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"手性化合物"
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Superior ligand for Pd（II）-catalyzed enantioselective arylation of C（spa）-H bonds： chiral acetyl protected aminoethyl quinoline
Enantioselective functionalization of prochiral C-H bonds is a highly attractive strategy for the construction of chiral compounds.Despite extensive efforts[1],enantioselective C（sp3）-H functionalization still remains challenging at present.For instance,although enantioselective C-H functionalization via desymmetrization of two carbon centers has been accomplished with Pd catalysis and a directing group,differenciation of the prochiral C-H bonds on one methylene carbon center has rarely been achieved.On a different front,introduction of a transient chiral directing group is expected to be useful in enantioselective C-H arylation of C（sp2）-H bonds.Nevertheless,
Journal Article