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The mechanical properties of a coal–rock body were examined through uniaxial compression tests, and the rupture process of the coal–rock body was monitored in real time using a combined acoustic emission (AE) monitoring system and a digital image correlation (DIC) full-field strain measurement system. From a comparison of the mechanical properties of coal and sandstone, clear differences are apparent regarding the uniaxial compressive strength, deformation characteristics, and damage mode; the brittle failure characteristics of the coal samples are also more evident. The change in AE energy reflects the accumulation and release of elastic energy during the rupture process, and the evolution of AE localization points under different stress levels can effectively reflect rupture propagation. Further, the DIC full-field strain measurement method can quantitatively monitor the evolution of the displacement and strain fields at the marking point and surface simultaneously, thereby overcoming the limitations of traditional empirical and qualitative rupture processes. During monitoring, the AE focuses on the internal rupture of the specimen and the DIC focuses on the surface deformation. These complement each other and reflect the rupture process more comprehensively.

HighlightsThrough facial basicity adjustment, kinetically favorable ZnxNi1-xO@CF electrode was formed with a high density hierarchical structure and three dimensional open pores.The optimal Zn-doping ratio in ZnxNi1-xO@CF has excellent sodium storage and desalination performance (128.9 mg g-1).The mechanism of Na+ intercalation process was studied by electrochemical quartz crystal microbalance with dissipation monitoring in situ test and the activation mechanism of redox-inert Zn-doping on electrode materials was reported.Despite the promising potential of transition metal oxides (TMOs) as capacitive deionization (CDI) electrodes, the actual capacity of TMOs electrodes for sodium storage is significantly lower than the theoretical capacity, posing a major obstacle. Herein, we prepared the kinetically favorable ZnxNi1 − xO electrode in situ growth on carbon felt (ZnxNi1 − xO@CF) through constraining the rate of OH− generation in the hydrothermal method. ZnxNi1 − xO@CF exhibited a high-density hierarchical nanosheet structure with three-dimensional open pores, benefitting the ion transport/electron transfer. And tuning the moderate amount of redox-inert Zn-doping can enhance surface electroactive sites, actual activity of redox-active Ni species, and lower adsorption energy, promoting the adsorption kinetic and thermodynamic of the Zn0.2Ni0.8O@CF. Benefitting from the kinetic-thermodynamic facilitation mechanism, Zn0.2Ni0.8O@CF achieved ultrahigh desalination capacity (128.9 mgNaCl g−1), ultra-low energy consumption (0.164 kW h kgNaCl−1), high salt removal rate (1.21 mgNaCl g−1 min−1), and good cyclability. The thermodynamic facilitation and Na+ intercalation mechanism of Zn0.2Ni0.8O@CF are identified by the density functional theory calculations and electrochemical quartz crystal microbalance with dissipation monitoring, respectively. This research provides new insights into controlling electrochemically favorable morphology and demonstrates that Zn-doping, which is redox-inert, is essential for enhancing the electrochemical performance of CDI electrodes.

The intercalation strategy has become crucial for 2D layered materials to achieve desirable properties, however, the intercalated guests are often limited to metal ions or small molecules. Here, we develop a simple, mild and efficient polymer-direct-intercalation strategy that different polymers (polyethyleneimine and polyethylene glycol) can directly intercalate into the MoS 2 interlayers, forming MoS 2 -polymer composites and interlayer-expanded MoS 2 /carbon heteroaerogels after carbonization. The polymer-direct-intercalation behavior has been investigated by substantial characterizations and molecular dynamic calculations. The resulting composite heteroaerogels possess 3D conductive MoS 2 /C frameworks, expanded MoS 2 interlayers (0.98 nm), high MoS 2 contents (up to 74%) and high Mo valence (+6), beneficial to fast and stable charge transport and enhanced pseudocapacitive energy storage. Consequently, the typical MoS 2 /N-doped carbon heteroaerogels exhibit outstanding supercapacitor performance, such as ultrahigh capacitance, remarkable rate capability and excellent cycling stability. This study offers a new intercalation strategy which may be generally applicable to 2D materials for promising energy applications. Methods to fabricate layered materials are often associated with harsh conditions and complicated manipulations. Here the authors report a polymer-direct-intercalation strategy to synthesize composite heteroaerogels consisting of molybdenum sulfide/carbon nanosheets for high-capacitance supercapacitors.

