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The Kathmandu Valley in south Asia is considered as one of the global \"hot spots\" in terms of urban air pollution. It is facing severe air quality problems as a result of rapid urbanization and land use change, socioeconomic transformation, and high population growth. In this paper, we present the first full year (February 2013–January 2014) analysis of simultaneous measurements of two short-lived climate forcers/pollutants (SLCF/P), i.e., ozone (O3) and equivalent black carbon (hereinafter noted as BC) and aerosol number concentration at Paknajol, in the city center of Kathmandu. The diurnal behavior of equivalent BC and aerosol number concentration indicated that local pollution sources represent the major contributions to air pollution in this city. In addition to photochemistry, the planetary boundary layer (PBL) and wind play important roles in determining O3 variability, as suggested by the analysis of seasonal changes of the diurnal cycles and the correlation with meteorological parameters and aerosol properties. Especially during pre-monsoon, high values of O3 were found during the afternoon/evening. This could be related to mixing and entrainment processes between upper residual layers and the PBL. The high O3 concentrations, in particular during pre-monsoon, appeared well related to the impact of major open vegetation fires occurring at the regional scale. On a synoptic-scale perspective, westerly and regional atmospheric circulations appeared to be especially conducive for the occurrence of the high BC and O3 values. The very high values of SLCF/P, detected during the whole measurement period, indicated persisting adverse air quality conditions, dangerous for the health of over 3 million residents of the Kathmandu Valley, and the environment. Consequently, all of this information may be useful for implementing control measures to mitigate the occurrence of acute pollution levels in the Kathmandu Valley and surrounding area.

Aerosol mass and the absorbing fraction are important variables, needed to constrain the role of atmospheric particles in the Earth radiation budget, both directly and indirectly through CCN activation. In particular, their monitoring in remote areas and mountain sites is essential for determining source regions, elucidating the mechanisms of long range transport of anthropogenic pollutants, and validating regional and global models. Since March 2006, aerosol mass and black carbon concentration have been monitored at the Nepal Climate Observatory-Pyramid, a permanent high-altitude research station located in the Khumbu valley at 5079 m a.s.l. below Mt. Everest. The first two-year averages of PM1 and PM1−10 mass were 1.94 μg m−3 and 1.88 μg m−3, with standard deviations of 3.90 μg m−3 and 4.45 μg m−3, respectively, while the black carbon concentration average is 160.5 ng m−3, with a standard deviation of 296.1 ng m−3. Both aerosol mass and black carbon show well defined annual cycles, with a maximum during the pre-monsoon season and a minimum during the monsoon. They also display a typical diurnal cycle during all the seasons, with the lowest particle concentration recorded during the night, and a considerable increase during the afternoon, revealing the major role played by thermal winds in influencing the behaviour of atmospheric compounds over the high Himalayas. The aerosol concentration is subject to high variability: in fact, as well as frequent \"background conditions\" (55% of the time) when BC concentrations are mainly below 100 ng m−3, concentrations up to 5 μg m−3 are reached during some episodes (a few days every year) in the pre-monsoon seasons. The variability of PM and BC is the result of both short-term changes due to thermal wind development in the valley, and long-range transport/synoptic circulation. At NCO-P, higher concentrations of PM1 and BC are mostly associated with regional circulation and westerly air masses from the Middle East, while the strongest contributions of mineral dust arrive from the Middle East and regional circulation, with a special contribution from North Africa and South-West Arabian Peninsula in post-monsoon and winter season.

This paper provides a detailed description of the atmospheric conditions characterizing the high Himalayas, thanks to continuous observations begun in March 2006 at the Nepal Climate Observatory-Pyramid (NCO-P) located at 5079 m a.s.l. on the southern foothills of Mt. Everest, in the framework of ABC-UNEP and SHARE-Ev-K2-CNR projects. The work presents a characterization of meteorological conditions and air-mass circulation at NCO-P during the first two years of activity. The mean values of atmospheric pressure, temperature and wind speed recorded at the site were: 551 hPa, −3.0 °C, 4.7 m s−1, respectively. The highest seasonal values of temperature (1.7 °C) and relative humidity (94%) were registered during the monsoon season, which was also characterized by thick clouds, present in about 80% of the afternoon hours, and by a frequency of cloud-free sky of less than 10%. The lowest temperature and relative humidity seasonal values were registered during winter, −6.3 °C and 22%, respectively, the season being characterised by mainly cloud-free sky conditions and rare thick clouds. The summer monsoon influenced rain precipitation (seasonal mean: 237 mm), while wind was dominated by flows from the bottom of the valley (S–SW) and upper mountain (N–NE). The atmospheric composition at NCO-P has been studied thanks to measurements of black carbon (BC), aerosol scattering coefficient, PM1, coarse particles and ozone. The annual behaviour of the measured parameters shows the highest seasonal values during the pre-monsoon (BC: 316.9 ng m−3, PM1: 3.9 μg m−3, scattering coefficient: 11.9 Mm−1, coarse particles: 0.37 cm−3 and O3: 60.9 ppbv), while the lowest concentrations occurred during the monsoon (BC: 49.6 ng m−3, PM1: 0.6 μg m−3, scattering coefficient: 2.2 Mm−1, and O3: 38.9 ppbv) and, for coarse particles, during the post-monsoon (0.07 cm−3. At NCO-P, the synoptic-scale circulation regimes present three principal contributions: Westerly, South-Westerly and Regional, as shown by the analysis of in-situ meteorological parameters and 5-day LAGRANTO back-trajectories. The influence of the brown cloud (AOD>0.4) extending over Indo–Gangetic Plains up to the Himalayan foothills has been evaluated by analysing the in-situ concentrations of the ABC constituents. This analysis revealed that brown cloud hot spots mainly influence the South Himalayas during the pre-monsoon, in the presence of very high levels of atmospheric compounds (BC: 1974.1 ng m−3, PM1: 23.5 μg m−3, scattering coefficient: 57.7 Mm−1, coarse particles: 0.64 cm−3, O3: 69.2 ppbv, respectively). During this season 20% of the days were characterised by a strong brown cloud influence during the afternoon, leading to a 5-fold increased in the BC and PM1 values, in comparison with seasonal means. Our investigations provide clear evidence that, especially during the pre-monsoon, the southern side of the high Himalayan valleys represent a \"direct channel\" able to transport brown cloud pollutants up to 5000 m a.s.l., where the pristine atmospheric composition can be strongly influenced.

