Explore the vast range of titles available.

This manuscript describes the successful synthesis of Fe 3 O 4 nanoparticles coated with β-cyclodextrin-intercalated layered double hydroxide, which were utilized to remove Uranium (VI) from an aqueous solution effectively. The newly developed nano-adsorbent underwent thorough analysis through advanced techniques such as scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), vibrating sample magnetometer (VSM), and energy-dispersive X-ray analysis (EDX). Through the utilization of a one-variable-at-a-time strategy, we effectively enhanced the removal process by optimizing key factors such as the sample’s pH and the amount of adsorbent utilized. These adjustments proved crucial in achieving utmost success. The adsorption mechanism was identified by plotting Langmuir and Freundlich isotherms. Under the optimized conditions, the removal efficiency of as high as 96.21%, as well as the adsorption capacity of 461.89 mg g − 1 , were obtained showing the desirable performance of the synthesized nano-adsorbent in Uranium (VI) removal from aqueous solutions. The selectivity of the adsorbent was evaluated by calculating distribution coefficients for Uranium (VI) and some interfering ions. The applicability of the adsorbent was tested by removing uranium (VI) from diverse complex environmental water samples. As a result of the removal efficiencies exceeding 92.76% with relative standard deviations (RSDs%) below 6.73%, the synthesized adsorbent can successfully remove Uranium (VI) from complex real samples with acceptable precisions.

The amount of polycyclic aromatic hydrocarbons (PAHs) can be reduced by food additives. In this study, the impact of various flavors was investigated on the formation of PAHs in roasted sunflower seeds. PAHs was measured in the shell and kernel of sunflower with the flavors of lemon, golpar (hogweed), salt, ketchup and raw sunflower. Measuring the amount of PAHs was analyzed by Gas chromatography–mass spectrometry (GC–MS). PAHs with low molecular weight were detected. The total of PAHs of sunflower seeds were in the range of 0.4–3.2 mg kg −1 . The lowest amount was related to the hogweed kernel, and the highest amount was related to the lemon. High molecular weight PAHs were not detected because the temperature did not rise above 100 °C during roasting. Some flavors, such as hogweed can reduce the amount of PAHs because of their antioxidant properties. On the contrary, the PAHs level with lemon juice was higher than other flavors.

Canned pickled cucumbers, tomato paste, and olives are three commonly consumed products in Iranian households that may be a source of heavy metals for individuals due to the type of packaging. Therefore, in this study, samples of these three types of food were collected from the market and were measured for mineral and heavy metal content. The levels of metals including Cadmium, Copper, Arsenic, Iron, Lead, and Zinc were determined using an AAS- Flame and Graphite furnace. Moreover, the concentrations of Mercury and Tin were determined using the ICP-MS. In canned cucumber samples, only two metals, tin and lead, were detected. The levels of heavy metals in these three products were compared using statistical tests. A significant difference was observed in the amount of cadmium ( p  < 0.05). The average lead content in these three products was above the permissible limit. The levels of copper, arsenic, iron, cadmium, zinc, mercury, and tin in the canned food samples were found to be within the acceptable limits set by national and international regulatory authorities.

In this paper, concentrations of some heavy metals in surficial sediments of the International Anzali Wetland were measured, this wetland is located in the northern part of Iran. Sediment pollution levels were examined and analyzed using reliable pollution indices including Pollution Load Index (PLI), Geoaccumulation Index (Igeo) and Enrichment Factor (CF), and finally it was revealed that heavy metal pollution ranged from low to moderate loads in the wetland. According to Sediment Quality Guidelines (SQGs) and Ecological Risk Index (ERI), it was concluded that As and Ni may have significant toxic impacts on aquatic organisms and also according to Effect Range Median (ERM), the toxicity probability of sediments in the Anzali wetland was estimated at 21%.

Background Bisphenol A (BPA) is one of the chemical compounds used in food packaging, so it can migrate from the packaging into food. Also, environmental pollution of this compound is high due to its high use. Therefore, it may enter food chains through the environment. Aflatoxin M1 (AFM1) is one of the common mycotoxins in milk. Its presence has been reported worldwide. Infant formula is an alternative to human milk. The main ingredient of this product is cow’s milk. Aims This study aimed to investigate the levels and risk assessment of BPA and aflatoxin M1 in infant formula. Methods Samples were purchased from 7 leading brands of infant formula in pharmacies. The samples were extracted according to common protocols and then injected into HPLC and analyzed with a fluorescence detector for both contaminants. Results BPA wasn’t detected in infant formula samples, but the presence of AFM1was confirmed in 11% of the samples. Of course, there is no risk in this regard with the risk assessment. Conclusion Infant formula samples are not of concern for infants in terms of BPA and aflatoxin M1. However, continuous monitoring is recommended for this product.

In this study, the application of Disperse Blue 6 (D. B. 6) an efficient redox additive for natural aqueous electrolyte was reported in where defective mesoporous carbon (DMC) with the interconnected porous network was applied as electrode material. Excellent electrochemical performance is achieved at 0.2 M of D. B. 6 in 1 M Na 2 SO 4 electrolyte. The obtained data from RAMAN, SEM, TEM, XRD and Nitrogen adsorption/desorption confirmed the DMC structure. The supercapacitive performance of DMC and DMC electrodes with D. B. 6 redox additive in 1 M Na 2 SO 4 (DMC-DB/Na 2 SO 4 ) as electrolyte was evaluated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charge/discharge (GCD) techniques. Compared to DMC, the DMC-DB/Na 2 SO 4 delivered the highest specific capacitance reaching to 323.33 F/g at the applied current density of 0.5 A/g. Moreover, the DMC-DB/Na 2 SO 4 exhibited cyclic stability, in where 88.3% of specific capacitance were retained after 2000 GCD measurement at the current density of 5 A/g. Furthermore, electrode exhibited a high energy density of 28.74 Wh/kg, nearly fourfold increase over the DMC electrode with pure Na 2 SO 4 electrolyte. These results shows that the D. B. 6 redox additive is a facile and straight direct approach to improve the performance of DMC supercapacitor.

