and the highest average values were recorded for panels having as adhesives oxidized lignin with cross-linkers as follow: 15 N/mm2 (MOR), 3320 N/mm2 (MOE) and 0.48 N/mm2 (IB). The density profile presented higher values for faces in case of oxidized lignin panels. Changes were observed for oxidized lignin with cross-linker panels wherein the core had higher values. The results showed that the panels manufactured with adhesives composed of oxidized lignosulfonate (20% of the dried wood particles weight) and the addition of PMDI and glucose in various percentages have a positive influence on their formaldehyde release and mechanical properties requested by EN 312 (2004) standard.
Comparative study of photodegradation of six wood species after short-time UV exposure
The effect of UV irradiation on different wood species represents an open subject of research. Six species, half softwoods and half hardwoods, all important for both historic and modern furniture, were subjected to the action of artificial UV radiation at a constant temperature of 40 °C. The species were: fir (Abies alba), pine (Pinus sylvestris), larch (Larix decidua), ash (Fraxinus excelsior), cherry (Prunus/Cerasus avium) and walnut (Juglans regia). Previous research showed that important and rapid changes occur within the first 24 h of exposure, and therefore, a short exposure time was adopted in this research, where the specimens were subjected to the action of UV-rich artificial light (UVB–UVA–Vis, 295–600 nm, UVA-Spot 400T source), at a constant temperature of 40 °C, in a climatic chamber. The effect of exposure was measured after 6, 12, 18 and 24 h. The test samples were covered with black cardboard on half of their surface to block the access of UV radiation and allow the investigation of temperature effect with none or limited UV penetration. The experiments proved that UV radiation caused rapidly colour changes (after 6 h), as darkening, monitored by direct observations and colour measurements in the CIE Lab system. The overall colour difference ΔE evolved in time, reaching, after 24 h UV exposure at 40 °C, a maximum for pine (15.93) and minimum for ash (7.05). FTIR–ATR analyses were performed to determine surface chemical structure changes associated with the measured colour changes. UV radiation caused photodegradation phenomena as lignin degradation and photooxidation processes leading to the formation of carbonyl containing chromophores, even after short-time exposure periods (6 h), which evolved in time following patterns influenced by the wood species. The moderate temperature had only a limited effect on the covered specimens, on both colour and surface chemistry changes, compared to the effect combined with UV irradiation, but particularities were observed in the behaviour of the wood species studied. The combined analysis of FTIR–ATR results with CIE Lab measurements showed only a slight trend in case of yellowness, which was associated with lignin degradation, but none for redness, associated mostly with wood extractives. The different behaviour of the wood species studied may be related to the differences in their chemical composition, especially lignin and extractives content.
Aging of Wood for Musical Instruments: Analysis of Changes in Color, Surface Morphology, Chemical, and Physical-Acoustical Properties during UV and Thermal Exposure
The acoustic features of old resonance wood in violins exhibit a superior quality when compared to those from new resonance wood. This study focuses on an assessment of the sound quality of two types of wood for musical instruments, spruce and maple (class A and D), before and after aging via thermal and UV exposure. The samples were characterized before and after UV aging in terms of color change (using a Chroma meter), surface morphology (using a MarSurf XT20 instrument), chemical changes (monitored by FTIR spectroscopy), and sound propagation speed (using an ultrasound device). After UV treatment, the wavier surface increased the area of exposure and degradation. Also, the color changes were found to be more accentuated in the case of spruce compared to sycamore maple. The FTIR results indicated more advanced aging processes for spruce when compared to maple under the same experimental conditions. This difference resulted mostly from the increased formation of carbonyl-containing chromophores via oxidative processes in spruce rather than in maple, which is in agreement with the color change findings. Exposure of both species to thermal and UV radiation led to an increase in sound propagation speed, both longitudinally and radially, and to a greater extent in wood quality class A when compared to quality class D.