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"Zhu, Kai"
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Scalable fabrication and coating methods for perovskite solar cells and solar modules
Since the report in 2012 of a solid-state perovskite solar cell (PSC) with a power-conversion efficiency (PCE) of 9.7% and a stability of 500 h, intensive efforts have been made to increase the certified PCE, reaching 25.2% in 2019. The PCE of PSCs now exceeds that of conventional thin-film solar-cell technologies, and the rate at which this increase has been achieved is unprecedented in the history of photovoltaics. Moreover, the development of moisture-stable and heat-stable materials has increased the stability of PSCs. Small-area devices (<1 cm
2
) are typically fabricated using a spin-coating method; however, this approach may not be suitable for the preparation of the large-area (>100 cm
2
) substrates required for commercialization. Thus, materials and methods need to be developed for coating large-area PSCs. In this Review, we discuss solution-based and vapour-phase coating methods for the fabrication of large-area perovskite films, examine the progress in performance and the parameters affecting the properties of large-area coatings, and provide an overview of the methodologies for achieving high-efficiency perovskite solar modules.
The scalable fabrication of perovskite solar cells and solar modules requires the development of new materials and coating methods. In this Review, we discuss solution-based and vapour-phase coating methods for large-area perovskite films and examine the progress in performance and the parameters affecting large-area coatings.
Journal Article
Prospects for metal halide perovskite-based tandem solar cells
Over the past decade, metal halide perovskite photovoltaics have been a major focus of research, with single-junction perovskite solar cells evolving from an initial power conversion efficiency of 3.8% to reach 25.5%. The broad bandgap tunability of perovskites makes them versatile candidates as the subcell in a tandem photovoltaics architecture. Stacking photovoltaic absorbers with cascaded bandgaps in a multi-junction device can potentially overcome the Shockley–Queisser efficiency limit of 33.7% for single-junction solar cells. There is now intense activity in developing tandem solar cells that pair perovskite with either itself or with a variety of mature photovoltaic technologies such as silicon and Cu(In,Ga)(S,Se)2 (CIGS). In this review, we survey recent advances in the field and discuss its outlook.A discussion of the evolution, present status and future outlook for tandem solar cells employing perovskite materials.
Journal Article
Healthy lifestyle behaviors, mediating biomarkers, and risk of microvascular complications among individuals with type 2 diabetes: A cohort study
The influence of overall lifestyle behaviors on diabetic microvascular complications remains unknown. In addition, the potential mediating biomarkers underlying the association is unclear. This study aimed to examine the associations of the combined lifestyle factors with risks of total and individual microvascular complications among patients with type 2 diabetes (T2D) and to explore the potential mediation effects of metabolic biomarkers.
This retrospective cohort study included 15,104 patients with T2D free of macro- and microvascular complications at baseline (2006 to 2010) from the UK Biobank. Healthy lifestyle behaviors included noncurrent smoking, recommended waist circumference, regular physical activity, healthy diet, and moderate alcohol drinking. Outcomes were ascertained using electronic health records. Over a median of 8.1 years of follow-up, 1,296 cases of the composite microvascular complications occurred, including 558 diabetic retinopathy, 625 diabetic kidney disease, and 315 diabetic neuropathy, with some patients having 2 or 3 microvascular complications simultaneously. After multivariable adjustment for sociodemographic characteristics, history of hypertension, glycemic control, and medication histories, the hazard ratios (95% confidence intervals (CIs)) for the participants adhering 4 to 5 low-risk lifestyle behaviors versus 0 to 1 were 0.65 (0.46, 0.91) for diabetic retinopathy, 0.43 (0.30, 0.61) for diabetic kidney disease, 0.46 (0.29, 0.74) for diabetic neuropathy, and 0.54 (0.43, 0.68) for the composite outcome (all Ps-trend ≤0.01). Further, the population-attributable fraction (95% CIs) of diabetic microvascular complications for poor adherence to the overall healthy lifestyle (<4 low-risk factors) ranged from 25.3% (10.0%, 39.4%) to 39.0% (17.7%, 56.8%). In addition, albumin, HDL-C, triglycerides, apolipoprotein A, C-reactive protein, and HbA1c collectively explained 23.20% (12.70%, 38.50%) of the associations between overall lifestyle behaviors and total diabetic microvascular complications. The key limitation of the current analysis was the potential underreporting of microvascular complications because the cases were identified via electronic health records.
