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HighlightsBifunctional electrode and electrolytic cell configuration for electrochemical water splitting are reviewed.The different green energy systems powered water splitting are summarized and discussed.An outlook of future research prospects for the development of green energy system powered water splitting in practical application process is proposed.Hydrogen (H2) production is a latent feasibility of renewable clean energy. The industrial H2 production is obtained from reforming of natural gas, which consumes a large amount of nonrenewable energy and simultaneously produces greenhouse gas carbon dioxide. Electrochemical water splitting is a promising approach for the H2 production, which is sustainable and pollution-free. Therefore, developing efficient and economic technologies for electrochemical water splitting has been an important goal for researchers around the world. The utilization of green energy systems to reduce overall energy consumption is more important for H2 production. Harvesting and converting energy from the environment by different green energy systems for water splitting can efficiently decrease the external power consumption. A variety of green energy systems for efficient producing H2, such as two-electrode electrolysis of water, water splitting driven by photoelectrode devices, solar cells, thermoelectric devices, triboelectric nanogenerator, pyroelectric device or electrochemical water–gas shift device, have been developed recently. In this review, some notable progress made in the different green energy cells for water splitting is discussed in detail. We hoped this review can guide people to pay more attention to the development of green energy system to generate pollution-free H2 energy, which will realize the whole process of H2 production with low cost, pollution-free and energy sustainability conversion.

This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL2 as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (σ and π) donation to the metal atom [M]⇇CL2. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR3 → [M]-CR2 → [M]-CR → [M]-C. This review includes some work on uranium and cerium complexes, but it does not present a complete coverage of actinide and lanthanide complexes with carbone or carbide ligands.

This study systematically reviews the development and application of remote sensing technology in monitoring and evaluating urban heat island (UHI) effects. The urban heat island effect, characterized by significantly higher temperatures in urban areas compared to surrounding rural regions, has become a widespread environmental issue globally, with impacts spanning public health, energy consumption, ecosystems, and social equity. The paper first analyzes the formation mechanisms and impacts of urban heat islands, then traces the evolution of remote sensing technology from early traditional platforms such as Landsat and NOAA-AVHRR to modern next-generation systems, including the Sentinel series and ECOSTRESS, emphasizing improvements in spatial and temporal resolution and their application value. At the methodological level, the study systematically evaluates core algorithms for land surface temperature extraction and heat island intensity calculation, compares innovative developments in multi-source remote sensing data integration and fusion techniques, and establishes a framework for accuracy assessment and validation. Through analyzing the heat island differences between metropolitan areas and small–medium cities, the relationship between urban morphology and thermal environment, and regional specificity and global universal patterns, this study revealed that the proportion of impervious surfaces is the primary driving factor of heat island intensity while simultaneously finding that vegetation cover exhibits significant cooling effects under suitable conditions, with the intensity varying significantly depending on vegetation types, management levels, and climatic conditions. In terms of applications, the paper elaborates on the practical value of remote sensing technology in identifying thermally vulnerable areas, green space planning, urban material optimization, and decision support for UHI mitigation. Finally, in light of current technological limitations, the study anticipates the application prospects of artificial intelligence and emerging analytical methods, as well as trends in urban heat island monitoring against the backdrop of climate change. The research findings not only enrich the theoretical framework of urban climatology but also provide a scientific basis for urban planners, contributing to the development of more effective UHI mitigation strategies and enhanced urban climate resilience.

This paper incorporates green innovation into a two-tier new energy vehicle supply (NEV) chain under a dual credit policy, in which the NEV manufacturer controls the level of green innovation and wholesale prices, and the NEV retailer controls sales prices. We analyze the pricing and green innovation strategies of the NEV manufacturer and retailer in decentralized and integrated scenarios by constructing differential game models. We then test the performance of the supply chain by comparing the profit, energy efficiency levels and green innovation levels of the NEV supply chain with those in the decentralized scenario. It is found that the profits, energy efficiency levels and green innovation levels of the NEV supply chain in the integrated scenario are higher than those in the decentralized scenario. Therefore, a revenue and investment sharing contract is designed to coordinate the supply chain and several conditions are derived for the contract to be accepted by both members of the supply chain. Numerical calculations are performed and the theoretical results and impacts of the unit credit trading price and the percentage of units of NEV converted into credits on the supply chain coordination are analyzed to further validate the effectiveness of the dual credit policy.

