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In modern society where fossil fuel prices are increasing and environmental issues are becoming more severe, biodiesel, as a new type of clean fuel, is receiving increasing attention. Biodiesel has the advantages of renewability, environmental friendliness, and good fuel properties, demonstrating broad application prospects. However, the use of biodiesel also faces some challenges, such as higher density and kinematic viscosity, lower calorific value, etc. The application of nanoparticles in biodiesel engines helps to achieve the goal of clean fuel. In terms of fuel characteristics, nanoparticles increase the calorific value, cetane value, and flash point of the fuel, improving combustion efficiency and safety, but increasing density may affect combustion. The use of nanoparticles can promote micro explosions and secondary atomization of fuel, improve combustion characteristics, and increase cylinder pressure, heat release rate, and brake thermal efficiency while reducing fuel consumption. Nanoparticles reduce HC and CO emissions, improve combustion through higher oxygen and reaction area, and reduce incomplete combustion products. On the contrary, nanoparticles also increase CO2 emissions because better combustion conditions promote oxidation reactions. For NOX emissions, some nanoparticles lower the combustion temperature to reduce emissions, while others increase emissions. Comparison shows that all nanoparticles offer varying degrees of improvement in engine performance and emissions, but the improvement provided by TiO2 nanoparticles is significantly better than that of other nanoparticles. In the future, the synergistic effect of multiple nanoparticles should be explored to further improve performance and reduce emissions, achieving effects that cannot be achieved by a single nanoparticle.

Faced with the depletion of fossil fuels and increasingly serious environmental pollution, finding an environmentally friendly renewable alternative fuel has become one of the current research focuses. In order to find new alternative fuels, reduce dependence on fossil fuels, improve air quality, and promote sustainable development goals, castor biodiesel was produced through transesterification, and mixed with diesel in a certain proportion. The engine performance and emissions were compared and analyzed under fixed load and different speeds of agricultural diesel engines. Biofuel, as a fuel containing oxygen, promotes complete combustion to a certain extent. As the proportion of castor biodiesel in the mixed fuel increases, the emissions of pollutants such as CO, HC, and smoke show a decreasing trend. The lowest CO, HC, and smoke emissions were observed in the B80 blend at 1800 rpm, at 0.3%, 23 ppm, and 3%, respectively. On the contrary, the CO2 and NOx emissions of the B80 blend are higher than those of 2.7 diesel, reaching 2.5% and 332 ppm respectively at 1800 rpm. The lower calorific value and higher viscosity of biodiesel result in a decrease in BTE and an increase in the BSFC of the blends. Higher combustion temperatures at high speeds promote oxidation reactions, resulting in reduced HC, CO, and smoke emissions, but increased CO2 and NOx emissions. At high speeds, fuel consumption increases, BSFC increases, and BTE decreases. Overall, castor biodiesel has similar physical and chemical properties to diesel and can be mixed with diesel in a certain proportion for use in CI engines, making it an excellent alternative fuel.

