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A large number of water masses are presented in the Atlantic Ocean, and knowledge of their distributions and properties is important for understanding and monitoring of a range of oceanographic phenomena. The characteristics and distributions of water masses in biogeochemical space are useful for, in particular, chemical and biological oceanography to understand the origin and mixing history of water samples. Here, we define the characteristics of the major water masses in the Atlantic Ocean as source water types (SWTs) from their formation areas, and map out their distributions. The SWTs are described by six properties taken from the biased-adjusted Global Ocean Data Analysis Project version 2 (GLODAPv2) data product, including both conservative (conservative temperature and absolute salinity) and non-conservative (oxygen, silicate, phosphate and nitrate) properties. The distributions of these water masses are investigated with the use of the optimum multi-parameter (OMP) method and mapped out. The Atlantic Ocean is divided into four vertical layers by distinct neutral densities and four zonal layers to guide the identification and characterization. The water masses in the upper layer originate from wintertime subduction and are defined as central waters. Below the upper layer, the intermediate layer consists of three main water masses: Antarctic Intermediate Water (AAIW), Subarctic Intermediate Water (SAIW) and Mediterranean Water (MW). The North Atlantic Deep Water (NADW, divided into its upper and lower components) is the dominating water mass in the deep and overflow layer. The origin of both the upper and lower NADW is the Labrador Sea Water (LSW), the Iceland–Scotland Overflow Water (ISOW) and the Denmark Strait Overflow Water (DSOW). The Antarctic Bottom Water (AABW) is the only natural water mass in the bottom layer, and this water mass is redefined as Northeast Atlantic Bottom Water (NEABW) in the north of the Equator due to the change of key properties, especially silicate. Similar with NADW, two additional water masses, Circumpolar Deep Water (CDW) and Weddell Sea Bottom Water (WSBW), are defined in the Weddell Sea region in order to understand the origin of AABW.

We quantify the oceanic sink for anthropogenic carbon dioxide (CO₂) over the period 1994 to 2007 by using observations from the global repeat hydrography program and contrasting them to observations from the 1990s. Using a linear regression–based method, we find a global increase in the anthropogenic CO₂ inventory of 34 ± 4 petagrams of carbon (Pg C) between 1994 and 2007. This is equivalent to an average uptake rate of 2.6 ± 0.3 Pg C year−1 and represents 31 ± 4% of the global anthropogenic CO₂ emissions over this period. Although this global ocean sink estimate is consistent with the expectation of the ocean uptake having increased in proportion to the rise in atmospheric CO₂, substantial regional differences in storage rate are found, likely owing to climate variability–driven changes in ocean circulation.

The GO-SHIP nutrient manual covers all aspects of nutrient analysis from basic sample collection and storage, specifically for Continuous Flow analysis using an Auto-Analyzer, and describes some specific nutrient methods for Nitrate, Nitrite, Silicate, Phosphate and Ammonium that are in use by many laboratories carrying out at-sea analysis and repeat hydrography sections across the world. The focus is on segmented flow analyzers not flow injection analyzers. It also covers laboratory best practices including quality control and quality assurance (QC/QA) procedures to obtain the best results, and suggests protocols for the use of reference materials (RM) and certified reference materials (CRMs).

Litter and plastic pollution in the marine environment is of major concern when considering the health of ocean ecosystems, and have become an important focus of ocean research during recent years. There is still significant uncertainty surrounding the distribution and impact of marine plastic litter on ocean ecosystems, and in particular on the nano- and microplastic fractions that are difficult to observe and may be harmful to marine organisms. Current estimates of ocean plastic concentrations only account for a small fraction of the approximated 8 million tons of plastic litter entering the oceans on an annual basis. Here, we present the distribution of 100–500 μm microplastic particles within the ocean mixed layer, covering a significant fraction of the ocean, in a near-synoptic survey. During The Ocean Race 2017/2018 edition (formerly known as Volvo Ocean Race ), two yachts served as ships of opportunity that regularly took samples of microplastics on a regular schedule during their circumnavigation. This effort resulted in information on microplastic distribution along the race track in the ocean’s upper, well-mixed, layer. We found concentrations ranging from 0–349 particles per cubic meter, but with large spatial variability. There was a tendency toward higher concentrations off south-western Europe and in the southwest Pacific, and indications of long-range transport of microplastic with major ocean currents.

