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Massive stars disrupt their natal molecular cloud material through radiative and mechanical feedback processes. These processes have profound effects on the evolution of interstellar matter in our Galaxy and throughout the universe, from the era of vigorous star formation at redshifts of 1–3 to the present day. The dominant feedback processes can be probed by observations of the Photo-Dissociation Regions (PDRs) where the far-ultraviolet photons of massive stars create warm regions of gas and dust in the neutral atomic and molecular gas. PDR emission provides a unique tool to study in detail the physical and chemical processes that are relevant for most of the mass in inter- and circumstellar media including diffuse clouds, proto-planetary disks, and molecular cloud surfaces, globules, planetary nebulae, and star-forming regions. PDR emission dominates the infrared (IR) spectra of star-forming galaxies. Most of the Galactic and extragalactic observations obtained with the JamesWebb Space Telescope (JWST) will therefore arise in PDR emission. In this paper we present an Early Release Science program using the MIRI, NIRSpec, and NIRCam instruments dedicated to the observations of an emblematic and nearby PDR: the Orion Bar. These early JWST observations will provide template data sets designed to identify key PDR characteristics in JWST observations. These data will serve to benchmark PDR models and extend them into the JWST era. We also present the Science-Enabling products that we will provide to the community. These template data sets and Science-Enabling products will guide the preparation of future proposals on star-forming regions in our Galaxy and beyond and will facilitate data analysis and interpretation of forthcoming JWST observations.

Stars are the building blocks of galaxies. The gas present in galaxies is the primary fuel for star formation. Galaxy evolution depends on the amount of gas present in the interstellar medium (ISM). Stars are born mainly from molecular gas in the GMCs. Robust knowledge of the molecular hydrogen H2 gas distribution is necessary to understand star formation in galaxies. Since H2 is not readily observable in the cold interstellar medium (ISM), the molecular gas content has traditionally been inferred using indirect tracers like carbon-monoxide (CO), dust emission, gamma ray interactions, and star formation efficiency. Physical processes resulting in enhancement and reduction of these indirect tracers can result in misleading estimates of molecular gas masses. My dissertation work is based on devising a new temperature power law distribution model for H2, a direct tracer, to calculate the total molecular gas mass in galaxies. The model parameters are estimated using mid infrared (MIR) H2 rotational line fluxes obtained from IRS-Spitzer (Infrared Spectrograph-Spitzer) instrument and the model is extrapolated to a suitable lower temperature to recover the total molecular gas mass. The power law model is able to recover the dark molecular gas, undetected by CO, in galaxies at metallicity as low as one-tenth of our Milky Way value. I have applied the power law model in U/LIRGs and shocks of Stephan's Quintet to understand molecular gas properties, where shocks play an important role in exciting H2. Comparing the molecular gas content derived through our power law model can be useful in studying the application of our model in mergers. The parameters derived by our model is useful in understanding variation in molecular gas properties in shock regions of Stephan's Quintet. Low mass stars are formed in small isolated dense cores known as Bok globules. Multiple star formation events are seen in a Bok globule. In my thesis I also studied a Bok globule, B207, and determined the physical properties and future evolutionary stage of the cloud. My thesis spans studying ISM properties in galaxies from kpc to sub-pc scales. Using the power law model in the coming era of James Webb Space Telescope (JWST) with the high sensitivity MIR Instrument (MIRI) spectrograph we will be able to understand the properties of molecular gas at low and high redshifts.

We present a first look at the MRS observations of the nucleus of the nearby galaxy M83, taken with MIRI onboard JWST. The observations show a rich set of emission features from the ionized gas, warm molecular gas, and dust. To begin dissecting the complex processes in this part of the galaxy, we divide the observations into four different regions. We find that the strength of the emission features varies strongly from region to region, with the south-east region displaying the weakest features tracing the dust continuum and ISM properties. Comparison between the cold molecular gas traced by the \\(^{12}\\)CO (1-0) transition with ALMA and the H\\(_2\\) S(1) transition shows a similar spatial distribution. This is in contrast to the distribution of the much warmer H\\(_2\\) emission from the S(7) transition found to be concentrated around the optical nucleus. We use the rotational emission lines and model the H\\(_2\\) excitation to estimate a total molecular gas mass accounting for the warm H\\(_2\\) component of M(\\(>\\)50 K)\\(_{\\rm H_{2}}\\) = 67.90 (\\(\\pm 5.43\\))\\(\\times\\)10\\(^{6}\\) M\\(_{\\odot}\\). We compare this value to the total gas mass inferred by probing the cold H\\(_2\\) gas through the \\(^{12}\\)CO (1-0) emission, M(CO)\\(_{\\rm H_{2}}\\) = 17.15\\(\\times\\)10\\(^{6}\\) M\\(_{\\odot}\\). We estimate that \\(\\sim\\)75\\% of the total molecular gas mass is contained in the warm H\\(_2\\) component. We also identify [\\ion{O}{4}] 25.89 \\(\\mu\\)m and [\\ion{Fe}{2}] 25.99 \\(\\mu\\)m emission. We propose that the diffuse [\\ion{Fe}{2}] 25.99 \\(\\mu\\)m emission might be tracing shocks created during the interactions between the hot wind produced by the starburst and the much cooler ISM above the galactic plane. More detailed studies are needed to confirm such a scenario.