Diesel engines are extensively employed in transportation, agriculture, and industry due to their high thermal efficiency and fuel economy. However, the combustion of conventional diesel fuel is accompanied by substantial emissions of pollutants, including carbon monoxide (CO), hydrocarbons (HC), nitrogen oxides (NOx), and carbon dioxide (CO2), posing significant threats to environmental quality. Biodiesel, as a renewable and cleaner alternative fuel, can significantly reduce emissions of CO, HC, and particulate matter (PM) due to its unique molecular structure. Nonetheless, its lower calorific value and poor cold-start performance limit its application, while its high oxygen content may contribute to increased NOx emissions. To address these limitations, researchers have proposed blending biodiesel with alcohol-based fuels such as methanol, ethanol, or butanol to create synergistic combustion systems that optimize engine performance and emission characteristics. This paper systematically reviews the effects of alcohol fuels on the performance and emission characteristics of biodiesel blends in diesel engines. Studies indicate that the addition of alcohol fuels can significantly enhance engine performance by improving fuel atomization, extending ignition delay, and increasing premixed combustion efficiency. These enhancements result in higher cylinder pressure, net heat release rate (HRR), and brake thermal efficiency (BTE), while reducing brake-specific fuel consumption (BSFC) to some extent. Moreover, most studies report that alcohol fuels help reduce CO, HC, smoke, and NOx emissions but tend to increase CO2 emissions. However, some findings suggest that in certain cases, the opposite results may occur. The impact of different types of alcohol fuels on performance and emissions varies significantly, requiring a comprehensive evaluation of their properties, such as latent heat, viscosity, and oxygen content. Although the appropriate addition of alcohol fuels demonstrates substantial potential for optimizing engine performance and reducing emissions, excessive blending may lead to adverse effects, necessitating careful control of the blending ratio. Future research should consider mixing two or more alcohol fuels with biodiesel to explore synergistic effects beyond the capabilities of single alcohols. Additionally, further studies should focus on optimizing fuel compositions and emission control strategies for varying operating conditions.

In this study, cottonseed oil biodiesel and waste lard biodiesel were produced through a transesterification process and blended with conventional diesel at different ratios (B10 and B20). The performance and emission characteristics of these fuels were systematically evaluated in a single-cylinder, four-stroke, water-cooled diesel engine operating at speeds of 1000–1800 rpm under a constant 50% load. The physicochemical properties of the fuels were analyzed, and engine parameters including brake-specific fuel consumption (BSFC), brake thermal efficiency (BTE), exhaust gas temperature (EGT), and emissions of carbon monoxide (CO), hydrocarbon (HC), carbon dioxide (CO2), and nitrogen oxides (NOx) were measured. The results demonstrated that, compared with diesel, biodiesel blends significantly reduced CO, HC, and CO2 emissions. At 1800 rpm, the LB20 blend showed reductions of 31.03% in CO, 47.06% in HCs, and 19.14% in CO2 relative to diesel. These reductions are mainly attributed to the higher oxygen content and lower hydrogen-to-carbon ratio of biodiesel, which promote more complete combustion. However, all biodiesel blends exhibited higher NOx emissions than diesel, with the increase being more pronounced at higher blend ratios. At 1800 rpm, the LB20 blend recorded the highest NOx emissions, which were 20.63% higher than those of diesel under the same condition. In terms of performance, biodiesel blends showed higher BSFC and lower BTE compared with diesel, mainly due to their lower calorific value and higher viscosity. The lowest BTE and the highest BSFC were both observed with the LB20 blend, at 22.64% and 358.11 g/kWh, respectively.

Surface amorphization provides electrocatalysts with more active sites and flexibility. However, there is still a lack of experimental observations and mechanistic explanations for the in situ amorphization process and its crucial role. Herein, we propose the concept that by in situ reconstructed amorphous surface, metal phosphorus trichalcogenides could intrinsically offer better catalytic performance for the alkaline hydrogen production. Trace Ru (0.81 wt.%) is doped into NiPS 3 nanosheets for alkaline hydrogen production. Using in situ electrochemical transmission electron microscopy technique, we confirmed the amorphization process occurred on the edges of NiPS 3 is critical for achieving superior activity. Comprehensive characterizations and theoretical calculations reveal Ru primarily stabilized at edges of NiPS 3 through in situ formed amorphous layer containing bridging S 2 2− species, which can effectively reduce the reaction energy barrier. This work emphasizes the critical role of in situ formed active layer and suggests its potential for optimizing catalytic activities of electrocatalysts. Surface amorphization generally provides electrocatalysts with more active sites and flexibility. Here it is employed in-situ liquid TEM to observe the surface reconstruction on Ru-NiPS3 nanosheets, confirming that the amorphization on the edges of NiPS3 is critical for achieving superior activity.

