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Information on geomagnetic field intensity in the past is essential for understanding the behavior and mechanism of the geodynamo. A fundamental unresolved problem of relative paleointensity (RPI) estimations from marine sediments is that changes in the constituents of magnetic mineral assemblages may influence RPI estimations, called lithological contamination. A negative correlation between RPI and the ratio of anhysteretic remanent magnetization (ARM) susceptibility to saturation isothermal remanent magnetization ( k ARM /SIRM), which is a proxy for the proportion of magnetofossils to detrital magnetic minerals, was previously reported from deep-sea sediments. This could be caused by lower RPI recording efficiency of the magnetofossil component than the detrital component. To elaborate further this issue, we have conducted a paleo- and rock magnetic study of a sediment core taken from the central north Pacific. RPI estimated from a slope in a diagram plotting a pair of natural remanent magnetization (NRM) and ARM at each alternating-field demagnetization step (NRM-ARM demagnetization diagram) has a negative correlation with k ARM /SIRM. Principal component analysis of first-order reversal curve diagrams indicates a downcore increase of the magnetofossil proportion with increased k ARM /SIRM. These results reinforce the lower RPI recording efficiency of magnetofossils. In this core, the magnetic coercivity ranges of the magnetofossil and detrital components overlap, which produces a linear NRM-ARM demagnetization diagram. This hinders a possibility of obtaining uncontaminated RPI from a coercivity window representing the magnetofossils or detrital magnetic components, which was tried by some previous studies. A linear NRM-ARM demagnetization diagram, which was sometimes used as a criterion of reliable RPI estimations, does not necessarily mean the absence of lithological contamination to the RPI. In sediments with changing proportion of magnetofossils, normalization with IRM may work better than ARM. Graphical Abstract

Chemical stratigraphy is useful for dating deep-sea sediments, which sometimes lack radiometric or biostratigraphic constraints. Oxic pelagic clay contains Fe–Mn oxyhydroxides that can retain seawater 187Os/188Os values, and its age can be estimated by fitting the isotopic ratios to the seawater 187Os/188Os curve. On the other hand, the stability of Fe–Mn oxyhydroxides is sensitive to redox change, and it is not clear whether the original 187Os/188Os values are always preserved in sediments. However, due to the lack of independent age constraints, the reliability of 187Os/188Os ages of pelagic clay has never been tested. Here we report inconsistency between magnetostratigraphic and 187Os/188Os ages in pelagic clay around Minamitorishima Island. In a ~ 5-m-thick interval, previous studies correlated 187Os/188Os data to a brief (< 1 million years) isotopic excursion in the late Eocene. Paleomagnetic measurements revealed at least 12 polarity zones in the interval, indicating a > 2.9–6.9 million years duration. Quartz and feldspars content showed that while the paleomagnetic chronology gives reasonable eolian flux estimates, the 187Os/188Os chronology leads to unrealistically high values. These results suggest that the low 187Os/188Os signal has diffused from an original thin layer to the current ~ 5-m interval, causing an underestimate of the deposition duration. The preservation of the polarity patterns indicates that a mechanical mixing such as bioturbation cannot be the main process for the diffusion, so diagenetic redistribution of Fe–Mn oxyhydroxides and associated Os may be responsible. The paleomagnetic chronology presented here also demands reconsiderations of the timing, accumulation rate, and origins of the high content of rare-earth elements and yttrium in pelagic clay around Minamitorishima Island.

Red clay widely occupies the seafloor of pelagic environments in middle latitudes, and potentially preserves long paleoceanographic records. We conducted a rock-magnetic study of Pacific Ocean red clay to elucidate paleoenvironmental changes. Three piston cores from the western North Pacific Ocean and IODP Hole U1365A cores in the South Pacific Ocean were studied here. Principal component analyses applied to first-order reversal curve diagrams (FORC-PCA) reveals three magnetic components (endmembers EM1 through EM3) in a core of the western North Pacific. EM1, which represents the features of interacting single-domain (SD) and vortex states, is interpreted to be of terrigenous origin. EM2 and EM3 are carried by non-interacting SD grains with different coercivity distributions, which are interpreted to be of biogenic origin. The EM1 contribution suddenly increases upcore at a depth of ~ 2.7 m, which indicates increased eolian dust input. The age of this event is estimated to be around the Eocene–Oligocene (E/O) boundary. Transmission electron microscopy reveals that EM2 is dominated by magnetofossils with equant octahedral morphology, while EM3 has a higher proportion of bullet-shaped magnetofossils. An increased EM3 contribution from ~ 6.7 to 8.2 m suggests that the sediments were in the oxic–anoxic transition zone (OATZ), although the core is oxidized in its entire depth now. The chemical conditions of OATZ may have been caused by higher biogenic productivity near the equator. FORC-PCA of Hole U1365A cores identified two EMs, terrigenous (EM1) and biogenic (EM2). The coercivity distribution of the biogenic component at Hole U1365A is similar to that of the lower coercivity biogenic component in the western North Pacific. A sudden upcore terrigenous-component increase is also evident at Hole U1365A with an estimated age around the E/O boundary. The increased terrigenous component may have been caused by the gradual tectonic drift of the sites on the lee of arid continental regions in Asia and Australia, respectively. Alternatively, the eolian increase may have been coeval in the both hemispheres and associated with the global cooling at the E/O boundary.