Lithium manganese oxides are considered as promising cathodes for lithium‐ion batteries due to their low cost and available resources. Layered LiMnO2 with orthorhombic or monoclinic structure has attracted tremendous interest thanks to its ultrahigh theoretical capacity (285 mAh g−1) that almost doubles that of commercialized spinel LiMn2O4 (148 mAh g−1). However, LiMnO2 undergoes phase transition to spinel upon cycling cause by the Jahn‐Teller effect of the high‐spin Mn3+. In addition, soluble Mn2+ generates from the disproportionation of Mn3+ and oxygen release during electrochemical processes may cause poor cycle performance. To address the critical issues, tremendous efforts have been made. This paper provides a general review of layered LiMnO2 materials including their crystal structures, synthesis methods, structural/elemental modifications, and electrochemical performance. In brief, first the crystal structures of LiMnO2 and synthetic methods have been summarized. Subsequently, modification strategies for improving electrochemical performance are comprehensively reviewed, including element doping to suppress its phase transition, surface coating to resist manganese dissolution into the electrolyte and impede surface reactions, designing LiMnO2 composites to improve electronic conductivity and Li+ diffusion, and finding compatible electrolytes to enhance safety. At last, future efforts on the research frontier and practical application of LiMnO2 have been discussed. A LiMnO2 cathode with high theoretical capacity shows great commercial value due to its low price and nontoxicity. This review summarizes the overall progress and challenges of LiMnO2, focusing on crystallographic structures, synthesis and modifications like element doping, surface coating, composites designing, and electrolytes matching for electrochemical performance improvement. Future perspectives on the research frontier and practical application are also discussed.

The Bowen ratio (β) comprehensively reflects physical characteristics of the land-surface climate. In this study, eddy covariance systems installed at Dingxi and Qingyang were used to conduct energy distribution measurements and observations characteristic of semi-arid and semi-humid farmland ecosystems on the China Loess Plateau. We studied mechanisms by which eco-environmental factors influence β. Additionally, we investigated responses of physiological and ecological factors to water and heat exchange under seasonally dry and wet conditions within each farmland ecosystem. Our results showed that sensible heat flux in the semi-arid farmland was the main consumer of available energy. In the semi-humid area, latent heat flux in summer had the dominant role in energy distribution (mean β 0.71). The β in the semi-arid region was 1.5 times higher than that in the semi-humid region during the growing season. β increased with an increase in the vapor pressure deficit (VPD) and ground–air temperature difference (Ts − Ta), and decreased significantly with an increase in effective precipitation and soil moisture. The change in β with environmental factors was more clear-cut in semi-arid areas than in semi-humid areas. The Priestley–Taylor coefficient (α) and β satisfied a power function law in the growing season. There was a strong correlation between them, with the coefficients of determination for semi-humid and semi-arid areas being 0.62 and 0.72, respectively. β decreased with an increase in the normalized difference vegetative index (NDVI), with this phenomenon being more obvious in the semi-humid zone (R2 = 0.40). β responded more rapidly to NDVI in the semi-arid area than in the semi-humid area. There was a negative exponential relationship between canopy stomatal conductance (Gs) and β, which displayed a stronger declining trend with the increase in Gs in the semi-arid area than in the semi-humid area. This study provides an important reference for the determination of land-surface characteristics of semi-arid and semi-humid farmland ecosystems on the Loess Plateau and for improving parameterization of land-surface processes.

During the second half of the 20th century, eastern Northwest China experienced a warming and drying climate change. To determine whether this trend has continued or changed during the present century, this study systematically analyzes the characteristics of warming and dry–wet changes in eastern Northwest China based on the latest observational data and World Climate Research Programme (WCRP) Coupled Model Intercomparison Project Phase 6 (CMIP6) collection data. The results show that eastern Northwest China has warmed continuously during the past 60 years with a sudden temperature change occurring in the late 1990s. However, the temperature in the 2000s decreased slowly, and that in the 2010s showed a warming trend. The amount of precipitation began to increase in the late 1990s, which indicates a contemporary climate transition from warm-dry to warm-wet in eastern Northwest China. The contribution of precipitation to humidity is significantly more than that of temperature. Long-term and interannual variations dominate the temperature change, with the contribution of the former much stronger than that of the latter. However, interannual variation dominates the precipitation change. The warming accelerates from period to period, and the temperature spatial consistently increased during the three most recent climatic periods. The precipitation decreased from 1961–1990 to 1981–2010, whereas its spatial consistency increased from 1981–2010 to 1991–2019. The significant warming and humidification which began in the late 1990s and is expected to continue until the end of the 21st century in the medium emission scenario. However, the current sub-humid climate will not easily be changed. The warming could cause a climate transition from warm temperate to subtropical by 2040. The dry-to-wet climate transition in eastern Northwest China could be related to a synergistic enhancement of the East Asian summer monsoon and the westerly circulation. This research provides a scientific decision-making basis for implementing western development strategies, ecological protection, and high-quality development of the Yellow River Basin Area as well as that for ecological construction planning and water resource management of eastern Northwest China.

