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Polymer-ceramic piezoelectric composites, combining high piezoelectricity and mechanical flexibility, have attracted increasing interest in both academia and industry. However, their piezoelectric activity is largely limited by intrinsically low crystallinity and weak spontaneous polarization. Here, we propose a Ti 3 C 2 T x MXene anchoring method to manipulate the intermolecular interactions within the all- trans conformation of a polymer matrix. Employing phase-field simulation and molecular dynamics calculations, we show that OH surface terminations on the Ti 3 C 2 T x nanosheets offer hydrogen bonding with the fluoropolymer matrix, leading to dipole alignment and enhanced net spontaneous polarization of the polymer-ceramic composites. We then translated this interfacial bonding strategy into electrospinning to boost the piezoelectric response of samarium doped Pb (Mg 1/3 Nb 2/3 )O 3 -PbTiO 3 /polyvinylidene fluoride composite nanofibers by 160% via Ti 3 C 2 T x nanosheets inclusion. With excellent piezoelectric and mechanical attributes, the as-electrospun piezoelectric nanofibers can be easily integrated into the conventional shoe insoles to form a foot sensor network for all-around gait patterns monitoring, walking habits identification and Metatarsalgi prognosis. This work utilizes the interfacial coupling mechanism of intermolecular anchoring as a strategy to develop high-performance piezoelectric composites for wearable electronics. The piezoelectricity of PVDF composites is mainly determined by the crystalline phases and spontaneous polarization. Here, the authors propose a Ti 3 C 2 T x anchoring method to modulate the molecular interactions and conformation of polymer matrix.

The discovery of ultrahigh piezoelectricity in relaxor-ferroelectric solid solution single crystals is a breakthrough in ferroelectric materials. A key signature of relaxor-ferroelectric solid solutions is the existence of polar nanoregions, a nanoscale inhomogeneity, that coexist with normal ferroelectric domains. Despite two decades of extensive studies, the contribution of polar nanoregions to the underlying piezoelectric properties of relaxor ferroelectrics has yet to be established. Here we quantitatively characterize the contribution of polar nanoregions to the dielectric/piezoelectric responses of relaxor-ferroelectric crystals using a combination of cryogenic experiments and phase-field simulations. The contribution of polar nanoregions to the room-temperature dielectric and piezoelectric properties is in the range of 50–80%. A mesoscale mechanism is proposed to reveal the origin of the high piezoelectricity in relaxor ferroelectrics, where the polar nanoregions aligned in a ferroelectric matrix can facilitate polarization rotation. This mechanism emphasizes the critical role of local structure on the macroscopic properties of ferroelectric materials. Combining a perovskite ferroelectric with moderate piezoelectric properties and a nonpiezoelectric pervoskite relaxor can create a highly piezoelectric material. Here, the authors help explain this unusual result by quantifying how polar nanoregions in the material contribute to its piezoelectric response.

Formation of the Tibetan Plateau is generally ascribed to the Cenozoic India–Asia collision. However, the origin of along-strike deformation of the Indian mantle lithosphere, especially beneath the eastern Tibetan Plateau region, and its effect on the plateau’s eastward growth remain unclear. Here, we conduct multiscale seismic tomography to provide a revised structure of the Indian mantle lithosphere beneath the eastern Tibetan Plateau region. Our results demonstrate that the Indian mantle lithosphere is currently torn vertically along ~26° N, with its northern portion shallowly subducting northeastwards and the southern portion steeply subducting eastwards into the mantle transition zone. Analysis of tectonic and magmatic records is consistent with advancing and retreating migration of the slab tear after about 50 Myr ago. We suggest that the rigid Yangtze cratonic lithosphere tore the intruding cratonic Indian mantle lithosphere approximately 35 Myr ago, resulting in diverging shallow subduction. The subsequent Miocene rollback of the southeastern Indian mantle lithosphere is proposed to induce a giant turbo-engine-like flow that caused clockwise rotation of the plateau crust and underlying mantle around the eastern syntaxis, leading to differential eastward growth of the Tibetan Plateau. The Cenozoic eastward growth of the Tibetan Plateau can be explained by slab tear and the resulting mantle flow beneath the eastern region, according to analysis of seismic tomography, tectonic and magmatic records of the Indian mantle lithosphere.