Construction of regional geomagnetic secular variation curves for the last several tens of thousands of years is important for understanding the behavior of non-dipole fields and applications to geochronology. Around Japan, secular variation records of older than 10 ka was scarce, in particular for relative paleointensity (RPI). Here, we conducted a paleomagnetic study of a sediment core covering the last ~ 40 kyr taken from a small basin in the Nankai Trough. The core consists of homogenous hemipelagic sediments except for turbidites and volcanic ashes. The age model was constructed based on seven 14 C datings and two volcanic ashes. Turbidites and volcanic ashes were excluded from the construction of secular variation curves because of geologically instantaneous deposition. It was revealed that the magnetization of this core is carried largely by detrital magnetic minerals, although magnetofossils are also contained. Bulk magnetic properties show some temporal changes in magnetic concentration and grain size, but still homogeneous enough for reliable RPI estimations except for turbidites and volcanic ashes. The resultant RPI shows no correlation with the normalizer, anhysteretic remanent magnetization, of the RPI estimations or with a proxy for a magnetic grain size and/or the proportion of magnetofossils to detrital magnetic minerals. The obtained RPI record shows a long-term increasing trend since ~ 40 ka, which coincides with global stack curves. On the other hand, there are some differences in shorter timescale variations, which may reflect non-dipole fields. This study demonstrated that hemipelagic sediments in the Nankai Trough have potential for recovering high-quality RPI records when turbidites and volcanic ashes were excluded and are useful for accumulating records to construct a regional master curve. Graphical abstract

True polar wander (TPW), or planetary reorientation, is well documented for other planets and moons and for Earth at present day with satellites, but testing its prevalence in Earth’s past is complicated by simultaneous motions due to plate tectonics. Debate has surrounded the existence of Late Cretaceous TPW ca. 84 million years ago (Ma). Classic palaeomagnetic data from the Scaglia Rossa limestone of Italy are the primary argument against the existence of ca. 84 Ma TPW. Here we present a new high-resolution palaeomagnetic record from two overlapping stratigraphic sections in Italy that provides evidence for a ~12° TPW oscillation from 86 to 78 Ma. This observation represents the most recent large-scale TPW documented and challenges the notion that the spin axis has been largely stable over the past 100 million years. The authors present a high-resolution palaeomagnetic record for a Late Cretaceous limestone in Italy. They claim that their record robustly shows a ~12° true polar wander oscillation between 86 and 78 Ma, with the greatest excursion at 84–82 Ma.

Reconstructing the history of Philippine Sea (PHS) plate motion is important for better understanding of the tectonics of the surrounding plates. It is generally considered that the PHS plate migrated northward since Eocene, but its rotation has not been constrained well; some reconstructions incorporated a large clockwise rotation but others did not. This is mainly because the difficulty of collecting oriented rocks from the mostly submerged PHS plate hindered establishing an apparent polar wander path. In this study, we conducted a paleomagnetic study of oriented cores taken using an ROV-based coring apparatus from the Hyuga Seamount on the northern part of the Kyushu-Palau Ridge, a remnant arc in the stable interior of the PHS plate. Stepwise thermal and alternating-field demagnetizations were applied to specimens taken successively from two ~ 30 cm long limestone cores of middle to late Oligocene age, and characteristic remanent magnetization directions could be isolated. Declination and inclination of D = 51.5° and I = 39.8°, respectively, were obtained as the mean of the two cores. The easterly-deflected declination means ~ 50° clockwise rotation of the PHS plate since middle to late Oligocene. In addition, ~ 5° latitudinal change of the site is estimated from the mean inclination. The result implies that the Kyushu-Palau Ridge was located to the southwest of the present position in middle to late Oligocene, and that PHS plate rotation as well as the Shikoku and Parece Vela Basin spreading contributed to the eastward migration of the Izu-Ogasawara (Bonin) Arc to the current position.

