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7 result(s) for "Uba Zango, Muttaqa"
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Immobilization of heavy metal contaminants in mining waste through enzyme-induced calcite precipitation biocementation
The presence of heavy metals affects the properties of soil due to a decrease in the dielectric constant, which increases the risk of contamination. Current conventional treatments are costly, slower, and environmentally unsustainable. Therefore, soil biocementation improvement using enzymatically induced calcium carbonate precipitation has gained attention due to its cost-effectiveness, sustainability, and environmental friendliness. This study investigates the effect of this technique on the retention and immobilization of heavy metal-contaminated mine waste sourced from Lohan Dam, Sabah, Malaysia, under different curing periods (1 and 3 days), degrees of compactions (70 and 80% of the maximum dry density), and curing temperatures (5 °C, 15 °C, and 25 °C) but at constant 1.0M cementation solution using inductively coupled plasma-optical emission spectrometry, acid washing test, and scanning electron microscopy. Results indicate that the treatment effect is immediate and able to increase the retention of heavy metals in the order of Ni> Cu > Pb, with the highest retention observed at 25 °C and higher retention at lower degrees of compaction. SEM images confirm the formation of calcite in soil particles. In conclusion, the optimum treatment conditions for a 1.0 M EICP cementation solution are 25 °C, 70% MDD, and 1-day curing.
Review on biological process of soil improvement in the mitigation of liquefaction in sandy soil
Recently, the concept of using biological process in soil improvement otherwise called bio-mediated soil improvement technique has shown greater prospects in the mitigation of liquefiable soils. It is an environmental friendly technique that has generated great interest to geotechnical engineers. This paper presents a review on the microorganism responsible for the biological processes in soil improvement system, factors that affect biological process, identifying the mechanism of liquefaction and commonly adopted method to mitigate liquefaction. Next, the effect of microbial induced calcite precipitation (MICP) on the strength and cyclic response were also analyzed, where it was identified that higher cementation level leads to formation of larger sized calcite crystals which in turn leads to the improved shear strength, stiffness and cyclic resistance ratio of the soil. However, the effects of various bacteria, cementation reagent concentrations amongst other factors were not fully explored in most of the studies. Finally, some of the challenges that lay ahead for the emerging technology are optimizing treatment factors (bacteria and cementation reagent concentration), upscaling process, training of researchers/technologist and long – time durability of the improved soils.
Montmorillonite for Adsorption and Catalytic Elimination of Pollutants from Wastewater: A State-of-the-Arts Review
Clay minerals have been recognized as one of the cheap and effective materials for wastewater remediation. Among the various clay minerals, montmorillonite (MMT) has received much attention due to its wide availability, low-cost and promising properties such as high porosity, mechanical strength, and cation exchange capacity. Additionally, MMT has high swelling properties. These features make it an ideal material for wastewater remediation applications. In addition, it possessed good cationic exchange capacity, making it easier to interact with various molecules. MMT and its composites exhibited good selectivity and catalytic activity for contaminants elimination from wastewater. Surface modification and functionalization have been identified as a way to improve the MMT’s adsorptive performance and endow it with light and light-harnessing properties. Thus, MMT composites, especially metal and metal-oxide nanoparticles, have shown good adsorption and photocatalytic activity toward the elimination/mineralization of various contaminants such as dyes, pharmaceuticals, heavy metals, and other organic and inorganic species. As such, MMT and its composites can be adopted as potential materials for wastewater remediation.