The impact of Active Galactic Nuclei (AGN) on star formation has implications for our understanding of the relationships between supermassive black holes and their galaxies, as well as for the growth of galaxies over the history of the Universe. We report on a high-resolution multi-phase study of the nuclear environment in the nearby Seyfert galaxy NGC 2110 using the Atacama Large Millimeter Array (ALMA), Hubble and Spitzer Space Telescopes, and the Very Large Telescope/SINFONI. We identify a region that is markedly weak in low-excitation CO \\(2\\rightarrow1\\) emission from cold molecular gas, but appears to be filled with ionised and warm molecular gas, which indicates that the AGN is directly influencing the properties of the molecular material. Using multiple molecular gas tracers, we demonstrate that, despite the lack of CO line emission, the surface densities and kinematics of molecular gas vary smoothly across the region. Our results demonstrate that the influence of an AGN on star-forming gas can be quite localized. In contrast to widely-held theoretical expectations, we find that molecular gas remains resilient to the glare of energetic AGN feedback.

Mid-infrared emission features probe the properties of ionized gas, and hot or warm molecular gas. The Orion Bar is a frequently studied photodissociation region (PDR) containing large amounts of gas under these conditions, and was observed with the MIRI IFU aboard JWST as part of the \"PDRs4All\" program. The resulting IR spectroscopic images of high angular resolution (0.2\") reveal a rich observational inventory of mid-IR emission lines, and spatially resolve the substructure of the PDR, with a mosaic cutting perpendicularly across the ionization front and three dissociation fronts. We extracted five spectra that represent the ionized, atomic, and molecular gas layers, and measured the most prominent gas emission lines. An initial analysis summarizes the physical conditions of the gas and the potential of these data. We identified around 100 lines, report an additional 18 lines that remain unidentified, and measured the line intensities and central wavelengths. The H I recombination lines originating from the ionized gas layer bordering the PDR, have intensity ratios that are well matched by emissivity coefficients from H recombination theory, but deviate up to 10% due contamination by He I lines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni, and show how certain line ratios vary between the five regions. We observe the pure-rotational H\\(_2\\) lines in the vibrational ground state from 0-0 S(1) to 0-0 S(8), and in the first vibrationally excited state from 1-1 S(5) to 1-1 S(9). We derive H\\(_2\\) excitation diagrams, and approximate the excitation with one thermal (~700 K) component representative of an average gas temperature, and one non-thermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model for the Orion Bar PDR and highlight the differences with the observations.

(Abridged) We investigate the impact of radiative feedback from massive stars on their natal cloud and focus on the transition from the HII region to the atomic PDR (crossing the ionisation front (IF)), and the subsequent transition to the molecular PDR (crossing the dissociation front (DF)). We use high-resolution near-IR integral field spectroscopic data from NIRSpec on JWST to observe the Orion Bar PDR as part of the PDRs4All JWST Early Release Science Program. The NIRSpec data reveal a forest of lines including, but not limited to, HeI, HI, and CI recombination lines, ionic lines, OI and NI fluorescence lines, Aromatic Infrared Bands (AIBs including aromatic CH, aliphatic CH, and their CD counterparts), CO2 ice, pure rotational and ro-vibrational lines from H2, and ro-vibrational lines HD, CO, and CH+, most of them detected for the first time towards a PDR. Their spatial distribution resolves the H and He ionisation structure in the Huygens region, gives insight into the geometry of the Bar, and confirms the large-scale stratification of PDRs. We observe numerous smaller scale structures whose typical size decreases with distance from Ori C and IR lines from CI, if solely arising from radiative recombination and cascade, reveal very high gas temperatures consistent with the hot irradiated surface of small-scale dense clumps deep inside the PDR. The H2 lines reveal multiple, prominent filaments which exhibit different characteristics. This leaves the impression of a \"terraced\" transition from the predominantly atomic surface region to the CO-rich molecular zone deeper in. This study showcases the discovery space created by JWST to further our understanding of the impact radiation from young stars has on their natal molecular cloud and proto-planetary disk, which touches on star- and planet formation as well as galaxy evolution.