Adherence to overall healthy lifestyle behaviors was associated with a significantly lower risk of microvascular complications in patients with T2D, and the favorable associations were partially mediated through improving biomarkers of glycemic control, systemic inflammation, liver function, and lipid profile.
Journal Article
Long-range hot-carrier transport in hybrid perovskites visualized by ultrafast microscopy
The Shockley-Queisser limit for solar cell efficiency can be overcome if hot carriers can be harvested before they thermalize. Recently, carrier cooling time up to 100 picoseconds was observed in hybrid perovskites, but it is unclear whether these long-lived hot carriers can migrate long distance for efficient collection. We report direct visualization of hot-carrier migration in methylammonium lead iodide (CH₃NH₃PbI₃) thin films by ultrafast transient absorption microscopy, demonstrating three distinct transport regimes. Quasiballistic transport was observed to correlate with excess kinetic energy, resulting in up to 230 nanometers transport distance that could overcome grain boundaries. The nonequilibrium transport persisted over tens of picoseconds and ~600 nanometers before reaching the diffusive transport limit. These results suggest potential applications of hot-carrier devices based on hybrid perovskites.
Journal Article
Collaborative agglomeration level and spatial correlation of intercity manufacturing industry: An empirical study based on the cities of the Yangtze River Delta
Taking 27 cities in the Yangtze River Delta as an example, the time section data from 2009 to 2019 are selected, and the location entropy index and the modified E-G index are introduced to measure the collaborative agglomeration level of intercity manufacturing industry in the Yangtze River Delta. The spatial weight matrix is constructed based on the highway mileage between cities. Using Moran’s index and Local Moran’s index, this article analyzes the spatial correlation of the collaborative agglomeration level of intercity manufacturing industry in the Yangtze River Delta. The results show that: Firstly, the overall agglomeration degree of manufacturing industry of cities in the Yangtze River Delta shows a fluctuating downward trend. The agglomeration degree of manufacturing industry in Jiangsu and Zhejiang Provinces has decreased, that of most cities in Anhui Province has increased steadily. Secondly, the collaborative agglomeration level of manufacturing industry between Shanghai, Nanjing, Hangzhou and other cities in Jiangsu and Zhejiang Provinces showed a downward trend, while the collaborative agglomeration level with Anhui cities increased steadily. The collaborative agglomeration level of manufacturing industry between Wuxi, Suzhou, Nanjing and cities with obvious advantages in manufacturing industry agglomeration degree shows an upward trend, while the collaborative agglomeration level with other cities has declined. The collaborative agglomeration level of intercity manufacturing industry in Hefei has generally improved, especially the collaborative agglomeration quality and depth of manufacturing industry between Hefei and other cities in Anhui Province have significantly improved. Thirdly, the regions with high collaborative agglomeration level of intercity manufacturing industry in the Yangtze River Delta are still mainly concentrated in Jiangsu and Zhejiang Provinces. Although there has been a trend of westward transfer in the past decade, the overall change range is small, and the spatial correlation of the collaborative agglomeration level of intercity manufacturing industry shows a weakening trend as a whole.
Journal Article
Limits to growth of forest biomass carbon sink under climate change
Widely recognized as a significant carbon sink, North American forests have experienced a history of recovery and are facing an uncertain future. This growing carbon sink is dictated by recovery from land-use change, with growth trajectory modified by environmental change. To address both processes, we compiled a forest inventory dataset from North America to quantify aboveground biomass growth with stand age across forest types and climate gradients. Here we show, the biomass grows from 90 Mg ha
–1
(2000–2016) to 105 Mg ha
–1
(2020 s), 128 Mg ha
–1
(2050 s), and 146 Mg ha
–1
(2080 s) under climate change scenarios with no further disturbances. Climate change modifies the forest recovery trajectory to some extent, but the overall growth is limited, showing signs of biomass saturation. The future (2080s) biomass will only sequester at most 22% more carbon than the current level. Given such a strong sink has limited growth potential, our ground-based analysis suggests policy changes to sustain the carbon sink.