Hydraulic conductivity and calcium carbonate content of biocemented heavy-metal contaminated mine waste soil
It is not uncommon for mining activity to generate wastes associated with negative engineering impacts include susceptibility to runoff due to the absence of vegetation, erosion, and sinkhole. Due to their high degree of permeability, movement of heavy metal contaminants in waste soils and aquifers occurs actively along with the hydrogeological parameters, and research on using biocementation methods such as enzyme induced calcite precipitation (EICP) to reduce the hydraulic conductivity is therefore beneficial. Mine waste soil collected from a copper mine in Lohan Dam, Sabah is characterized physically, morphologically, and chemically then treated with EICP under different operational parameters include curing duration (1,3,7 days), curing temperatures (5, 10, and 25 o C ), and relative density (70 and 80 %). The hydraulic conductivity was then tested using a constant head permeability test and the calcium carbonate content (%) is determined using the HCL washing method. Properties of the Lohan Dam wastes are found to be predominantly coarse grain soil of low plasticity, high specific gravity, high permeability, acidic in nature, and low organic content. Morphologically, they are composed of powdered and hardened particles with dark brown color with high amount of irregular-shaped particles. Mineralogical, Lohan Dam soil wastes contain a high level of heavy metals beyond the safety level of the Department of Environmental Malaysia. EICP treatment had to change the degree of permeability from ‘high and medium’ to ‘low’ with a 94-97% reduction in hydraulic conductivity corresponding to the amount of calcium carbonate content produced ranging 6.94-9.63%. In conclusion, relative density shows the marginal effect, curing duration, and temperature shows a more significant impact on the treatment effectiveness.
Bio-desaturation and bio-sealing techniques for mitigation of soil liquefaction: a review
Biogeotechnology is a recent area of study that deals with the improvement of engineering properties of soils in an eco-friendly and sustainable approach through the use of microorganisms. This paper first, reviewed the concept of bio-mediated soil improvement technique, components involved and the roles they played. Two processes of bio-mediation soil improvement techniques i.e. microbial-induced calcite precipitation (MICP) for producing bio-cement via ureolysis and bio-desaturation for generating specifically biogenic nitrogen gas via denitrification, their mechanisms of occurring and factors influencing them were described in details. An overview study was done on soil liquefaction. Conventional methods employed for mitigations of liquefaction hazards were reviewed and their limitations were drawn. The use of the de-saturation process for mitigation of soil liquefaction was adequately addressed. Mitigation of liquefaction using biological processes, in particular, MICP and/or bio-desaturation were introduced. The findings from the previous works have shown that both the two techniques are capable of improving liquefaction resistance of soils. Most of the results have shown that presence of biogenic nitrogen gas in soils treated with denitrifying bacteria is able to induce partial desaturation in the soil which consequently increases the cyclic shear strength, reduces pore water pressure and changes the soil behaviour from compressive to dilatant. Finally, potentials, challenges, and recommendations for future studies were identified.
Advancements in Clay Materials for Trace Level Determination and Remediation of Phenols from Wastewater: A Review
The wide spread of phenols and their toxicity in the environment pose a severe threat to the existence and sustainability of living organisms. Rapid detection of these pollutants in wastewaters has attracted the attention of researchers from various fields of environmental science and engineering. Discoveries regarding materials and method developments are deemed necessary for the effective detection and remediation of wastewater. Although various advanced materials such as organic and inorganic materials have been developed, secondary pollution due to material leaching has become a major concern. Therefore, a natural-based material is preferable. Clay is one of the potential natural-based sorbents for the detection and remediation of phenols. It has a high porosity and polarity, good mechanical strength, moisture resistance, chemical and thermal stability, and cation exchange capacity, which will benefit the detection and adsorptive removal of phenols. Several attempts have been made to improve the capabilities of natural clay as sorbent. This manuscript will discuss the potential of clays as sorbents for the remediation of phenols. The activation, modification, and application of clays have been discussed. The achievements, challenges, and concluding remarks were provided.
The Progressive Response of Sahelian Dams to Sediment Intrusion: Case of Kano State between 1976 and 2009
Reservoirs are built to store water during abundance for possible reuse during scarcity; sediment incursion is the leading phenomenon that limit reservoirs to sustain this function. Therefore, modelling the rate at which reservoir accumulates sediments is critical in understanding the nature of the problem, the time frame within which it is expected to occur, and the best mitigation strategy that will maintain the reservoir service. This study investigated the sediment influx in three typical Sahelian reservoirs in Kano state using the bathymetric method. The reservoir capacities were found to be declining at different rates but with grave consequences on the future, and economy of the state. In prolific terms, the state is losing 490 million litres of water storage each year. Presently, Magaga lost 39% of its capacity; Thomas has lost 13%; while Kafin-chiri has lost 5%. For sustainability, this trend needs to be addressed. The short and long-term best management strategies to curtail this trend have been outlined in this study.