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A key legacy of the recently launched the Transiting Exoplanet Survey Satellite (TESS) mission will be to provide the astronomical community with many of the best transiting exoplanet targets for atmospheric characterization. However, time is of the essence to take full advantage of this opportunity. The James Webb Space Telescope (JWST), although delayed, will still complete its nominal five year mission on a timeline that motivates rapid identification, confirmation, and mass measurement of the top atmospheric characterization targets from TESS. Beyond JWST, future dedicated missions for atmospheric studies such as the Atmospheric Remote-sensing Infrared Exoplanet Large-survey (ARIEL) require the discovery and confirmation of several hundred additional sub-Jovian size planets (Rp < 10 R⊕) orbiting bright stars, beyond those known today, to ensure a successful statistical census of exoplanet atmospheres. Ground-based extremely large telescopes (ELTs) will also contribute to surveying the atmospheres of the transiting planets discovered by TESS. Here we present a set of two straightforward analytic metrics, quantifying the expected signal-to-noise in transmission and thermal emission spectroscopy for a given planet, that will allow the top atmospheric characterization targets to be readily identified among the TESS planet candidates. Targets that meet our proposed threshold values for these metrics would be encouraged for rapid follow-up and confirmation via radial velocity mass measurements. Based on the catalog of simulated TESS detections by Sullivan et al., we determine appropriate cutoff values of the metrics, such that the TESS mission will ultimately yield a sample of ∼300 high-quality atmospheric characterization targets across a range of planet size bins, extending down to Earth-size, potentially habitable worlds.

A drop in the ocean Earth's bulk composition is similar to that of a group of oxygen-poor meteorites called enstatite chondrites, thought to have formed in the early solar nebula. This leads to the suggestion that proto-Earth was dry, and that volatiles including water were delivered by asteroid and comet impacts. The deuterium-to-hydrogen (D/H) ratios measured in six Oort cloud comets are much higher than on Earth, however, apparently ruling out a dominant role for such bodies. Now the Herschel Space Telescope has been used to determine the D/H ratio in the Kuiper belt comet 103P/Hartley 2. The ratio is Earth-like, suggesting that this population of comets may have contributed to Earth's ocean waters. For decades, the source of Earth's volatiles, especially water with a deuterium-to-hydrogen ratio (D/H) of (1.558 ± 0.001) × 10 −4 , has been a subject of debate. The similarity of Earth’s bulk composition to that of meteorites known as enstatite chondrites 1 suggests a dry proto-Earth 2 with subsequent delivery of volatiles 3 by local accretion 4 or impacts of asteroids or comets 5 , 6 . Previous measurements in six comets from the Oort cloud yielded a mean D/H ratio of (2.96 ± 0.25) × 10 −4 . The D/H value in carbonaceous chondrites, (1.4 ± 0.1) × 10 −4 , together with dynamical simulations, led to models in which asteroids were the main source of Earth's water 7 , with ≤10 per cent being delivered by comets. Here we report that the D/H ratio in the Jupiter-family comet 103P/Hartley 2, which originated in the Kuiper belt, is (1.61 ± 0.24) × 10 −4 . This result substantially expands the reservoir of Earth ocean-like water to include some comets, and is consistent with the emerging picture of a complex dynamical evolution of the early Solar System 8 , 9 .

We review the evidence for buried ice in the asteroid belt; specifically the questions around the so-called Main Belt Comets (MBCs). We summarise the evidence for water throughout the Solar System, and describe the various methods for detecting it, including remote sensing from ultraviolet to radio wavelengths. We review progress in the first decade of study of MBCs, including observations, modelling of ice survival, and discussion on their origins. We then look at which methods will likely be most effective for further progress, including the key challenge of direct detection of (escaping) water in these bodies.

Carbon dioxide (CO 2 ) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO 2 is an indicator of the metal enrichment (that is, elements heavier than helium, also called ‘metallicity’) 1 – 3 , and thus the formation processes of the primary atmospheres of hot gas giants 4 – 6 . It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets 7 – 9 . Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO 2 , but have not yielded definitive detections owing to the lack of unambiguous spectroscopic identification 10 – 12 . Here we present the detection of CO 2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science programme 13 , 14 . The data used in this study span 3.0–5.5 micrometres in wavelength and show a prominent CO 2 absorption feature at 4.3 micrometres (26-sigma significance). The overall spectrum is well matched by one-dimensional, ten-times solar metallicity models that assume radiative–convective–thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide and hydrogen sulfide in addition to CO 2 , but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 micrometres that is not reproduced by these models. Transmission spectroscopy observations from the James Webb Space Telescope show the detection of carbon dioxide in the atmosphere of the gas giant exoplanet WASP-39b.