Enhanced Southern Ocean ventilation in recent decades has been suggested to be a relevant modulator of the observed changes in ocean heat and carbon uptake. This study focuses on the Southern Ocean midlatitude ventilation changes from the 1960s to the 2010s. A global 1/4° configuration of the NEMO–Louvain-la-Neuve sea ice model, version 2 (LIM2), including the inert tracer CFC-12 (a proxy of ocean ventilation) is forced with the CORE, phase II (CORE-II), and JRA-55 driving ocean (JRA55-do) atmospheric reanalyses. Sensitivity experiments, where the variability of wind stress and/or the buoyancy forcing is suppressed on interannual time scales, are used to unravel the mechanisms driving ventilation changes. Ventilation changes are estimated by comparing CFC-12 interior inventories among the different experiments. All simulations suggest a multidecadal fluctuation of Southern Ocean ventilation, with a decrease until the 1980s–90s and a subsequent increase. This evolution is related to the atmospheric forcing and is caused by the (often counteracting) effects of wind stress and buoyancy forcing. Until the 1980s, increased buoyancy gains caused the ventilation decrease, whereas the subsequent ventilation increase was driven by strengthened wind stress causing deeper mixed layers and a stronger meridional overturning circulation. Wind stress emerges as the main driver of ventilation changes, even though buoyancy forcing modulates its trend and decadal variability. The three Southern Ocean basins take up CFC-12 in distinct density intervals but overall respond similarly to the atmospheric forcing. This study suggests that Southern Ocean ventilation is expected to increase as long as the effect of increasing Southern Hemisphere wind stress overwhelms that of increased stratification.

The Mediterranean Sea is a small region of the global ocean but with a very active overturning circulation that allows surface perturbations to be transported to the interior ocean. Understanding of ventilation is important for understanding and predicting climate change and its impact on ocean ecosystems. To quantify changes of deep ventilation, we investigated the spatiotemporal variability of transient tracers (i.e. CFC-12 and SF6) observations combined with temporal evolution of hydrographic and oxygen observations in the Mediterranean Sea from 13 cruises conducted during 1987-2018, with emphasize on the update from 2011 to 2018. Spatially, both the Eastern and Western Mediterranean Deep Water (EMDW and WMDW) show a general west-to-east gradient of increasing salinity and potential temperature but decreasing oxygen and transient tracer concentrations. Temporally, stagnant and weak ventilation is found in most areas of the EMDW during the last decade despite the prevailing ventilation in the Adriatic Deep Water between 2011 and 2016, which could be a result of the weakened Adriatic source intensity. The EMDW has been a mixture of the older Southern Aegean Sea dense waters formed during the Eastern Mediterranean Transient (EMT) event, and the more recent ventilated deep-water of the Adriatic origin. In the western Mediterranean basin, we found uplifting of old WMDW being replaced by the new deep-water from the Western Mediterranean Transition (WMT) event and uplifting of the new WMDW toward the Alboran Sea. The temporal variability revealed enhanced ventilation after the WMT event but slightly weakened ventilation after 2016, which could be a result of combined influences from the eastern (for the weakened Adriatic source intensity) and western (for the weakened influence from the WMT event) Mediterranean Sea. Additionally, the Mediterranean Sea is characterized by a Tracer Minimum Zone (TMZ) at mid-depth of the water column attributed to the rapid deep ventilation so that the TMZ is the slowest ventilated layer. This zone of weak ventilation stretches across the whole Mediterranean Sea from the Levantine basin into the western basin.

Version 2 of the Global Ocean Data Analysis Project (GLODAPv2) data product is composed of data from 724 scientific cruises covering the global ocean. It includes data assembled during the previous efforts GLODAPv1.1 (Global Ocean Data Analysis Project version 1.1) in 2004, CARINA (CARbon IN the Atlantic) in 2009/2010, and PACIFICA (PACIFic ocean Interior CArbon) in 2013, as well as data from an additional 168 cruises. Data for 12 core variables (salinity, oxygen, nitrate, silicate, phosphate, dissolved inorganic carbon, total alkalinity, pH, CFC-11, CFC-12, CFC-113, and CCl4) have been subjected to extensive quality control, including systematic evaluation of bias. The data are available in two formats: (i) as submitted but updated to WOCE exchange format and (ii) as a merged and internally consistent data product. In the latter, adjustments have been applied to remove significant biases, respecting occurrences of any known or likely time trends or variations. Adjustments applied by previous efforts were re-evaluated. Hence, GLODAPv2 is not a simple merging of previous products with some new data added but a unique, internally consistent data product. This compiled and adjusted data product is believed to be consistent to better than 0.005 in salinity, 1 % in oxygen, 2 % in nitrate, 2 % in silicate, 2 % in phosphate, 4 µmol kg−1 in dissolved inorganic carbon, 6 µmol kg−1 in total alkalinity, 0.005 in pH, and 5 % for the halogenated transient tracers.The original data and their documentation and doi codes are available at the Carbon Dioxide Information Analysis Center (http://cdiac.ornl.gov/oceans/GLODAPv2/). This site also provides access to the calibrated data product, which is provided as a single global file or four regional ones – the Arctic, Atlantic, Indian, and Pacific oceans – under the doi:10.3334/CDIAC/OTG.NDP093_GLODAPv2. The product files also include significant ancillary and approximated data. These were obtained by interpolation of, or calculation from, measured data. This paper documents the GLODAPv2 methods and products and includes a broad overview of the secondary quality control results. The magnitude of and reasoning behind each adjustment is available on a per-cruise and per-variable basis in the online Adjustment Table.