Many functional and quantum materials derive their functionality from the responses of both their electronic and lattice subsystems to thermal, electric, and mechanical stimuli or light. Here we propose a dynamical phase-field model for predicting and modeling the dynamics of simultaneous electronic and structural processes and the accompanying mesoscale pattern evolution under static or ultrafast external stimuli. As an illustrative example of application, we study the transient dynamic response of ferroelectric domain walls excited by an ultrafast above-bandgap light pulse. We discover a two-stage relaxational electronic carrier evolution and a structural evolution containing multiple oscillational and relaxational components across picosecond to nanosecond timescales. The phase-field model offers a general theoretical framework which can be applied to a wide range of functional and quantum materials with interactive electronic and lattice orders and phase transitions to understand, predict, and manipulate their ultrafast dynamics and rich mesoscale evolution dynamics of domains, domain walls, and charges.

Piezoelectric nanocomposites with oxide fillers in a polymer matrix combine the merit of high piezoelectric response of the oxides and flexibility as well as biocompatibility of the polymers. Understanding the role of the choice of materials and the filler‐matrix architecture is critical to achieving desired functionality of a composite towards applications in flexible electronics and energy harvest devices. Herein, a high‐throughput phase‐field simulation is conducted to systematically reveal the influence of morphology and spatial orientation of an oxide filler on the piezoelectric, mechanical, and dielectric properties of the piezoelectric nanocomposites. It is discovered that with a constant filler volume fraction, a composite composed of vertical pillars exhibits superior piezoelectric response and electromechanical coupling coefficient as compared to the other geometric configurations. An analytical regression is established from a linear regression‐based machine learning model, which can be employed to predict the performance of nanocomposites filled with oxides with a given set of piezoelectric coefficient, dielectric permittivity, and stiffness. This work not only sheds light on the fundamental mechanism of piezoelectric nanocomposites, but also offers a promising material design strategy for developing high‐performance polymer/inorganic oxide composite‐based wearable electronics. A high‐throughput phase‐field model is built to systematically investigate the influence of oxide filler morphology on the piezoelectric properties of polymer/oxide nanocomposites. It is discovered that with a constant filler volume fraction, the vertical pillars exhibit the best piezoelectric performances. A linear regression‐based machine learning model is further employed to predict the performance of the polymer/ceramic nanocomposites.

Overheating remains a major barrier to chip miniaturization, leading to device malfunction. Addressing the urgent need for thermal management promotes the development of solid-state electrocaloric cooling. However, enhancing passive heat dissipation through two-dimensional materials in electrocaloric polymers typically compromises the electrocaloric effect. In this work, we utilize two-dimensional polyamide with porous structure and hydrogen bonding to achieve multiple polar conformations with short-range order in the electrocaloric composite polymers. The structure minimizes intermolecular interactions while reducing energy barriers for field-driven polar-nonpolar conformational transitions. The electrocaloric polymer exhibits doubled cooling efficiency at electric fields as low as 40 MV m −1 . Additionally, the electrode design achieves a vertical deformation of 2 millimeters, demonstrating the feasibility of self-driven electric refrigeration devices. This porous organic two-dimensional material resolves cooling efficiency limitations from spatial confinement, advancing the integration of two-dimensional materials in flexible electronics. Solid-state cooling technology based on electrocaloric materials shows promising potential for addressing electronic overheating challenges. Here, the authors employ two-dimensional polyamide to enhance the electrocaloric cooling performance by reducing intermolecular interactions and facilitating electrocaloric phase transitions thereby, offering insights into the application of spatially confined materials in flexible electronics.

Background: Dysphagia is a common complication following intracerebral hemorrhage (ICH) and is associated with an increased risk of aspiration pneumonia and poor outcomes. Objectives: This study aimed to explore associated lesion patterns and contributing factors of post-ICH dysphagia, and predict dysphagia outcomes following ICH. Design: A multicenter, prospective study. Methods: Patients with ICH from two stroke centers within 72 h of symptom onset received baseline bedside swallowing evaluations. Dysphagia-related lesion patterns were identified using support-vector regression-based lesion-symptom mapping. Predictors of swallowing impairment on the 7th and 30th day, as well as stroke-associated pneumonia (SAP), were determined through multiple logistic regression analyses, and nomograms were developed. Results: A total of 153 patients were included in the final analysis. Of those, 28 had dysphagia. Dysphagia-related lesions predominantly affected bilateral subcortical and adjacent cortical regions. Stroke severity, hematoma expansion, and basal ganglia hemorrhage were significantly associated with initial dysphagia. Baseline aspiration risk and age were identified as independent predictors of impaired swallowing function on days 7 and 30, and SAP. Moreover, ICH volume was significantly correlated with swallowing impairment on day 7 and SAP occurrence. Midline shift and basal ganglia hematoma remained independent predictors of impaired swallowing on day 30. Predictive models for swallowing impairment on days 7 and 30, as well as SAP, demonstrated strong calibration and discriminatory ability, with C indices of 0.867, 0.895, and 0.773, respectively. Conclusion: Post-ICH dysphagia can be predicted based on stroke severity, hematoma expansion, and basal ganglia hemorrhage. Incorporating aspiration risk and imaging evaluation can further improve the identification of patients at high risk for swallowing impairment at both 1 week and 1 month after ICH.

