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"Zhang, Fengsan"
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Diffusion Behavior of Polyurethane Slurry for Simultaneous Enhancement of Reservoir Strength and Permeability Through Splitting Grouting Technology
2025
A polyurethane slurry was developed to simultaneously enhance the strength and permeability of geological formations, differing from the conventional fracture grouting used for soft-soil reinforcement. Injected via splitting grouting, the slurry cures to form high-strength, highly permeable channels that increase reservoir permeability while improving mechanical stability (dual-enhanced stimulation). To quantify its diffusion behavior and guide field application, we built a splitting-grouting model using the finite–discrete element method (FDEM), parameterized with the reservoir properties of coalbed methane (CBM) formations in the Ordos Basin and the slurry’s measured rheology and filtration characteristics. Considering the stratified structures within coal rock formed by geological deposition, this study utilizes Python code interacting with Abaqus to divide the coal seam into coal rock and natural bedding. We analyzed the effects of engineering parameters, geological factors, and bedding characteristics on slurry–vein propagation patterns, the stimulation extent, and fracturing pressure. The findings reveal that increasing the grouting rate from 1.2 to 3.6 m3/min enlarges the stimulated volume and the maximum fracture width and raises the fracturing pressure from 26.28 to 31.44 MPa. A lower slurry viscosity of 100 mPa·s promotes the propagation of slurry veins, making it easier to develop multiple veins. The bedding-to-coal rock strength ratio controls crossing versus layer-parallel growth: at 0.3, veins more readily penetrate bedding planes, whereas at 0.1 they preferentially spread along them. Raising the lateral pressure coefficient from 0.6 to 0.8 increases the likelihood of the slurry expanding along the beddings. Natural bedding structures guide directional flow; a higher bedding density (225 lines per 10,000 m3) yields greater directional deflection and a more intricate fracture network. As the angle of bedding increases from 10° to 60°, the slurry veins are more susceptible to directional changes. Throughout the grouting process, the slurry veins can undergo varying degrees of directional alteration. Under the studied conditions, both fracturing and compaction grouting modes are present, with fracturing grouting dominating in the initial stages, while compaction grouting becomes more prominent later on. These results provide quantitative guidance for designing dual-enhanced stimulation to jointly improve permeability and mechanical stability.
Journal Article
Research on Damage Characteristics of Clean Fracturing Fluid in Deep Coal Seam
2025
This study focuses on investigating the damage characteristics and mechanisms of Slickwo clean fracturing fluid to the reservoir by using the deep coal seam in the Yan’an gas field as the research subject. During the experiment, fracturing fluids with varying A content were employed to displace coal and rock cores. The impact of these fluids on the permeability and pore structure of coal and rock was analyzed using a combination of nuclear magnetic resonance and high-pressure mercury injection technology. The findings indicate that the permeability damage rates of cores Y-1 and Y-2 post-displacement are 48.4% and 53.6% correspondingly, with the damage worsening as the agent A content increases. NMR data reveals that the fracturing fluid exhibits the highest retention in small pores, followed by medium-sized pores, and the least in large pores. The rise in agent A content enhanced the retention degree in individual pore throats and overall, increasing from 62.24% to 68.74%. The escalation in agent A content results in higher macromolecular residues, causing seepage channel blockages and enhancing the adsorption properties between fracturing fluid and coal rock. This phenomenon leads to inadequate backflow, primarily in smaller apertures. Simultaneously, the interaction between the gel breaker and clay minerals triggers particle migration, blockage, and expansion, consequently diminishing the permeability of coal and rock and inducing specific damages.
Journal Article
Surface Properties and Application of Fluorinated Emulsifier-Free Emulsion Surface Sizing Agent
2013
Fluorinated emulsifier-free emulsion surface sizing agent (FEE) was prepared by emulsifier-free polymerization of hexafluoro-butyl methacrylate (FA), styrene (St) and so on in the presence of fuorinated random amphiphilic polymers (ASRF) copolymerized by FA, St and acrylatic acid. Effects of ASRF content and treatment temperature on the surface properties of the films were investigated. Effects of ASRF content and oxide starch on the application were also discussed. Additionally, fiber morphologies of the samples were characterized by SEM.The results show that the appropriate increases of ASRF content and treatment temperature are good for the decreases of surface free energies of the films. When the ASRF content and oxide starch content is 5% and less 50% respectively, the FEE and its combination with oxide starch have good sizing performance. After the treatment by FEE, the fiber surface becomes smooth, which provides lower surface free energy of the fibers.
Journal Article