The North Atlantic Meridional Overturning Circulation (AMOC) ventilates a large part of the world ocean via the formation of mode waters and North Atlantic Deep Water. The extent to which human activities have impacted this ventilation system remains unclear. To assess the temporal variations of ocean ventilation in the North Atlantic, we calculated the “age\" of seawater, that is, the duration since its last contact with the ocean surface, from both observed and simulated chlorofluorocarbon-12 and sulfur hexafluoride concentrations. Our results indicate that, despite fluctuations in ventilation strength in the Labrador Sea over the past decades, the North Atlantic waters are generally aging. By integrating observations with model simulations, we propose that this aging trend is indicative of a climate change signal rather than natural variability. North Atlantic waters have been aging over the past three decades, indicating a slowdown in ocean ventilation. By combining observations with models, this slowdown is likely driven by climate change.

This study evaluates the potential usefulness of the halogenated compounds HCFC-22, HCFC-141b, HCFC-142b, HFC-134a, HFC-125, HFC-23, PFC-14, and PFC-116 as oceanographic transient tracers to better constrain ocean ventilation processes. We do this mainly in terms of four aspects of the characteristics of the potential tracers: input function (including atmospheric history and historical surface saturation), seawater solubility, feasibility of measurement, and stability in seawater; of these, atmospheric history and seawater solubility have been investigated in previous work. For the latter two aspects, we collected seawater samples and modified an established analytical technique for the Medusa–Aqua system to simultaneously measure these compounds. HCFC-22, HCFC-141b, HCFC-142b, HFC-134a, and HFC-125 have been measured in depth profiles in the Mediterranean Sea for the first time and for reproducibility in the Baltic Sea. We found that the historical surface saturation of halogenated transient tracers in the Mediterranean Sea is estimated to have been nearly constant at 94 % based on historical data. Of the investigated compounds, HCFC-142b, HCFC-141b, and HFC-134a are found to currently be the most promising transient tracers in the ocean. The compounds that have the greatest potential as future tracers are PFC-14 and PFC-116, mainly hampered by the low solubility in seawater that creates challenging analytical conditions, i.e., low concentrations. HCFC-22 is found to be likely unstable in warm seawater, which compromises the potential as an oceanic transient tracer, although it is possibly useful in colder water. For the compounds HFC-125 and HFC-23, we were not able to fully evaluate their potential as tracers due to inconclusive results, especially regarding their solubility and stability in seawater, but also with regard to potential analytical challenges. On the other hand, HFC-125, HFC-23, and HCFC-22 might not need to be considered because there are alternative tracers with similar input histories that are better suited as transient tracers.

We present a mapped climatology (GLODAPv2.2016b) of ocean biogeochemical variables based on the new GLODAP version 2 data product (Olsen et al., 2016; Key et al., 2015), which covers all ocean basins over the years 1972 to 2013. The quality-controlled and internally consistent GLODAPv2 was used to create global 1°  ×  1° mapped climatologies of salinity, temperature, oxygen, nitrate, phosphate, silicate, total dissolved inorganic carbon (TCO2), total alkalinity (TAlk), pH, and CaCO3 saturation states using the Data-Interpolating Variational Analysis (DIVA) mapping method. Improving on maps based on an earlier but similar dataset, GLODAPv1.1, this climatology also covers the Arctic Ocean. Climatologies were created for 33 standard depth surfaces. The conceivably confounding temporal trends in TCO2 and pH due to anthropogenic influence were removed prior to mapping by normalizing these data to the year 2002 using first-order calculations of anthropogenic carbon accumulation rates. We additionally provide maps of accumulated anthropogenic carbon in the year 2002 and of preindustrial TCO2. For all parameters, all data from the full 1972–2013 period were used, including data that did not receive full secondary quality control. The GLODAPv2.2016b global 1°  ×  1° mapped climatologies, including error fields and ancillary information, are available at the GLODAPv2 web page at the Carbon Dioxide Information Analysis Center (CDIAC; doi:10.3334/CDIAC/OTG.NDP093_GLODAPv2).