Osteoarthritis (OA) and Rheumatoid Arthritis (RA) are significant health concerns with notable prevalence and economic impact. RA, affecting 0.5% to 1.0% of the global population, leads to chronic joint damage and comorbidities. OA, primarily afflicting the elderly, results in joint degradation and severe pain. Both conditions incur substantial healthcare expenses and productivity losses. The cGAS-STING pathway, consisting of cyclic GMP–AMP synthase (cGAS) and stimulator of interferon genes (STING), is a crucial component of mammalian immunity. This pathway is responsible for detecting foreign DNA, particularly double-stranded DNA (dsDNA), triggering innate immune defense responses. When cGAS recognizes dsDNA, it catalyzes the synthesis of cyclic GMP–AMP (cGAMP), which then binds to and activates STING. Activated STING, in turn, initiates downstream signaling events leading to the production of interferons and other immune mediators. The cGAS-STING pathway is essential for defending against viral infections and maintaining cellular balance. Dysregulation of this pathway has been implicated in various inflammatory diseases, including arthritis, making it a target for potential therapeutic interventions. Understanding the intricate molecular signaling network of cGAS-STING in these arthritis forms offers potential avenues for targeted therapies. Addressing these challenges through improved early detection, comprehensive management, and interventions targeting the cGAS-STING pathway is crucial for alleviating the impact of OA and RA on individuals and healthcare systems. This review offers an up-to-date comprehension of the cGAS-STING pathway’s role in the development and therapeutic approaches for these arthritis types.

HighlightsThe current understanding and advances on laser synthesis of nanomaterials are summarized.The laser microfabrication-enabled energy conversion and storage devices are reviewed.The limitations and solutions for current laser processing of nanomaterials and other more potential development directions for laser processing are proposed.Nanomaterials are known to exhibit a number of interesting physical and chemical properties for various applications, including energy conversion and storage, nanoscale electronics, sensors and actuators, photonics devices and even for biomedical purposes. In the past decade, laser as a synthetic technique and laser as a microfabrication technique facilitated nanomaterial preparation and nanostructure construction, including the laser processing-induced carbon and non-carbon nanomaterials, hierarchical structure construction, patterning, heteroatom doping, sputtering etching, and so on. The laser-induced nanomaterials and nanostructures have extended broad applications in electronic devices, such as light–thermal conversion, batteries, supercapacitors, sensor devices, actuators and electrocatalytic electrodes. Here, the recent developments in the laser synthesis of carbon-based and non-carbon-based nanomaterials are comprehensively summarized. An extensive overview on laser-enabled electronic devices for various applications is depicted. With the rapid progress made in the research on nanomaterial preparation through laser synthesis and laser microfabrication technologies, laser synthesis and microfabrication toward energy conversion and storage will undergo fast development.

Ganoderma lucidum is a medicinal mushroom that has been widely used in East Asia for the treatment of various diseases. The pharmacological activity of this fungus is primarily attributable to the polysaccharides and triterpenoids. In this study, to obtain the fruit bodies with improved content of active constituents, we examined the effect of salicylic acid (SA) and calcium ion on the biosynthesis of polysaccharides and triterpenoids by spraying the chemicals during the fruiting. To explore the underlying mechanisms for the variation, the transcripts of related genes involved in the polysaccharide and triterpenoid biosynthesis were measured. Results showed that Ca2+ had no effect on production of polysaccharides and triterpenoids, whereas SA increased triterpenoid content by 23.32%, compared to the control, but it had little influence on polysaccharide production. Interestingly, the combined induction increased polysaccharide and triterpenoid content by 9.02% and 13.61%, respectively, compared to the control. Under Ca2+ induction, the transcript of ugp gene in the polysaccharide biosynthetic pathway up-regulated in all three stages (mycelium, primordium, and fruit body), while pgm and gls gave no response in the mycelium and primordium stages, and up-regulated in the fruit body stage. Differently, six key triterpenoid biosynthetic genes including hmgr, hmgs, mvd, fps, sqs, and ls did not respond to the induction. In the case of SA and combined induction, pgm and ugp were up-regulated in all three stages, while gls showed an increased expression in the primordium stage and no response in other stages. The six triterpenoid biosynthetic genes were up-regulated in all three stages. The present study provides a useful approach to producing G. lucidum fruit bodies with high polysaccharide and triterpenoid content. This is important to the G. lucidum industry.