Intense anthropogenic emissions over the Indian sub-continent lead to the formation of layers of particulate pollution that can be transported to the high altitude regions of the Himalaya-Hindu-Kush (HKH). Aerosol particles contain a substantial fraction of strongly absorbing material, including black carbon (BC), organic compounds (OC), and dust all of which can contribute to atmospheric warming, in addition to greenhouse gases. Using a 3-year record of continuous measurements of aerosol optical properties, we present a time series of key climate relevant aerosol properties including the aerosol absorption (σap) and scattering (σsp) coefficients as well as the single-scattering albedo (w0). Results of this investigation show substantial seasonal variability of these properties, with long range transport during the pre- and post-monsoon seasons and efficient precipitation scavenging of aerosol particles during the monsoon season. The monthly averaged scattering coefficients range from 0.1 Mm−1 (monsoon) to 20 Mm−1 while the average absorption coefficients range from 0.5 Mm−1 to 3.5 Mm−1. Both have their maximum values during the pre-monsoon period (April) and reach a minimum during Monsoon (July–August). This leads to dry w0 values from 0.86 (pre-monsoon) to 0.79 (monsoon) seasons. Significant diurnal variability due to valley wind circulation is also reported. Using aerosol optical depth (AOD) measurements, we calculated the resulting direct local radiative forcing due to aerosols for selected air mass cases. We found that the presence of absorbing particulate material can locally induce an additional top of the atmosphere (TOA) forcing of 10 to 20 W m−2 for the first atmospheric layer (500 m above surface). The TOA positive forcing depends on the presence of snow at the surface, and takes place preferentially during episodes of regional pollution occurring on a very regular basis in the Himalayan valleys. Warming of the first atmospheric layer is paralleled by a substantial decrease of the amount of radiation reaching the surface. The surface forcing is estimated to range from −4 to −20 W m−2 for small-scale regional pollution events and large-scale pollution events, respectively. The calculated surface forcing is also very dependent on surface albedo, with maximum values occurring over a snow-covered surface. Overall, this work presents the first estimates of aerosol direct radiative forcing over the high Himalaya based on in-situ aerosol measurements, and results suggest a TOA forcing significantly greater than the IPCC reported values for green house gases.

In spite of being located at the heart of the highest mountain range in the world, the Himalayan Nepal Climate Observatory (5079 m a.s.l.) at the Ev-K2-CNR Pyramid is shown to be affected by the advection of pollution aerosols from the populated regions of southern Nepal and the Indo-Gangetic plains. Such an impact is observed along most of the period April 2006–March 2007 addressed here, with a minimum in the monsoon season. Backtrajectory-analysis indicates long-range transport episodes occurring in this year to originate mainly in the west Asian deserts. At this high altitude site, the measured aerosol optical depth is observed to be about one order of magnitude lower than the one measured at Ghandi College (60 m a.s.l.), in the Indo-Gangetic basin. As for Ghandi College, and in agreement with the in situ ground observations at the Pyramid, the fine mode aerosol optical depth maximizes during winter and minimizes in the monsoon season. Conversely, total optical depth maximizes during the monsoon due to the occurrence of elevated, coarse particle layers. Possible origins of these particles are wind erosion from the surrounding peaks and hydrated/cloud-processed aerosols. Assessment of the aerosol radiative forcing is then expected to be hampered by the presence of these high altitude particle layers, which impede an effective, continuous measurement of anthropogenic aerosol radiative properties from sky radiance inversions and/or ground measurements alone. Even though the retrieved absorption coefficients of pollution aerosols were rather large (single scattering albedo of the order of 0.6–0.9 were observed in the month of April 2006), the corresponding low optical depths (~0.03 at 500 nm) are expected to limit the relevant radiative forcing. Still, the high specific forcing of this aerosol and its capability of altering snow surface albedo provide good reasons for continuous monitoring.