The mineralogy of atmospheric silicate dust controls its interaction with clouds. K-feldspar has a remarkably high ice-nucleating activity, and its distribution may have influenced the global climate throughout Earth's history. However, long-term archives of past atmospheric feldspar are not known. Here, we investigate feldspar mineralogy, content, and grain size in pelagic clay cores. Sediments around Minamitorishima Island contain > 10 wt% of K-feldspar before ~ 35 Ma, which is five times more than the younger sediments. This distribution does not resemble other volcanic minerals or geochemically estimated volcanic input, suggesting that the K-feldspars are not associated with volcanic ash. The K-feldspars are present as isolated grains as well as pseudorhombohedral microcrystals indicative of authigenic overgrowth. On the other hand, they contain some Na, arguing against a purely authigenic origin. Grain size distributions of chemically separated quartz and feldspars show stratigraphic variation analogous to other North Pacific sites, further suggesting a link to eolian materials. Sediments from a South Pacific site also show K-feldspar enrichment over plagioclase before ~ 44 Ma, although the content relative to bulk sediment does not change much. We propose that the K-feldspar may be enriched in the wide area of the Pacific before ~ 30 to 40 Ma.

The existence of missing geomagnetic reversals has been proposed, with potential for new magnetostratigraphic age controls. We estimate geomagnetic reversal frequency from 0 to 155 Ma using adaptive‐bandwidth kernel density estimation (AKDE) to evaluate data sparseness and to assess how reversal frequency changes when recently identified geomagnetic reversals are incorporated into the geomagnetic polarity time scale (GPTS) data set. AKDE is a two‐stage procedure that uses an initial density estimator based on an initial (pilot) bandwidth. We found that the pilot bandwidth determined using cross‐validation is stable with respect to data set length. The AKDE results obtained based on the cross‐validated pilot bandwidth reveal four troughs after the Cretaceous Normal Superchron, spaced 13.5–15.0 Myr apart and corresponding to relatively long chrons (>0.8 Myr). One trough near 32 Ma becomes less distinct after the four recently identified reversals are added to the data set. This sensitivity suggests that troughs in the frequency curve may indicate missing geomagnetic reversals.

Atmospheric carbon dioxide concentrations and climate are regulated on geological timescales by the balance between carbon input from volcanic and metamorphic outgassing and its removal by weathering feedbacks; these feedbacks involve the erosion of silicate rocks and organic-carbon-bearing rocks. The integrated effect of these processes is reflected in the calcium carbonate compensation depth, which is the oceanic depth at which calcium carbonate is dissolved. Here we present a carbonate accumulation record that covers the past 53 million years from a depth transect in the equatorial Pacific Ocean. The carbonate compensation depth tracks long-term ocean cooling, deepening from 3.0–3.5 kilometres during the early Cenozoic (approximately 55 million years ago) to 4.6 kilometres at present, consistent with an overall Cenozoic increase in weathering. We find large superimposed fluctuations in carbonate compensation depth during the middle and late Eocene. Using Earth system models, we identify changes in weathering and the mode of organic-carbon delivery as two key processes to explain these large-scale Eocene fluctuations of the carbonate compensation depth. A detailed reconstruction of the calcium carbonate compensation depth—at which calcium carbonate is dissolved—in the equatorial Pacific Ocean over the past 53 million years shows that it tracks ocean cooling, increasing as the ocean cools. A history of carbon cycles and climate change The carbonate compensation depth — the oceanic depth at which carbonate is dissolved — reflects the amount of carbon dioxide present in the atmosphere, and thus gives clues about climate on geological timescales. This paper reports a detailed reconstruction of the carbonate compensation depth in the equatorial Pacific over the past 53 million years. The compensation depth is found to track ocean cooling, deepening from 3.0–3.5 kilometres during the early Cenozoic (56–53 million years ago) to 4.6 kilometres today. Rapid fluctuations observed in the carbonate compensation depth around 46–34 million years ago could be explained, in part, by changes in weathering and in the type of organic carbon supplied to the sea floor.

The ocean may have played a central role in the atmospheric p CO 2 rise during the last deglaciation. However, evidence on where carbon was exchanged between the ocean and the atmosphere in this period is still lacking, hampering our understanding of global carbon cycle on glacial–interglacial timescales. Here we report a new surface seawater p CO 2 reconstruction for the western equatorial Pacific Ocean based on boron isotope analysis—a seawater p CO 2 proxy—using two species of near-surface dwelling foraminifera from the same marine sediment core. The results indicate that the region remained a modest CO 2 sink throughout the last deglaciation.