Fossil fuels confront the problem of strategic resource depletion since they have been continuously utilized for more than 200 years and cause serious damages to the ecological environment of the planet. In this work, the transesterification of castor plant oil was utilized to make biodiesel, and castor biodiesel’s physicochemical qualities were assessed. On a single-cylinder, four-stroke, water-cooled agricultural diesel engine, an experimental study was conducted to compare and analyze the engine performance and emission characteristics of diesel and biodiesel blends in various amounts. The B20, B40, B60, and B80 biodiesel blends were evaluated at different engine speeds (1200, 1400, 1600, and 1800 rpm) with a constant engine load (50%). According to the experimental findings, the brake thermal efficiency (BTE) declines as the engine speed rises, and the biodiesel fuel blend has a lower brake thermal efficiency (BTE) than diesel fuel because of its higher density and viscosity and lower calorific value. The amount of gasoline required to create power increases as the speed does, and the brake-specific fuel consumption (BSFC) trend is upward. Due to their low calorific value and high viscosity properties, biodiesel blends have a greater brake-specific fuel consumption (BSFC) than diesel. The fuel’s exhaust gas temperature (EGT) has an upward trend with an increased rotational speed. The biodiesel blend’s high cetane number shortens the ignition delay and lowers the exhaust gas temperature (EGT) compared to diesel. A fuel with oxygen added, biodiesel enhances combustion, increases the combustion temperature, speeds up the oxidation process, and lowers carbon monoxide (CO) and hydrocarbon emissions. B80 produces the lowest carbon monoxide and hydrocarbon emissions at 1800 rpm, at 0.33%, and 30 ppm, respectively. On the other hand, increased carbon dioxide (CO2) emissions result from a high oxygen concentration. In addition, compared to diesel fuel, biodiesel’s greater combustion temperature causes the creation of increased nitrogen oxide (NOx) emissions. According to the research findings, a castor biodiesel fuel blend is an excellent alternative fuel for engines since it can be utilized directly without modifying the current engine construction and has good engine and exhaust emission performance.

Memory transistors based on two-dimensional (2D) ferroelectric semiconductors are intriguing for next-generation in-memory computing. To date, several 2D ferroelectric materials have been unveiled, among which 2D In 2 Se 3 is the most promising, as all the paraelectric (β), ferroelectric (α) and antiferroelectric (β′) phases are found in 2D quintuple layers. However, the large-scale synthesis of 2D In 2 Se 3 films with the desired phase is still absent, and the stability for each phase remains obscure. Here we show the successful growth of centimetre-scale 2D β-In 2 Se 3 film by chemical vapour deposition including distinct centimetre-scale 2D β′-In 2 Se 3 film by an InSe precursor. We also demonstrate that as-grown 2D β′-In 2 Se 3 films on mica substrates can be delaminated or transferred onto flexible or uneven substrates, yielding α-In 2 Se 3 films through a complete phase transition. Thus, a full spectrum of paraelectric, ferroelectric and antiferroelectric 2D films can be readily obtained by means of the correlated polymorphism in 2D In 2 Se 3 , enabling 2D memory transistors with high electron mobility, and polarizable β′–α In 2 Se 3 heterophase junctions with improved non-volatile memory performance. A chemical-vapour-deposition-based approach enables the phase-controllable synthesis of large-scale two-dimensional β-, β′- and α-In 2 Se 3 films.