Tropospheric ozone (O 3 ) is an important atmospheric pollutant and climate forcer. The Mediterranean basin is a hot-spot region in terms of short-term O 3 distribution, with frequent episodes of high tropospheric O 3 , especially during summer. To improve the characterisation of summer O 3 variability in the Mediterranean area, during the period 6–27 August 2009 an experimental campaign was conducted at Campo Imperatore, Mt Portella (CMP), a high mountain site (2,388 m a.s.l.) located in the central Italian Apennines. As deduced from analysis of atmospheric circulation, the measurement site was significantly affected by air masses originating over the Mediterranean basin, which affected the measurement site for 32 % of the time. Analysis of average values and diurnal and day-to-day variability revealed that CMP O 3 observations (average value 60.0 ± 5.1 ppbv) were comparable with measurements at other European mountain stations, indicating a prevalent effect of meteorological conditions and atmospheric transport on the synoptic scale. In fact, only a small “reverse” diurnal variation typically characterises diurnal O 3 variability because of local thermal wind circulation, which sporadically favours transport of air masses rich in O 3 from the foothill regions. Statistical analysis of five-day back-trajectory ensembles indicates that synoptic-scale air-mass transport from the Mediterranean Sea usually results in decreasing O 3 concentrations at CMP, whereas the highest hourly O 3 values are mostly associated with air masses from central continental Europe, eastern Europe, and northern Italy. High O 3 concentrations are also related to downward air-mass transport from higher altitudes. Comparison of in-situ O 3 variability with tropospheric O 3 satellite-based measurements reveals similar features of the two data sets. Together with the results from back-trajectory analysis, this indicates that CMP measurements might usefully improve characterisation of broad-scale O 3 variability over the central Mediterranean basin.

We present and compare 11 years of snow data (snow depth and snow water equivalent, SWE) measured by an automatic weather station (AWS) and corroborated by data from field campaigns on the Forni Glacier in Italy. The aim of the analysis is to estimate the SWE of new snowfall and the annual SWE peak based on the average density of the new snow at the site (corresponding to the snowfall during the standard observation period of 24 h) and automated snow depth measurements. The results indicate that the daily SR50 sonic ranger measurements and the available snow pit data can be used to estimate the mean new snow density value at the site, with an error of ±6 kg m−3. Once the new snow density is known, the sonic ranger makes it possible to derive SWE values with an RMSE of 45 mm water equivalent (if compared with snow pillow measurements), which turns out to be about 8 % of the total SWE yearly average. Therefore, the methodology we present is interesting for remote locations such as glaciers or high alpine regions, as it makes it possible to estimate the total SWE using a relatively inexpensive, low-power, low-maintenance, and reliable instrument such as the sonic ranger.

Over the course of six years (2006-2011), equivalent black carbon (eqBC), coarse aerosol mass (PM1-10), and surface ozone (O3), observed during the monsoon onset period at the Nepal Climate Observatory-Pyramid WMO GAW Global Station (NCO-P, 5079 m a.s.l.), were analyzed to investigate events characterized by a significant increase in these short-lived climate forcers pollutants (SLCF P). These events occurred during periods characterized by low (or nearly absent) rain precipitation in the central Himalayas, and they appeared to be related to weakening stages (or 'breaking') of the South Asian summer monsoon system. As revealed by the combined analysis of atmospheric circulation, air-mass three-dimensional back trajectories, and satellite measurements of atmospheric aerosol loading, surface open fire, and tropospheric NO x , the large amount of SLCF P reaching the NCO-P appeared to be related to natural (mineral dust) and anthropogenic emissions occurring within the PBL of central Pakistan (i.e., Thar Desert), the Northwestern Indo-Gangetic plain, and the Himalayan foothills. The systematic occurrence of these events appeared to represent the most important source of SLCF P inputs into the central Himalayas during the summer monsoon onset period, with possible important implications for the regional climate and for hydrological cycles.

The transcriptome-wide endosperm-preferred expression of maize genes was addressed by analyzing a large database of expressed sequence tags (ESTs). We generated 30,531 high quality sequence-reads from the 5'-ends of cDNA libraries from maize endosperm harvested at 10, 15, and 20 days after pollination. A further 196,900 maize sequence-reads retrieved from public databases were added to this endosperm collection to generate MAIZEST, a database with tools for data storage and analysis. MAIZEST contains 227,431 ESTs, one third of which represents developing endosperm and the remaining two-thirds represent transcripts from 49 cDNA libraries constructed from different organs and tissues. Assembling the MAIZEST ESTs generated 29,206 putative transcripts, of which a set of 4032 assembled sequences was composed exclusively of sequences derived from endosperm cDNA libraries. After sequence analysis using overlapping parameters, a sub-set of 2403 assembled sequences was functionally annotated and revealed a wide variety of putative new genes involved in endosperm development and metabolism.