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems 1 , 2 . Access to the chemical inventory of an exoplanet requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based 3 – 5 and high-resolution ground-based 6 – 8 facilities. Here we report the medium-resolution ( R  ≈ 600) transmission spectrum of an exoplanet atmosphere between 3 and 5 μm covering several absorption features for the Saturn-mass exoplanet WASP-39b (ref.  9 ), obtained with the Near Infrared Spectrograph (NIRSpec) G395H grating of JWST. Our observations achieve 1.46 times photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO 2 (28.5 σ ) and H 2 O (21.5 σ ), and identify SO 2 as the source of absorption at 4.1 μm (4.8 σ ). Best-fit atmospheric models range between 3 and 10 times solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO 2 , underscore the importance of characterizing the chemistry in exoplanet atmospheres and showcase NIRSpec G395H as an excellent mode for time-series observations over this critical wavelength range 10 . The medium-resolution transmission spectrum of the exoplanet WASP-39b, described using observations from the Near Infrared Spectrograph G395H grating aboard JWST, shows significant absorption from CO 2 and H 2 O and detection of SO 2 .

pyspeckit is a toolkit and library for spectroscopic analysis in Python. We describe the pyspeckit package and highlight some of its capabilities, such as interactively fitting a model to data, akin to the historically widely-used splot function in IRAF. pyspeckit employs the Levenberg-Marquardt optimization method via the mpfit and lmfit implementations, and important assumptions regarding error estimation are described here. Wrappers to use pymc and emcee as optimizers are provided. A parallelized wrapper to fit lines in spectral cubes is included. As part of the astropy affiliated package ecosystem, pyspeckit is open source and open development and welcomes input and collaboration from the community.

Sky survey telescopes and powerful targeted telescopes play complementary roles in astronomy. In order to investigate the nature and characteristics of the motions of very faint objects, a flexibly-pointed instrument capable of high astrometric accuracy is an ideal complement to current astrometric surveys and a unique tool for precision astrophysics. Such a space-based mission will push the frontier of precision astrometry from evidence of Earth-mass habitable worlds around the nearest stars, to distant Milky Way objects, and out to the Local Group of galaxies. As we enter the era of the James Webb Space Telescope and the new ground-based, adaptive-optics-enabled giant telescopes, by obtaining these high precision measurements on key objects that Gaia could not reach, a mission that focuses on high precision astrometry science can consolidate our theoretical understanding of the local Universe, enable extrapolation of physical processes to remote redshifts, and derive a much more consistent picture of cosmological evolution and the likely fate of our cosmos. Already several missions have been proposed to address the science case of faint objects in motion using high precision astrometry missions: NEAT proposed for the ESA M3 opportunity, micro-NEAT for the S1 opportunity, and Theia for the M4 and M5 opportunities. Additional new mission configurations adapted with technological innovations could be envisioned to pursue accurate measurements of these extremely small motions. The goal of this White Paper is to address the fundamental science questions that are at stake when we focus on the motions of faint sky objects and to briefly review instrumentation and mission profiles.

We report the discovery by the ground-based HATNet survey of the transiting exoplanet HAT-P-68b, which has a mass of 0.724 \\(\\pm\\) 0.043 \\(M_{Jup}\\), and radius of 1.072 \\(\\pm\\) 0.012 \\(R_{Jup}\\). The planet is in a circular P = 2.2984-day orbit around a moderately bright V = 13.937 \\(\\pm\\) 0.030 magnitude K dwarf star of mass 0.673 \\(+\\) 0.020 \\(-\\)0.014 \\(M_{\\odot}\\), and radius 0.6726 \\(\\pm\\) 0.0069 \\(R_{\\odot}\\). The planetary nature of this system is confirmed through follow-up transit photometry obtained with the FLWO~1.2m telescope, high-precision RVs measured using Keck-I/HIRES, FLWO~1.5m/TRES, and OHP~1.9m/Sophie, and high-spatial-resolution speckle imaging from WIYN~3.5m/DSSI. HAT-P-68 is at an ecliptic latitude of \\(+3^{\\circ}\\) and outside the field of view of both the NASA TESS primary mission and the K2 mission. The large transit depth of 0.036 mag (\\(r\\)-band) makes HAT-P-68b a promising target for atmospheric characterization via transmission spectroscopy.

emcee is a Python library implementing a class of affine-invariant ensemble samplers for Markov chain Monte Carlo (MCMC). This package has been widely applied to probabilistic modeling problems in astrophysics where it was originally published, with some applications in other fields. When it was first released in 2012, the interface implemented in emcee was fundamentally different from the MCMC libraries that were popular at the time, such as PyMC, because it was specifically designed to work with \"black box\" models instead of structured graphical models. This has been a popular interface for applications in astrophysics because it is often non-trivial to implement realistic physics within the modeling frameworks required by other libraries. Since emcee's release, other libraries have been developed with similar interfaces, such as dynesty (Speagle 2019). The version 3.0 release of emcee is the first major release of the library in about 6 years and it includes a full re-write of the computational backend, several commonly requested features, and a set of new \"move\" implementations.

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (that is, elements heavier than helium, also called 'metallicity'), and thus the formation processes of the primary atmospheres of hot gas giants. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2, but have not yielded definitive detections owing to the lack of unambiguous spectroscopic identification. Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science programme. The data used in this study span 3.0-5.5 micrometres in wavelength and show a prominent CO2 absorption feature at 4.3 micrometres (26-sigma significance). The overall spectrum is well matched by one-dimensional, ten-times solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 micrometres that is not reproduced by these models.