Successive indentations of Eurasia by India have led to the Tibet-Himalaya E–W orthogonal collision belt and the SE Tibetan Plateau N–S oblique collision belt along the frontal and eastern edges of the indenter, respectively. The belts exhibit distinctive lithospheric structures and tectonic evolutions. A comprehensive compilation of available geological and geophysical data reveals two sudden tectonic transitions in the early Eocene and the earliest Miocene, respectively, of the tectonic evolution of the orthogonal belt. Synthesizing geological and geochronological data helps us to suggest a NEE–SWW trending, ~450 km-long, ~250 km-wide magmatic zone in SE Tibet, which separates the oblique collision belt (eastern and SE Tibet) into three segments of distinctive seismic structures including the mantle and crust anisotropies. The newly identified Yongping basin is located in the central part of the magmatic zone. Geochronological and thermochronological data demonstrate that (1) this basin and the magmatic zone started to form at ~48 Ma likely due to NNW–SSE lithosphere stretching according to the spatial coincidence of the concentrated mantle-sourced igneous rocks on the surface with the seismic anomalies at depth; and (2) its fills was shortened in the E–W direction since ~23 Ma. These two dates correspond to the onset of the first and second tectonic transitions of the orthogonal collision belt. As such, both the orthogonal and oblique belts share a single time framework of their tectonic evolution. By synthesizing geological and geophysical data of both collision belts, the indenting process can be divided into three stages separated by two tectonic transitions. Continent–continent collision as a piston took place exclusively during the second stage. During the other two stages, the India lithosphere underthrust beneath Eurasia.

Magnetoelectric composite thin films hold substantial promise for applications in novel multifunctional devices. However, there are presently shortcomings for both the extensively studied bilayer epitaxial (2-2) and vertically architectured nanocomposite (1-3) film systems, restricting their applications. Here we design a novel growth strategy to fabricate an architectured nanocomposite heterostructure with magnetic quasiparticles (0) embedded in a ferroelectric film matrix (3) by alternately growing (2-2) and (1-3) layers within the film. The new heteroepitaxial films not only overcome the clamping effect from substrate, but also significantly suppress the leakage current paths through the ferromagnetic phase. We demonstrate, by focusing on switching characteristics of the piezoresponse, that the heterostructure shows magnetic field dependence of piezoelectricity due to the improved coupling enabled by good connectivity amongst the piezoelectric and magnetostrictive phases. This new architectured magnetoelectric heterostructures may open a new avenue for applications of magnetoelectric films in micro-devices. Magnetoelectric composites of magnetic and ferroelectric components are promising for their use in applications such as information storage. Here, the authors find that magnetic quasiparticles embedded in a ferroelectric film matrix show promising properties compared to the usual thin-film architectures.

Magnetic skyrmions are swirling spin structures stabilized typically by the Dyzaloshinskii-Moriya interaction. The existing control of magnetic skyrmions has often relied on the use of an electric current, which may cause overheating in densely packed devices. Here we demonstrate, using phase-field simulations, that an isolated Néel skyrmion in a magnetic nanodisk can be repeatedly created and deleted by voltage-induced strains from a juxtaposed piezoelectric. Such a skyrmion switching is non-volatile, and consumes only ~0.5 fJ per switching which is about five orders of magnitude smaller than that by current-induced spin-transfer-torques. It is found that the strain-mediated skyrmion creation occurs through an intermediate vortex-like spin structure, and that the skyrmion deletion occurs though a homogenous shrinkage during which the Néel wall is temporarily transformed to a vortex-wall. These findings are expected to stimulate experimental research into strain-mediated voltage control of skyrmions, as well as other chiral spin structures for low-power spintronics.