Dative bonds between p - and d -block atoms are common but species containing a double dative bond, which donate two-electron pairs to the same acceptor, are far less common. The synthesis of complexes between UCl 4 and carbodiphosphoranes (CDP), which formally possess double dative bonds Cl 4 U⇇CDP, is reported in this paper. Single-crystal X-ray diffraction shows that the uranium−carbon distances are in the range of bond lengths for uranium−carbon double bonds. A bonding analysis suggests that the molecules are uranium−carbone complexes featuring divalent carbon(0) ligands rather than uranium−carbene species. The complexes represent rare examples with a double dative bond in f -block chemistry. Our study not only introduces the concept of double dative bonds between carbones and f -block elements but also opens an avenue for the construction of other complexes with double dative bonds, thus providing new opportunities for the applications o f f -block compounds. While chemical bonding between carbon and the d - and p -block elements is relatively well-studied, that between carbon and the f -block elements remains comparatively poorly understood. Here, the authors synthesize a series of uranium−carbone complexes in which carbon forms an unprecedented double dative bond to uranium.

Multiple sclerosis (MS) is a chronic inflammatory disease of the central nervous system (CNS) characterized by destruction of the myelin sheath structure. The loss of myelin leads to damage of a neuron’s axon and cell body, which is identified as brain lesions on magnetic resonance image (MRI). The pathogenesis of MS remains largely unknown. However, immune mechanisms, especially those linked to the aberrant lymphocyte activity, are mainly responsible for neuronal damage. Th1 and Th17 populations of lymphocytes were primarily associated with MS pathogenesis. These lymphocytes are essential for differentiation of encephalitogenic CD8 + T cell and Th17 lymphocyte crossing the blood brain barrier and targeting myelin sheath in the CNS. B-lymphocytes could also contribute to MS pathogenesis by producing anti-myelin basic protein antibodies. In later studies, aberrant function of Treg and Th9 cells was identified as contributing to MS. This review summarizes the aberrant function and count of lymphocyte, and the contributions of these cell to the mechanisms of MS. Additionally, we have outlined the novel MS therapeutics aimed to amend the aberrant function or counts of these lymphocytes.

We report the isolation and spectroscopic identification of the eight-coordinated alkaline earth metal–dinitrogen complexes M(N 2 ) 8 (M=Ca, Sr, Ba) possessing cubic ( O h ) symmetry in a low-temperature neon matrix. The analysis of the electronic structure reveals that the metal-N 2 bonds are mainly due to [M(d π )]→(N 2 ) 8 π backdonation, which explains the observed large red-shift in N-N stretching frequencies. The adducts M(N 2 ) 8 have a triplet ( 3 A 1g ) electronic ground state and exhibit typical bonding features of transition metal complexes obeying the 18-electron rule. We also report the isolation and bonding analysis of the charged dinitrogen complexes [M(N 2 ) 8 ] + (M=Ca, Sr). The study of main group complexes remains important to our fundamental understanding of main group element bonding and properties. Here the authors isolate and spectroscopically characterize a series of 8-coordinated alkaline earth metal–dinitrogen complexes M(N 2 ) 8 (M=Ca, Sr, Ba) in a low-temperature neon matrix.