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Kenaf (Hibiscus cannabinus L.) is one of the most investigated and industrially applied natural fibers for polymer composite reinforcement. However, relatively limited information is available regarding its epoxy composites. In this work, both thermal and chemical properties were, for the first time, determined in kenaf fiber reinforced epoxy matrix composites. Through XRD analysis, a microfibrillar angle of 7.1° and crystallinity index of 44.3% was obtained. The FTIR analysis showed the functional groups normally found for natural lignocellulosic fibers. TMA analysis of the composites with 10 vol% and 20 vol% of kenaf fibers disclosed a higher coefficient of thermal expansion. The TG/DTG results of the epoxy composites revealed enhanced thermal stability when compared to plain epoxy. The DSC results corroborated the results obtained by TGA, which indicated a higher mass loss in the first stage for kenaf when compared to its composites. These results might contribute to kenaf fiber composite applications requiring superior performance.

The environmental impact of petroleum-based materials in driving climate change has stimulated growing interest in natural lignocellulosic fibers (NLFs) as reinforcements for polymeric matrices. NLFs exhibit specific mechanical properties that, in some cases, rival those of synthetic fibers such as aramid, carbon, and glass. Among the wide variety of NLFs, kenaf has been extensively investigated in applications including textiles, construction, and furniture, owing to its long-established global cultivation. Previous studies have also demonstrated its potential as a reinforcement in polymeric matrices for engineering applications, including ballistic protection. In this context, the present work reports, for the first time, on the tensile and dynamic impact toughness of epoxy matrix composites reinforced with 10, 20, and 30 vol% kenaf fibers. The tensile toughness, defined as the area under the stress–strain curve up to fracture, ranged from 9.36 kJ/m2 at 10 vol% to 52.30 kJ/m2 at 30 vol% fiber content—representing a three- to tenfold increase compared to the neat epoxy matrix. In Izod impact tests, the composites containing 30 vol% kenaf fibers absorbed 22 times more energy than the neat epoxy, rising from 1.8 to 38.8 kJ/m2. On average, the tensile toughness values exceeded those of the corresponding dynamic impact toughness. Scanning electron microscopy revealed the fracture morphology and highlighted the influence of the fibers under both toughness conditions.

Several industry sectors have sought to develop materials that combine lightness, strength and cost-effectiveness. Natural lignocellulosic natural fibers have demonstrated to be efficient in replacing synthetic fibers, owing to several advantages such as costs 50% lower than that of synthetic fibers and promising mechanical specific properties. Polymeric matrix composites that use kenaf fibers as reinforcement have shown strength increases of over 600%. This work aims to evaluate the performance of epoxy matrix composites reinforced with kenaf fibers, by means of dynamic-mechanical analysis (DMA) and ballistic test. Through DMA, it was possible to obtain the curves of storage modulus (E′), loss modulus (E″) and damping factor, Tan δ, of the composites. The variation of E′ displayed an increase from 1540 MPa for the plain epoxy to 6550 MPa for the 30 vol.% kenaf fiber composites, which evidences the increase in viscoelastic stiffness of the composite. The increase in kenaf fiber content induced greater internal friction, resulting in superior E″. The Tan δ was considerably reduced with increasing reinforcement fraction, indicating better interfacial adhesion between the fiber and the matrix. Ballistic tests against 0.22 caliber ammunition revealed similar performance in terms of both residual and limit velocities for plain epoxy and 30 vol.% kenaf fiber composites. These results confirm the use of kenaf fiber as a promising reinforcement of polymer composites for automotive parts and encourage its possible application as a ballistic armor component.

The growing concern about the limitation of non-renewable resources has brought a focus on the development of environmentally sustainable and biodegradable composite materials. In this context, a trend in the development of natural fibers used as a reinforcement in composites is ever-increasing. In this work, for the first-time, fibers extracted from the seven-islands-sedge plant (Cyperus malaccensis) have been characterized by X-ray diffraction (XRD) to calculate the crystallinity index and the microfibrillar angle (MFA). Also, an evaluation of the ultimate tensile strength by diameter intervals has been investigated and statistically analyzed by both the Weibull method and the analysis of variance (ANOVA). Moreover, the maximum deformation and tensile modulus have been found from the data acquired. Pullout tests have been conducted to investigate the critical length and interfacial strength when sedge fibers, are incorporated into epoxy resin matrix. Microstructure analysis by scanning electron microscopy (SEM) was performed to observe the mechanism responsible for causing rupture of the fiber as well as the effective fiber interfacial adhesion to the epoxy matrix.

Basic properties of sedge fibers from the seven-islands-sedge plant (Cyperus malaccensis) were investigated with possible application in reinforcing composite materials. A dimensional distribution and the effect of fiber diameter on density were investigated using gas pycnometry. The Weibull method, used to statistically analyze the acquired data from the diameter intervals, indicated an inverse dependence, where the thinnest fibers had the highest density values. The morphology of the fibers was obtained through scanning electron microscopy (SEM), in which a lower presence of defects was revealed in the thinner fibers, corroborating the inverse density dependence. In addition, the sedge fiber was characterized by differential scanning calorimetry and thermogravimetric analysis, which indicate an initial thermal degradation at around 241 °C. These results revealed for the first time that thinner sedge fibers might be promising reinforcement for polymer composites with a limit in temperature application.