Fossil fuel is a non-renewable fuel, and with the development of modern industry and agriculture, the storage capacity of fossil fuels is constantly decreasing. In this study, a systematic study and analysis were conducted on the combustion characteristics, engine performance, and exhaust emission characteristics of castor biodiesel–diesel blends and pure diesel fuel in different proportions at different speeds of a single-cylinder four-stroke diesel engine under constant load. The castor biodiesel required for the experiment is generated through an ester exchange reaction and mixed with diesel in proportion to produce biodiesel–diesel blends. The experimental results show that as an oxygenated fuel with a higher cetane number, the CO, HC, and smoke emissions of diesel and B80 blend fuel at 1800 rpm were reduced by 16.9%, 31.6%, and 68%, respectively. On the contrary, the NOx and CO2 emissions increased by 17.3% and 34.6% compared to diesel at 1800 rpm. In addition, due to its high viscosity and low calorific value, the brake thermal efficiency and brake-specific fuel consumption of the biodiesel–diesel blends are slightly lower than those of diesel, but the biodiesel–diesel blends exhibit lower exhaust gas temperatures. Comparing B80 and diesel fuel at 1800 rpm, the BSFC of diesel at 1800 rpm is 3.12 kg/W·h, whereas for B80 blended fuel, it increases to 4.2 kg/W·h, and BTE decreases from 25.39% to 21.33%. On the contrary, B60 blended fuel exhibits a lower exhaust emission temperature, displaying 452 °C at 1800 rpm. Based on the experimental results, it can be concluded that castor biodiesel is a very promising clean alternative fuel with low waste emissions and good engine performance.

Early detection and intervention are very important for the diagnosis and treatment of Parkinson’s disease. Firstly, according to the characteristics of dysarthria and abnormal sensitivity to the pronunciation of words such as ‘[pɑ˥’, ‘pjɑʊ˥’, ‘ pən˥’, and ‘pjɛn˥’ in patients with early Parkinson’s disease, a Chinese tongue twister “[pɑ˥ paɪ⇃ pjɑʊ˥ pɪŋ˥ pən˥ peɪ⇃ pʰo˥, pʰɑʊ˥ ˩pɪŋ˥ pɪŋ˥ pʰaɪ↿ peɪ⇃ pjɛn˥ pʰɑʊ⇃” was designed. The original recordings of Parkinson’s suspected patients were collected in a hospital geriatrics clinic to construct a tongue twister speech database. Secondly, Hilbert transform is introduced to process audio data to obtain the instantaneous amplitude signal of speech, the peak value, peak position, peak width and peak area of each syllable corresponding to the instantaneous amplitude and the total speech length, are extracted to construct the machine learning speech feature data set. Finally, SVM is introduced to train and evaluate the speech features of Parkinson’s disease suspected patients, its performance is compared with those of BP and LSTM models. The results show that the recognition accuracy of the three machine learning models is 92.10%, 88.94% and 90.18%, respectively, which indicates that the speech features extracted in this paper are effective. Combined with instantaneous amplitude features of speech and SVM model, a computer-aided diagnosis system for Parkinson’s disease is built. The clinical trial results show that the recognition accuracy of the system for Parkinson’s disease patients can reach 91.43%, and the system has fast response speed and strong anti-interference ability, which can fully assist doctors in making real-time and remote selections of patients with Parkinson’s disease.

Currently, in the ongoing development of the tobacco industry, a large amount of tobacco rhizomes is discarded as waste. These wastes are usually disposed of through incineration or burial. However, these tobacco wastes still have some economic value. High-purity nicotine has a promising market outlook as the primary raw material for electronic cigarette liquid. Nicotine is not only found in tobacco leaves but also in the rhizomes of tobacco plants. This study presents a method for treating tobacco waste and extracting high-purity nicotine from it. After mixing the raw material powder and entrainer in specific ratios, as much of the nicotine in tobacco roots can be extracted as possible using supercritical carbon dioxide extraction. The effects of temperature, the ratio of the entrainer, and the volume fraction of ethanol in the entrainer on the nicotine yield in supercritical fluid extraction (SFE) at 25 MPa for 120 min were discussed. By using 90% ethanol (a raw material mass-to-volume ratio of 1:5) as the entrainer, we obtained the highest nicotine yield of 0.49% at 65 °C. Meanwhile, the purity of the crude extract was 61.71%, and after purification, it increased to 97.57%. In this way, we can not only obtain nicotine with market value but also further reduce the harm to the environment caused by tobacco waste disposal.