Chemical exposure of heavy metals in children is of particular concern. However, using heavy metal-contaminated toys can threaten the life and well-being of children. Therefore, quality control of toys for avoiding children exposure to potentially toxic metals is important. The investigation of potentially toxic metals (arsenic, barium, antimony, cadmium, chromium, mercury, lead, selenium) in toys was performed in present study. A total number of 150 popular cheap priced plastic toy samples were purchased from the eight metropolitan and most visited provinces in Iran and analyzed by atomic absorption spectrophotometer for arsenic, barium, antimony cadmium, chromium, mercury, lead, and selenium. As results showed As, Ba, Cd, Cr, Hg, Pb, Sb, and Se respectively were in the range of 0–0.9 mg/kg, 0.3–5 mg/kg, 0–3.1 mg/kg, 0.04–4.8 mg/kg, 0–0.03 mg/kg, 0.22–11.7 mg/kg, 0–1.2 mg/kg, and 0.03–1.1 mg/kg. Cadmium was higher than the European standard in Kurdistan province. The highest amount of mercury was also observed in Tehran. The highest amount of lead, selenium, and antimony was detected in Qom province. The results showed that all the toxic elements in the collected toys were within the permissible limit. Furthermore, market monitoring is needed to control toys safety on a large scale in metropolitan cities like Qom province.

In recent years, supercapacitors have gained importance as electrochemical energy storage devices. Those are attracting a lot of attention because of their excellent properties, such as fast charge/discharge, excellent cycle stability, and high energy/power density, which are suitable for many applications. Further development and innovation of these devices depend on the production of suitable, inexpensive, environmentally friendly, and widely available materials for use as active materials in electrodes and electrolytes. Different materials (such as activated carbon, metal oxides, graphene, conducting polymers, and ionic liquids) have recently been used to fabricate powerful symmetric or asymmetric supercapacitor electrodes. This paper presents the advantages and disadvantages as well as the electrochemical parameters of different electrodes based on a detailed literature review. The focus is particularly on ionic liquids, which are used as electrode materials. Finally, the future development and perspectives of supercapacitors based on ionic liquids are discussed.

A highly sensitive new method is described for performing dispersive microextractions. It is making use of a magnetic carbon nanocomposite and two miscible organic solvents. The method was applied to simultaneous extraction of 32 polychlorinated biphenyls (PCBs) prior to their quantitation by gas chromatography with electron capture detection. The effects of pH value of sample for both micro solid phase extraction and dispersive liquid-liquid microextraction, of the amount of sorbent, extraction time, type and volume of the miscible organic solvents and of salt addition were optimized. Figures of merit obtained under optimized conditions (sample solution: 500 ml, volume of disperser solvent, ACN, 1.5 mL; volume of extraction solvent, TCB, 30 [mu]L; extraction time: 50 min, 20 mg magnetic sorbent, centrifuge, 5 min, 4000 rpm), include (a) preconcentration factors between 10,880 and 34,000; (b) repeatabilities of [less than or equal to]14.9%, (c) detection limits between 0.01 and 0.2 ng kg-1, and (d) linear dynamic ranges from 0.05 to 100 ng kg - 1. The method was applied to the simultaneous analysis of residues in (spiked) real samples of fish, milk, packing sheet, and tap waters. Some of the analytes were found to be present in fish samples. The method is simple, rapid, and more sensitive than any of the previously reported ones.

A highly sensitive new method is described for performing dispersive microextractions. It is making use of a magnetic carbon nanocomposite and two miscible organic solvents. The method was applied to simultaneous extraction of 32 polychlorinated biphenyls (PCBs) prior to their quantitation by gas chromatography with electron capture detection. The effects of pH value of sample for both micro solid phase extraction and dispersive liquid-liquid microextraction, of the amount of sorbent, extraction time, type and volume of the miscible organic solvents and of salt addition were optimized. Figures of merit obtained under optimized conditions (sample solution: 500 ml, volume of disperser solvent, ACN, 1.5 mL; volume of extraction solvent, TCB, 30 μL; extraction time: 50 min, 20 mg magnetic sorbent, centrifuge, 5 min, 4000 rpm), include (a) preconcentration factors between 10,880 and 34,000; (b) repeatabilities of ≤14.9%, (c) detection limits between 0.01 and 0.2 ng kg-1, and (d) linear dynamic ranges from 0.05 to 100 ng kg − 1. The method was applied to the simultaneous analysis of residues in (spiked) real samples of fish, milk, packing sheet, and tap waters. Some of the analytes were found to be present in fish samples. The method is simple, rapid, and more sensitive than any of the previously reported ones. Graphical abstract Schematic presentation of simultaneous extraction of 32 polychlorinated biphenyls (PCBs) by using magnetic carbon nanocomposites (MCNs) based dispersive microextraction (M-SPE), subsequent dispersive liquid-liquid microextraction (DLLME) with two miscible stripping solvents, and quantitation by GC-μECD.