The recovery of North American forests is likely to impact their capacity as a carbon sink. Here, Zhu et al. show a growth in aboveground biomass in various climate change scenarios, with these forests expected to sequester no more than 22% more carbon than current levels by the 2080s.
Journal Article
A Joint Optimization Model of Production Scheduling and Maintenance Based on Data Driven for a Parallel-Series Production Line
The maintenance of a production line is becoming more important with the development of demanding higher operational efficiency and safety in industrial system. However, a production line often operates under dynamically operational and environmental conditions and the production scheduling is also a very important factor for the maintenance of a production line. First, this paper proposes an integrated data-driven model that coordinates maintenance planning decisions with production scheduling decisions to solve the problem of scheduling and maintenance planning for a parallel-series production line. The degradation information is considered, and the total cost is to be minimized in the proposed model. Also, the total cost is related with production process and maintenance considering reliability of equipment. Then, in order to better describe the relationship between production and maintenance, the accumulative processing time of equipment is used as the input of its failure function. Also, an ability factor is developed to control its reduced level by adopting preventive maintenance. Finally, a case study is used to demonstrate the implementation and potential applications of the proposed model. The long-term wear test experiments are conducted at a research laboratory facility of Shanghai Pangyuan Machinery Co., Ltd. The result proves that the proposed method is feasible and efficient to solve the joint decision-making problem for a parallel-series production line with multivariety and small batch production. The proposed model in this paper is suitable for semiconductor manufacturing.
Journal Article
Metal–organic framework-based separator for lithium–sulfur batteries
Lithium–sulfur batteries are a promising energy-storage technology due to their relatively low cost and high theoretical energy density. However, one of their major technical problems is the shuttling of soluble polysulfides between electrodes, resulting in rapid capacity fading. Here, we present a metal–organic framework (MOF)-based battery separator to mitigate the shuttling problem. We show that the MOF-based separator acts as an ionic sieve in lithium–sulfur batteries, which selectively sieves Li
+
ions while efficiently suppressing undesired polysulfides migrating to the anode side. When a sulfur-containing mesoporous carbon material (approximately 70 wt% sulfur content) is used as a cathode composite without elaborate synthesis or surface modification, a lithium–sulfur battery with a MOF-based separator exhibits a low capacity decay rate (0.019% per cycle over 1,500 cycles). Moreover, there is almost no capacity fading after the initial 100 cycles. Our approach demonstrates the potential for MOF-based materials as separators for energy-storage applications.
One of the major problems in Li–S batteries is the undesired shuttling of lithium polysulfides between electrodes. Here the authors present a metal–organic framework-based separator to mitigate the shuttle effect, leading to stable long cycles.
Journal Article
Relationships between plant diversity and soil microbial diversity vary across taxonomic groups and spatial scales
Plant diversity has long been assumed to predict soil microbial diversity. However, contradictory results have been found when examining their relationships, particularly at broad spatial scales. To address this issue, we conducted a meta‐analysis to evaluate the patterns in the correlation between plant diversity and soil microbial diversity and the underlying factors driving the relationship. We collected correlation data from 84 studies covering more than 3900 natural terrestrial samples globally. Using the hierarchical mixed‐effects model, we investigated factors including targeted taxonomic group, microbial examination method, sampling extent, biome type, soil type, and environmental factors to assess the patterns of the plant–microbial correlation and the determinants of their variations. We found that microbial richness displayed a modest but positive correlation with plant diversity (r = 0.333, CI = 0.220–0.437). In spite of variability among taxonomic groups and their relationship with plant diversity, positive correlations were more pronounced in the intermediate sampling extent of latitude and elevation coverage, and tropical forests. Among examined environmental factors, soil pH was negatively associated with the plant and soil microbial relationships at large spatial scales. The plant–microbial correlation appears more sensitive to edaphic factor variation in the poor nutrients and soil less compact systems. Collectively, our results point to key differences across taxonomic groups, spatial scales and biomes, and the modulating effects of climate and soil. The findings shed light on our deep understanding in plant–microbial diversity relationships at broad spatial scales and ecosystem sensitivity to biodiversity loss and environmental change.
Journal Article