Aero-engine combustors may experience extreme low pressures in the case of an in-flight shutdown, which makes the study of aviation kerosene flame propagation characteristics at low pressures important. The present work examined flame propagation during the combustion of aviation kerosene over the pressure range from 25 to 100 kPa using a constant-volume bomb apparatus. The laminar burning speeds at different initial pressures, temperatures and equivalence ratios were measured and compared. In addition, numerical simulations were used to examine the reaction sensitivity of the laminar burning speed at low pressure. In trials at the lean flammability limit, the data indicated that it was more difficult to ignite the fuel under a lower pressure condition of 25 kPa and a lower temperature condition of 420 K. The experimental results of laminar burning speed were fitted to an equation providing the laminar burning speeds expected at different pressures (25–100 kPa), temperatures (400–480 K) and equivalence ratios (0.8–1.5). The temperature index (α=1.76) and pressure index (β=−0.15) of the fitting equation were obtained. Both hydrodynamic and diffusional thermal flame instabilities were found to be suppressed at low pressures. The negative effects of two specific reactions on laminar burning speed were greatly reduced at these same low pressures of 25 kPa.

Evapotranspiration (ET) is the most significant constituent of the response to climate warming. It serves as a crucial link in the soil–vegetation–atmospheric continuum. Analyzing the driving forces and response of ET to regional-scale climate warming holds scientific significance in improving global water resource assessment methods and drought monitoring techniques. The innovation presented in this article is the calculation of ET by using GRACE/GRACE-FO satellite data through the water balance equation. The inter-annual and seasonal changes in ET in different regions of the Qilian Mountains were analyzed, along with quantifying the contribution of environmental meteorological factors to ET. The ETGRACE and ETMonitor products have good consistency, with a monthly correlation coefficient of 0.92, an NSE coefficient of 0.80, and a root mean square error of 10.38 mm. The results indicate that the increasing trend of ET in the Qilian Mountains region exhibits a “medium–high–low” distribution pattern. The rate of increase in ET is 5.2 mm/year in the central segment. In spring and summer, the overall trend of ET is an increasing one. However, the central and western segments exhibit a slight decreasing trend of ET in autumn. During winter, the southern part of the Qilian Mountains experiences a notable reduction in ET. The correlation between the changes in ET and soil moisture exhibited a strong association, with soil moisture change contributing significantly to ET: 57.8% for the eastern section, 52.8% for the middle section, and 46.9% for the western section. The thermal effect primarily controls ET variations within eastern sections, where temperature change accounts for approximately 6.7% of the total variation in ET levels. Conversely, the moisture factor dominates western sections, where precipitation change accounts for about 6.5% of the total variation in ET levels. Due to the distinct gradient characteristics of environmental meteorological factors in the central segment, the fluctuation of these factors collaboratively drives ET changes. This article provides a new approach for obtaining continuous and reliable actual evapotranspiration in high-altitude areas.

The temporal and spatial characteristics of drought disasters in Southern China were analyzed by using the daily observation data from 252 meteorological stations and drought disaster data in 14 provinces, autonomous regions, and municipalities of Southern China during 1961–2015. The characteristics of drought disaster risk were determined, and the countermeasures for prevention and control were also suggested. The results showed that the annual precipitation fluctuated and has no obvious linear trend in Southern China in the past 55 years. However, the average annual precipitation decreased significantly and its oscillation amplitude is increasing in the early twenty-first century. The annual average temperature exhibited a significant upward trend in these years in the research area. The increasing rate was even higher than the global means. The temperature has increased since 1976, and an abrupt change was occurred in 1997. Area with high risk of drought was concentrated mainly in Southwest China. With the climatic warming, the drought frequency and intensity and the drought-affected areas have been increasing, as well as the risk of drought disaster. The risk area of secondary highest drought disaster expanded dramatically after 1997. In the future, the occurrence of droughts may increase in Southern China. Therefore, it is necessary to enhance risk management for drought disasters by implementing eco-environmental modifications in the vulnerable areas, as well as ensuring food security in the agricultural production areas, addressing the uneven spatial and temporal distributions of water resources and the discrepancy between supply and demand, and enhancing the prevention and control of drought disaster risk.

After successfully growing single-crystal TaP, we measured its longitudinal resistivity （Pxx） and Hall resistivity （Pyx） at magnetic fields up to 9 T in the temperature range of 2-300 K. At 8 T, the magnetoresistance （MR） reached 3.28 ×10^5% at 2 K, 176% at 300 K. Neither value appeared saturated. We confirmed that TaP is a hole-electron compensated semimetal with a low carrier concentration and high hole mobility ofμh=3.71 × 105 cm2/V s, and found that a magnetic-field-induced metal-insulator transition occurs at room temperature. Remarkably, because a magnetic field （H） was applied in parallel to the electric field （E）, a negative MR due to a chiral anomaly was observed and reached -3000% at 9 T without any sign of saturation, either, which is in contrast to other Weyl semimetals （WSMs）. The analysis of the Shubnikov-de Haas （SdH） oscillations superimposed on the MR revealed that a nontrivial Berry＇s phase with a strong offset of 0.3958, which is the characteristic feature of charge carriers enclosing a Weyl node. These results indicate that TaP is a promising candidate not only for revealing fundamental physics of the WSM state but also for some novel applications.