(Abridged) Mid-infrared observations of photodissociation regions (PDRs) are dominated by strong emission features called aromatic infrared bands (AIBs). The most prominent AIBs are found at 3.3, 6.2, 7.7, 8.6, and 11.2 \\(\\mu\\)m. The most sensitive, highest-resolution infrared spectral imaging data ever taken of the prototypical PDR, the Orion Bar, have been captured by JWST. We provide an inventory of the AIBs found in the Orion Bar, along with mid-IR template spectra from five distinct regions in the Bar: the molecular PDR, the atomic PDR, and the HII region. We use JWST NIRSpec IFU and MIRI MRS observations of the Orion Bar from the JWST Early Release Science Program, PDRs4All (ID: 1288). We extract five template spectra to represent the morphology and environment of the Orion Bar PDR. The superb sensitivity and the spectral and spatial resolution of these JWST observations reveal many details of the AIB emission and enable an improved characterization of their detailed profile shapes and sub-components. While the spectra are dominated by the well-known AIBs at 3.3, 6.2, 7.7, 8.6, 11.2, and 12.7 \\(\\mu\\)m, a wealth of weaker features and sub-components are present. We report trends in the widths and relative strengths of AIBs across the five template spectra. These trends yield valuable insight into the photochemical evolution of PAHs, such as the evolution responsible for the shift of 11.2 \\(\\mu\\)m AIB emission from class B\\(_{11.2}\\) in the molecular PDR to class A\\(_{11.2}\\) in the PDR surface layers. This photochemical evolution is driven by the increased importance of FUV processing in the PDR surface layers, resulting in a \"weeding out\" of the weakest links of the PAH family in these layers. For now, these JWST observations are consistent with a model in which the underlying PAH family is composed of a few species: the so-called 'grandPAHs'.

The JWST has captured the most detailed and sharpest infrared images ever taken of the inner region of the Orion Nebula, the nearest massive star formation region, and a prototypical highly irradiated dense photo-dissociation region (PDR). We investigate the fundamental interaction of far-ultraviolet photons with molecular clouds. The transitions across the ionization front (IF), dissociation front (DF), and the molecular cloud are studied at high-angular resolution. These transitions are relevant to understanding the effects of radiative feedback from massive stars and the dominant physical and chemical processes that lead to the IR emission that JWST will detect in many Galactic and extragalactic environments. Due to the proximity of the Orion Nebula and the unprecedented angular resolution of JWST, these data reveal that the molecular cloud borders are hyper structured at small angular scales of 0.1-1\" (0.0002-0.002 pc or 40-400 au at 414 pc). A diverse set of features are observed such as ridges, waves, globules and photoevaporated protoplanetary disks. At the PDR atomic to molecular transition, several bright features are detected that are associated with the highly irradiated surroundings of the dense molecular condensations and embedded young star. Toward the Orion Bar PDR, a highly sculpted interface is detected with sharp edges and density increases near the IF and DF. This was predicted by previous modeling studies, but the fronts were unresolved in most tracers. A complex, structured, and folded DF surface was traced by the H2 lines. This dataset was used to revisit the commonly adopted 2D PDR structure of the Orion Bar. JWST provides us with a complete view of the PDR, all the way from the PDR edge to the substructured dense region, and this allowed us to determine, in detail, where the emission of the atomic and molecular lines, aromatic bands, and dust originate.

We present a spatially-resolved (~3 pc pix\\(^{-1}\\)) analysis of the distribution, kinematics, and excitation of warm H2 gas in the nuclear starburst region of M83. Our JWST/MIRI IFU spectroscopy reveals a clumpy reservoir of warm H2 (> 200 K) with a mass of ~2.3 x 10\\(^{5}\\) Msun in the area covered by all four MRS channels. We additionally use the [Ne II] 12.8 \\({\\mu}\\)m and [Ne III] 15.5 \\({\\mu}\\)m lines as tracers of the star formation rate, ionizing radiation hardness, and kinematics of the ionized ISM, finding tantalizing connections to the H2 properties and to the ages of the underlying stellar populations. Finally, qualitative comparisons to the trove of public, high-spatial-resolution multiwavelength data available on M83 shows that our MRS spectroscopy potentially traces all stages of the process of creating massive star clusters, from the embedded proto-cluster phase through the dispersion of ISM from stellar feedback.

Barnard 207 (B207, LDN 1489, LBN 777), also known as the Vulture Head nebula, is a cometary globule in the Taurus-Auriga-Perseus molecular cloud region. B207 is known to host a Class I protostar, IRAS 04016+2610, located at a projected distance of ~8,400 au from the dense core centre. Using imaging and photometry over a wide wavelength range, from UV to sub-mm, we study the physical properties of B207 and the dust grains contained within. The core density, temperature, and mass are typical of other globules found in the Milky Way interstellar medium (ISM). The increase in the dust albedo with increasing optical wavelengths, along with the detection of coreshine in the near infrared, indicates the presence of larger dust grains in B207. The measured optical, near-, mid- and far-infrared intensities are in agreement with the CMM+AMM and CMM+AMMI dust grain type of The Heterogeneous dust Evolution Model for Interstellar Solids (THEMIS), suggesting mantle formation on the dust grains throughout the globule. We investigate the possibility of turbulence being responsible for diffusing dust grains from the central core to external outer layers of B207. However, in situ formation of large dust grains cannot be excluded.